698 research outputs found
Oxygen diffusion and reactivity at low temperature on bare amorphous olivine-type silicate
The mobility of O atoms at very low temperatures is not generally taken into
account, despite O diffusion would add to a series of processes leading to the
observed rich molecular diversity in space. We present a study of the mobility
and reactivity of O atoms on an amorphous silicate surface. Our results are in
the form of RAIRS and temperature-programmed desorption spectra of O2 and O3
produced via two pathways: O + O and O2 + O, investigated in a submonolayer
regime and in the range of temperature between 6.5 and 30 K. All the
experiments show that ozone is formed efficiently on silicate at any surface
temperature between 6.5 and 30 K. The derived upper limit for the activation
barriers of O + O and O2 + O reactions is 150 K/kb. Ozone formation at low
temperatures indicates that fast diffusion of O atoms is at play even at 6.5 K.
Through a series of rate equations included in our model, we also address the
reaction mechanisms and show that neither the Eley Rideal nor the Hot atom
mechanisms alone can explain the experimental values. The rate of diffusion of
O atoms, based on modeling results, is much higher than the one generally
expected, and the diffusive process proceeds via the Langmuir-Hinshelwood
mechanism enhanced by tunnelling. In fact, quantum effects turn out to be a key
factor that cannot be neglected in our simulations. Astrophysically, efficient
O3 formation on interstellar dust grains would imply the presence of huge
reservoirs of oxygen atoms. Since O3 is a reservoir of elementary oxygen, and
also of OH via its hydrogenation, it could explain the observed concomitance of
CO2 and H2O in the ices.Comment: 28 pages, 14 figure
Formation of Molecular Hydrogen on Amorphous Silicate Surfaces
Experimental results on the formation of molecular hydrogen on amorphous silicate surfaces are presented and analyzed using a rate equation model. The energy barriers for the relevant diffusion and desorption processes are obtained. They turn out to be significantly higher than those obtained for polycrystalline silicates, demonstrating the importance of grain morphology. Using these barriers we evaluate the efficiency of molecular hydrogen formation on amorphous silicate grains under interstellar conditions. It is found that unlike polycrystalline silicates, amorphous silicate grains are efficient catalysts of H_2 formation in diffuse interstellar clouds
High resolution spectroscopy of the extended narrow-line region of IC 5063 and NGC 7212
We studied the properties of the gas of the extended narrow line region
(ENLR) of two Seyfert 2 galaxies: IC 5063 and NGC 7212. We analysed high
resolution spectra to investigate how the main properties of this region depend
on the gas velocity. We divided the emission lines in velocity bins and we
calculated several line ratios. Diagnostic diagrams and SUMA composite models
(photo-ionization + shocks), show that in both galaxies there might be evidence
of shocks significantly contributing in the gas ionization at high |V|, even
though photo-ionization from the active nucleus remains the main ionization
mechanism. In IC 5063 the ionization parameter depends on V and its trend might
be explained assuming an hollow bi-conical shape for the ENLR, with one of the
edges aligned with the galaxy disk. On the other hand, NGC 7212 does not show
any kind of dependence. The models show that solar O/H relative abundances
reproduce the observed spectra in all the analysed regions. They also revealed
an high fragmentation of the gas clouds, suggesting that the complex kinematics
observed in these two objects might be caused by interaction between the ISM
and high velocity components, such as jets.Comment: 29 pages, 32 figures, accepted for publication in MNRA
Molecular Hydrogen Formation on Amorphous Silicates Under Interstellar Conditions
Experimental results on the formation of molecular hydrogen on amorphous silicate surfaces are presented for the first time and analyzed using a rate equation model. The energy barriers for the relevant diffusion and desorption processes are obtained. They turn out to be significantly higher than those obtained earlier for polycrystalline silicates, demonstrating the importance of grain morphology. Using these barriers we evaluate the efficiency of molecular hydrogen formation on amorphous silicate grains under interstellar conditions. It is found that unlike polycrystalline silicates, amorphous silicate grains are efficient catalysts of H_{2} formation within a temperature range which is relevant to diffuse interstellar clouds. The results also indicate that the hydrogen molecules are thermalized with the surface and desorb with low kinetic energy. Thus, they are unlikely to occupy highly excited states
Constraints of T conformation of carp azide hemoglobin on Fe site structure
AbstractThe iron site structure modifications induced by the transition from the quaternary R to T structure in ferric carp azide hemoglobin have been detected from analysis of multiple scattering resonances in the XANES (X-ray absorption near edge structure) spectra. High signal-to-noise XANES spectra measured at the Frascati ‘wiggler’ synchrotron radiation facility reveal that the forces on the Fe active site, due to the transition from the R to T quaternary conformation, only induce the tilting of the porphyrin plane and probably also of the proximal histidine. The variation of the Fe-N mean distance is not detected by XANES spectroscopy and therefore it is less than 0.01 Å
Cobalt, chromium and molybdenum ions kinetics in the human body: data gained from a total hip replacement with massive third body wear of the head and neuropathy by cobalt intoxication.
