SPB stars in the open SMC cluster NGC 371

Pulsation in beta Cep and SPB stars are driven by the kappa mechanism which depends critically on the metallicity. It has therefore been suggested that beta Cep and SPB stars should be rare in the Magellanic Clouds which have lower metallicities than the solar neighborhood. To test this prediction we have observed the open SMC cluster NGC 371 for 12 nights in order to search for beta Cep and SPB stars. Surprisingly, we find 29 short-period B-type variables in the upper part of the main sequence, many of which are probably SPB stars. This result indicates that pulsation is still driven by the kappa mechanism even in low metallicity environments. All the identified variables have periods longer than the fundamental radial period which means that they cannot be beta Cep stars. Within an amplitude detection limit of 5 mmag no stars in the top of the HR-diagram show variability with periods shorter than the fundamental radial period. So if beta Cep stars are present in the cluster they oscillate with amplitudes below 5 mmag, which is significantly lower than the mean amplitude of beta Cep stars in the Galaxy. We see evidence that multimode pulsation is more common in the upper part of the main sequence than in the lower. We have also identified 5 eclipsing binaries and 3 periodic pulsating Be stars in the cluster field.Comment: 8 pages, 11 figures. Accepted for publication in MNRA

Properties of 42 Solar-type Kepler Targets from the Asteroseismic Modeling Portal

Recently the number of main-sequence and subgiant stars exhibiting solar-like oscillations that are resolved into individual mode frequencies has increased dramatically. While only a few such data sets were available for detailed modeling just a decade ago, the Kepler mission has produced suitable observations for hundreds of new targets. This rapid expansion in observational capacity has been accompanied by a shift in analysis and modeling strategies to yield uniform sets of derived stellar properties more quickly and easily. We use previously published asteroseismic and spectroscopic data sets to provide a uniform analysis of 42 solar-type Kepler targets from the Asteroseismic Modeling Portal (AMP). We find that fitting the individual frequencies typically doubles the precision of the asteroseismic radius, mass and age compared to grid-based modeling of the global oscillation properties, and improves the precision of the radius and mass by about a factor of three over empirical scaling relations. We demonstrate the utility of the derived properties with several applications

Alternative Stacking Sequences in Hexagonal Boron Nitride

The relative orientation of successive sheets, i.e. the stacking sequence, in layered two-dimensional materials is central to the electronic, thermal, and mechanical properties of the material. Often different stacking sequences have comparable cohesive energy, leading to alternative stable crystal structures. Here we theoretically and experimentally explore different stacking sequences in the van der Waals bonded material hexagonal boron nitride (h-BN). We examine the total energy, electronic bandgap, and dielectric response tensor for five distinct high symmetry stacking sequences for both bulk and bilayer forms of h-BN. Two sequences, the generally assumed AA' sequence and the relatively unknown (for h-BN) AB (Bernal) sequence, are predicted to have comparably low energy. We present a scalable modified chemical vapor deposition method that produces large flakes of virtually pure AB stacked h-BN; this new material complements the generally available AA' stacked h-BN

Designing Excited States: Theory-Guided Access to Efficient Photosensitizers for Photodynamic Action

Cataloged from PDF version of article.The in silico design of tetraradical S 1 states was validated experimentally through synthesis, followed by characterization including phosphorescence measurements, use of trap molecules, and cell culture studies, leading to a series of orthogonal dimers of Bodipy chromophores with remarkable singlet oxygen efficiencies (see picture). A new path for the rational development of efficient photosensitizers is thus revealed. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

Electron Beam-Induced Nanopores in Bernal-Stacked Hexagonal Boron Nitride

Controlling the size and shape of nanopores in two-dimensional materials is a key challenge in applications such as DNA sequencing, sieving, and quantum emission in artificial atoms. We here investigate experimentally and theoretically triangular vacancies in (unconventional) Bernal-stacked AB-h-BN formed using a high-energy electron beam. Due to the geometric configuration of AB-h-BN, triangular pores in different layers are aligned, and their sizes are controlled by the duration of the electron irradiation. Interlayer covalent bonding at the vacancy edge is not favored, as opposed to what occurs in the more common AA'-stacked BN. A variety of monolayer, concentric and bilayer pores in bilayer AB-h-BN are observed in high-resolution transmission electron microscopy and characterized using ab initio simulations. Bilayer pores in AB-h-BN are commonly formed, and grow without breaking the bilayer character. Nanopores in AB-h-BN exhibit a wide range of electronic properties, ranging from half-metallic to non-magnetic and magnetic semiconducting. Therefore, because of the controllability of the pore size, the electronic structure is also highly controllable in these systems, and can potentially be tuned for particular applications

Characterizing two solar-type Kepler subgiants with asteroseismology: KIC10920273 and KIC11395018

