Detectability of atmospheric features of Earth-like planets in the habitable zone around M dwarfs

We investigate the detectability of atmospheric spectral features of Earth-like planets in the habitable zone (HZ) around M dwarfs with the future James Webb Space Telescope (JWST). We use a coupled 1D climate-chemistry-model to simulate the influence of a range of observed and modelled M-dwarf spectra on Earth-like planets. The simulated atmospheres served as input for the calculation of the transmission spectra of the hypothetical planets, using a line-by-line spectral radiative transfer model. To investigate the spectroscopic detectability of absorption bands with JWST we further developed a signal-to-noise ratio (S/N) model and applied it to our transmission spectra. High abundances of CH$_4$ and H$_2$O in the atmosphere of Earth-like planets around mid to late M dwarfs increase the detectability of the corresponding spectral features compared to early M-dwarf planets. Increased temperatures in the middle atmosphere of mid- to late-type M-dwarf planets expand the atmosphere and further increase the detectability of absorption bands. To detect CH$_4$, H$_2$O, and CO$_2$ in the atmosphere of an Earth-like planet around a mid to late M dwarf observing only one transit with JWST could be enough up to a distance of 4 pc and less than ten transits up to a distance of 10 pc. As a consequence of saturation limits of JWST and less pronounced absorption bands, the detection of spectral features of hypothetical Earth-like planets around most early M dwarfs would require more than ten transits. We identify 276 existing M dwarfs (including GJ 1132, TRAPPIST-1, GJ 1214, and LHS 1140) around which atmospheric absorption features of hypothetical Earth-like planets could be detected by co-adding just a few transits. We show that using transmission spectroscopy, JWST could provide enough precision to be able to partly characterise the atmosphere of Earth-like TESS planets around mid to late M dwarfs.Comment: 18 pages, 10 figure

Near infrared nadir retrieval of vertical column densities: methodology and application to SCIAMACHY

Nadir observations with the shortwave infrared channels of SCIAMACHY on-board the ENVISAT satellite can be used to derive information on atmospheric gases such as CO, CH<sub>4</sub>, N<sub>2</sub>O, CO<sub>2</sub>, and H<sub>2</sub>O. For the operational level 1b-2 processing of SCIAMACHY data, a new retrieval code BIRRA (Beer InfraRed Retrieval Algorithm) has been developed. BIRRA performs a nonlinear or separable least squares fit (with bound constraints optional) of the measured radiance, where molecular concentration vertical profiles are scaled to fit the observed data. Here we present the forward modeling (radiative transfer) and inversion (least squares optimization) fundamentals of the code along with the further processing steps required to generate higher level products such as global distributions and time series. Moreover, various aspects of level 1 (observed spectra) and auxiliary input data relevant for successful retrievals are discussed. BIRRA is currently used for operational analysis of carbon monoxide vertical column densities from SCIAMACHY channel 8 observations, and is being prepared for methane retrievals using channel 6 spectra. A set of representative CO retrievals and first CH<sub>4</sub> results are presented to demonstrate BIRRA's capabilities

Modeling of Viscous Shock Tube Using ES-BGK Model Kinetic Equations

The viscous effects on unsteady shock wave propagation are investigated by numerical solution of the Boltzmann model kinetic equations. The kinetic equations are solved for two unsteady non-equilibrium flow problems, namely, the one-dimensional Riemann problem and a two-dimensional viscous shock-tube. The numerical method comprises the discrete velocity method in the velocity space and the finite volume discretization in physical space using various flux schemes. The discrete version of H-theorem is applied for analysis of accuracy of the numerical solution as well as of the onset of non-equilibrium. Simulations show that the maximum entropy generation rate in viscous shock tube occurs in the boundary layer / shock wave interaction region. The entropy generation rate is used to determine the time-variation of the speed of propagation of shock, contact discontinuity and rarefaction waves

ROSAT HRI observations of Centaurus A

We present results from a sensitive high-resolution X-ray observation of the nearby active galaxy Centaurus A (NGC 5128) with the ROSAT HRI. The 65~ksec X-ray image clearly distinguishes different components of the X-ray emission from Cen A: the nucleus and the jet, the diffuse galaxy halo, and a number of individual sources associated with the galaxy. The luminosity of the nucleus increased by a factor of two compared to an earlier ROSAT observation in 1990. The high spatial resolution of the ROSAT HRI shows that most of the knots in the jet are extended both along and perpendicular to the jet axis. We report the detection of a new X-ray feature, at the opposite side of the X-ray jet which is probably due to compression of hot interstellar gas by the expanding southwestern inner radio lobe.Comment: To be published in Astrophys. Journal Letters. 4 pages, 3 plate

