2023 Roadmap on ammonia as a carbon-free fuel

The 15 short chapters that form this 2023 ammonia-for-energy roadmap provide a comprehensive assessment of the current worldwide ammonia landscape and the future opportunities and associated challenges facing the use of ammonia, not only in the part that it can play in terms of the future displacement of fossil-fuel reserves towards massive, long-term, carbon-free energy storage and heat and power provision, but also in its broader holistic impacts that touch all three components of the future global food-water-energy nexus

Renewable Electricity Generation in Small Island Developing States: The Effect of Importing Ammonia

Recently, we demonstrated for Curaçao that renewable electricity generation from wind combined with energy storage in the form of ammonia is competitive with imported fossil fuels, such as LNG, oil, and coal. In the current work, we have expanded the model by considering imported green ammonia as an alternative to local electricity generation and storage. Local production of ammonia as an energy storage medium was compared with imported ammonia to make up the electricity produced from onshore wind, for Curaçao and Fiji’s largest island Viti Levu. Curaçao and Viti Levu have been selected as two interesting extremes with favorable and non-favorable wind conditions, respectively. Assuming a market price of 500 USD/t NH3, it is found that importing ammonia is the most feasible solution for both islands, with a levelized cost of electricity (LCOE) of 0.11 USD/kWh for Curaçao and 0.37 USD/kWh for Viti Levu. This compares to 0.12 USD/kWh for Curaçao; however, for Viti Levu, this value increases to 1.10 USD/kWh for a completely islanded system based on onshore wind and imported ammonia. These islands represent two extreme cases in terms of wind load factor and load consistency, as Curaçao has a high and consistent wind load factor when compared to Viti Levu. Thus, the conclusions obtained for these locations are expected to be applicable for other small island developing states

Plasma-driven catalysis: green ammonia synthesis with intermittent electricity

Ammonia is one of the most produced chemicals, mainly synthesized from fossil fuels for fertilizer applications. Furthermore, ammonia may be one of the energy carriers of the future, when it is produced from renewable electricity. This has spurred research on alternative technologies for green ammonia production. Research on plasma-driven ammonia synthesis has recently gained traction in academic literature. In the current review, we summarize the literature on plasma-driven ammonia synthesis. We distinguish between mechanisms for ammonia synthesis in the presence of a plasma, with and without a catalyst, for different plasma conditions. Strategies for catalyst design are discussed, as well as the current understanding regarding the potential plasma-catalyst synergies as function of the plasma conditions and their implications on energy efficiency. Finally, we discuss the limitations in currently reported models and experiments, as an outlook for research opportunities for further unravelling the complexities of plasma-catalytic ammonia synthesis, in order to bridge the gap between the currently reported models and experimental results