6openopenPazzaglia, U; Apostoli, P; Congiu, T; Catalani, S; Marchese, M; Zarattini, G.Pazzaglia, Ugo; Apostoli, Pietro; Congiu, T; Catalani, S; Marchese, M; Zarattini, Guid
Human primary dermal fibroblasts interacting with 3-dimensional matrices for surgical application show specific growth and gene expression programs
Several types of 3-dimensional (3D) biological matrices are employed for clinical and surgical applications, but few indications are available to guide surgeons in the choice among these materials. Here we compare the in vitro growth of human primary fibroblasts on different biological matrices commonly used for clinical and surgical applications and the activation of specific molecular pathways over 30 days of growth. Morphological analyses by Scanning Electron Microscopy and proliferation curves showed that fibroblasts have different ability to attach and proliferate on the different biological matrices. They activated similar gene expression programs, reducing the expression of collagen genes and myofibroblast differentiation markers compared to fibroblasts grown in 2D. However, differences among 3D matrices were observed in the expression of specific metalloproteinases and interleukin-6. Indeed, cell proliferation and expression of matrix degrading enzymes occur in the initial steps of interaction between fibroblast and the investigated meshes, whereas collagen and interleukin-6 expression appear to start later. The data reported here highlight features of fibroblasts grown on different 3D biological matrices and warrant further studies to understand how these findings may be used to help the clinicians choose the correct material for specific applications
A new species of Aquilegia (Ranunculaceae) from Sardinia (Italy)
The new species Aquilegia cremnophila (Ranunculaceae) from the Italian island of Sardinia is here described and illustrated. It occurs in shady rocky crevices, near the upper parts of Mt. Corrasi (Supramontes Region), where it is a member of chasmophilous communities. This species is morphologically, phenologically, ecologically and genetically well differentiated from the other Sardinian taxa, showing some relationships mainly with A. nugorensis, an endemic species of Central-Eastern Sardinia. Its conservation status is examined. A key of all taxa present in Sardinia is also provided. © 2012 Magnolia Press.Peer Reviewe
Exploring the parent population of beamed NLS1s: from the black hole to the jet
The aim of this work is to understand the nature of the parent population of
beamed narrow-line Seyfert 1 galaxies (NLS1s), by studying the physical
properties of three parent candidates samples: steep-spectrum radio-loud NLS1s,
radio-quiet NLS1s and disk-hosted radio-galaxies. In particular, we focused on
the black hole mass and Eddington ratio distribution and on the interactions
between the jet and the narrow-line region.Comment: 6 pages, 2 figures, to appear in Proceedings of High Energy Phenomena
in Relativistic Outflows (HEPRO) V, Workshop Series of the Argentinian
Astronomical Societ
Unveiling the parent population of beamed narrow-line Seyfert 1s
Narrow-line Seyfert 1 galaxies (NLS1s) are active galactic nuclei (AGN)
recently identified as a new class of -ray sources. The high energy
emission is explained by the presence of a relativistic jet observed at small
angles, just like in the case of blazars. When the latter are observed at
larger angles they appear as radio-galaxies, but an analogue parent population
for beamed NLS1s has not yet been determined. In this work we analyze this
problem by studying the physical properties of three different samples of
parent sources candidates: steep-spectrum radio-loud NLS1s, radio-quiet NLS1s,
and disk-hosted radio-galaxies, along with compact steep-spectrum sources. In
our approach, we first derived black hole mass and Eddington ratio from the
optical spectra, then we investigated the interaction between the jet and the
narrow-line region from the [O III] 4959,5007 lines. Finally,
the radio luminosity function allowed us to compare their jet luminosity and
hence determine the relations between the samples.Comment: 6 pages, no figures. Proceedings of the 28th Texas Symposium, Geneva,
December 13-18, 201
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