Indeterminacy and instability in Petschek reconnection

We explain two puzzling aspects of Petschek's model for fast reconnection. One is its failure to occur in plasma simulations with uniform resistivity. The other is its inability to provide anything more than an upper limit for the reconnection rate. We have found that previously published analytical solutions based on Petschek's model are structurally unstable if the electrical resistivity is uniform. The structural instability is associated with the presence of an essential singularity at the X-line that is unphysical. By requiring that such a singularity does not exist, we obtain a formula that predicts a specific rate of reconnection. For uniform resistivity, reconnection can only occur at the slow, Sweet-Parker rate. For nonuniform resistivity, reconnection can occur at a much faster rate provided that the resistivity profile is not too flat near the X-line. If this condition is satisfied, then the scale length of the nonuniformity determines the reconnection rate

Photo-triggered hydrogen atom transfer from an iridium hydride complex to unactivated olefins

Many photoactive metal complexes can act as electron donors or acceptors upon photoexcitation, but hydrogen atom transfer (HAT) reactivity is rare. We discovered that a typical representative of a widely used class of iridium hydride complexes acts as an H-atom donor to unactivated olefins upon irradiation at 470 nm in the presence of tertiary alkyl amines as sacrificial electron and proton sources. The catalytic hydrogenation of simple olefins served as a test ground to establish this new photo-reactivity of iridium hydrides. Substrates that are very difficult to activate by photoinduced electron transfer were readily hydrogenated, and structure–reactivity relationships established with 12 different olefins are in line with typical HAT reactivity, reflecting the relative stabilities of radical intermediates formed by HAT. Radical clock, H/D isotope labeling, and transient absorption experiments provide further mechanistic insight and corroborate the interpretation of the overall reactivity in terms of photo-triggered hydrogen atom transfer (photo-HAT). The catalytically active species is identified as an Ir(II) hydride with an IrII–H bond dissociation free energy around 44 kcal mol−1, which is formed after reductive 3MLCT excited-state quenching of the corresponding Ir(III) hydride, i.e. the actual HAT step occurs on the ground-state potential energy surface. The photo-HAT reactivity presented here represents a conceptually novel approach to photocatalysis with metal complexes, which is fundamentally different from the many prior studies relying on photoinduced electron transfer

A case study of the effects of privatization of child welfare on services for children and families: The Nebraska experience

Privatization, or contracting with non-governmental agencies for provision of state or federally funded services, is a strategy that has gained recent attention from policymakers as a potential tool for successful child welfare reform. The Child Welfare Privatization Initiatives Project was created in 2007 as a joint effort between the United States Department of Health and Human Services and the Office of the Assistant Secretary for Planning and Evaluation. The framework identified by this project produced twelve key considerations for states moving towards a privatized system. This case study considers these twelve considerations in a description of the large-scale effort to privatize child welfare services in the state of Nebraska that began in 2008. Problems leading to a need for child welfare reform and possible factors that motivated policymakers to shift services from the public to the private sector are also described. While proponents of privatization appeared to expect rapid increased efficiency and cost-savings, this case study explores multiple reductions in quality and availability of services for children and families served by the child welfare system that occurred during the effort. Further, the cost of child welfare services in Nebraska increased by 27% and the private agencies invested over $21 million of their own funds as they attempted to uphold contracts. Recommendations for practitioners and policymakers considering participating in efforts to privatize child welfare services in the future are made based on Nebraska’s recent experience

Pathways between childhood victimization and psychosis-like symptoms in the ALSPAC Birth Cohort

Background: Several large population-based studies have demonstrated associations between adverse childhood experiences and later development of psychotic symptoms. However, little attention has been paid to the mechanisms involved in this pathway and the few existing studies have relied on cross-sectional assessments. Methods: Prospective data on 6692 children from the UK Avon Longitudinal Study of Parents and Children (ALSPAC) were used to address this issue. Mothers reported on children’s exposure to harsh parenting and domestic violence in early childhood, and children self-reported on bullying victimization prior to 8.5 years. Presence of children’s anxiety at 10 years and their depressive symptoms at 9 and 11 years were ascertained from mothers, and children completed assessments of self-esteem and locus of control at 8.5 years. Children were interviewed regarding psychotic symptoms at a mean age of 12.9 years. Multiple mediation analysis was performed to examine direct and indirect effects of each childhood adversity on psychotic symptoms. Results: The association between harsh parenting and psychotic symptoms was fully mediated by anxiety, depressive symptoms, external locus of control, and low self-esteem. Bullying victimization and exposure to domestic violence had their associations with psychotic symptoms partially mediated by anxiety, depression, locus of control, and self-esteem. Similar results were obtained following adjustment for a range of confounders and when analyses were conducted for boys and girls separately. Conclusions: These findings tentatively suggest that specific cognitive and affective difficulties in childhood could be targeted to minimize the likelihood of adolescents exposed to early trauma from developing psychotic symptoms