Determining fundamental properties of stars through stellar modeling has improved substantially due to recent advances in asteroseismology. Thanks to the unprecedented data quality obtained by space missions, particularly CoRoT and Kepler, invaluable information is extracted from the high-precision stellar oscillation frequencies, which provide very strong constraints on possible stellar models for a given set of classical observations. In this work, we have characterized two relatively faint stars, KIC10920273 and KIC11395018, using oscillation data from Kepler photometry and atmospheric constraints from ground-based spectroscopy. Both stars have very similar atmospheric properties; however, using the individual frequencies extracted from the Kepler data, we have determined quite distinct global properties, with increased precision compared to that of earlier results. We found that both stars have left the main sequence and characterized them as follows: KIC10920273 is a one-solar-mass star (M=1.00 +/- 0.04 M_sun), but much older than our Sun (t=7.12 +/- 0.47 Gyr), while KIC11395018 is significantly more massive than the Sun (M=1.27 +/- 0.04 M_sun) with an age close to that of the Sun (t=4.57 +/- 0.23 Gyr). We confirm that the high lithium abundance reported for these stars should not be considered to represent young ages, as we precisely determined them to be evolved subgiants. We discuss the use of surface lithium abundance, rotation and activity relations as potential age diagnostics.Comment: 12 pages, 3 figures, 5 tables. Accepted by Ap

Asteroseismology of the solar analogs 16 Cyg A & B from Kepler observations

The evolved solar-type stars 16 Cyg A & B have long been studied as solar analogs, yielding a glimpse into the future of our own Sun. The orbital period of the binary system is too long to provide meaningful dynamical constraints on the stellar properties, but asteroseismology can help because the stars are among the brightest in the Kepler field. We present an analysis of three months of nearly uninterrupted photometry of 16 Cyg A & B from the Kepler space telescope. We extract a total of 46 and 41 oscillation frequencies for the two components respectively, including a clear detection of octupole (l=3) modes in both stars. We derive the properties of each star independently using the Asteroseismic Modeling Portal, fitting the individual oscillation frequencies and other observational constraints simultaneously. We evaluate the systematic uncertainties from an ensemble of results generated by a variety of stellar evolution codes and fitting methods. The optimal models derived by fitting each component individually yield a common age (t=6.8+/-0.4 Gyr) and initial composition (Z_i=0.024+/-0.002, Y_i=0.25+/-0.01) within the uncertainties, as expected for the components of a binary system, bolstering our confidence in the reliability of asteroseismic techniques. The longer data sets that will ultimately become available will allow future studies of differential rotation, convection zone depths, and long-term changes due to stellar activity cycles.Comment: 6 pages, 2 figures, 2 tables, ApJ Letters (accepted

Kepler White Paper: Asteroseismology of Solar-Like Oscillators in a 2-Wheel Mission

We comment on the potential for continuing asteroseismology of solar-type and red-giant stars in a 2-wheel Kepler Mission. Our main conclusion is that by targeting stars in the ecliptic it should be possible to perform high-quality asteroseismology, as long as favorable scenarios for 2-wheel pointing performance are met. Targeting the ecliptic would potentially facilitate unique science that was not possible in the nominal Mission, notably from the study of clusters that are significantly brighter than those in the Kepler field. Our conclusions are based on predictions of 2-wheel observations made by a space photometry simulator, with information provided by the Kepler Project used as input to describe the degraded pointing scenarios. We find that elevated levels of frequency-dependent noise, consistent with the above scenarios, would have a significant negative impact on our ability to continue asteroseismic studies of solar-like oscillators in the Kepler field. However, the situation may be much more optimistic for observations in the ecliptic, provided that pointing resets of the spacecraft during regular desaturations of the two functioning reaction wheels are accurate at the < 1 arcsec level. This would make it possible to apply a post-hoc analysis that would recover most of the lost photometric precision. Without this post-hoc correction---and the accurate re-pointing it requires---the performance would probably be as poor as in the Kepler-field case. Critical to our conclusions for both fields is the assumed level of pointing noise (in the short-term jitter and the longer-term drift). We suggest that further tests will be needed to clarify our results once more detail and data on the expected pointing performance becomes available, and we offer our assistance in this work.Comment: NASA Kepler Mission White Paper; 10 pages, 2 figure

Surgical Parameters for Minimally Invasive Trans- Eustachian Tube CSF Leak Repair: A Cadaveric Study and Literature Review

Background Cerebrospinal fluid rhinorrhea from a lateral skull base defect refractory to spontaneous healing and/or conservative management is most commonly managed via open surgery. Approach for repair is dictated by location of the defect, which may require surgical exploration. The final common pathway is the eustachian tube (ET). Endoscopic ET obliteration via endonasal and lateral approaches is under development. Whereas ET anatomy has been studied, surgical landmarks have not been previously described or quantified. We aimed to define surgical parameters of specific utility to endoscopic ET obliteration. Methods A literature review was performed of known ET anatomic parameters. Next, using a combination of endoscopic and open techniques in cadavers, we cannulated the intact ET and dissected its posterior component to define the major curvature position of the ET, defined as the genu, and quantified the relative distances through the ET lumen. The genu was targeted as a major obstacle encountered when cannulating the ET from the nasopharynx. Results Among 10 ETs, we found an average distance of 23 ± 5 mm from the nasopharynx to the ET genu, distance of 24 ± 3 mm from the genu to the anterior aspect of the tympanic membrane and total ET length of 47 ± 4 mm. Conclusions Although membranous and petrous components of the ET are important to its function, the genu may be a more useful surgical landmark. Basic surgical parameters for endoscopic ET obliteration are defined