Can we detect internal moisture content in hardened concrete with an infrared camera?

The main goal of this paper was to assess the ability of infrared thermography to detect non-superficial moisture content in concrete elements. For this purpose, a commercial camera (Flir i5) was used and firstly its capacities and technical limitations were analyzed by comparing it with other commonly commercialized. Secondly, the experiments were undertaken using a concrete specimen (water/cement=0.5) and water under a pressure of 500 kPa was injected over 72 hours into one side of the specimen. The specimen was then left at room temperature (20ºC) for 24 hours, so the surface moisture disappeared. Prior to the images acquisition, the specimen surface was heated by a lamp located at a distance of 0.68 m from the central point of the specimen. In this way, two areas (dry and injected) to be registered would receive the same energy, since they were equidistant from the heating source. The first record was acquired before heating the specimen and then, the heating process was interrupted every 10 minutes to perform the infrared images acquisitions. Finally, by means of the destructive test, the average water penetration depth was assessed to be 3 cm. The infrared images acquired before heating the specimen showed a small temperature variation as a result of the presence of water, 16,3 ºC in the dry area and 15,8 ºC in the injected area. However, after the heating, due to the greater specific heat of water, the injected part achieved a temperature 4º C lower than the symmetrical dry area. This result was very interesting because, in the initial moment (before heating) the surface specimen was dry, but there was a wet area inside of the specimen that was not visually identifiable. Nevertheless, by means of infrared imaging an indicator was obtained that allowed to detect the presence of this internal moisture content

Assessment of the dielectric anisotropy in timber using the nondestructive GPR technique

In the realm of architecture ground-penetrating radar has been used as nondestructive technique to assess physical properties of wood structures in situ. However, a better understanding of the dielectric anisotropy of timber is needed to develop this application. An experiment was conducted on samples of sawn timber of different species (densities) to study their dielectric responses according to the grain directions using a GPR with a 1.6 GHz antenna. Interesting differences were found: the propagation velocities, as well as the amplitudes of the direct and reflected waves always presented lesser when the electric field was longitudinal to the grain than when transverse. But when the field was propagated in whatever transverse direction some of those parameters not differ greatly.On the other hand, this work is supported partly by the "Programa de Apoyo a la Investigacion y Desarrollo (PAID-00-11)" of the Universitat Politecnica de Valencia. The authors would like to acknowledge the contribution of Dr Briggs of the School of Forest Resources at the University of Washington, Seattle (USA).Martínez Sala, RM.; Rodríguez Abad, I.; Díez Barra, R.; Capuz Lladró, R. (2013). Assessment of the dielectric anisotropy in timber using the nondestructive GPR technique. Construction and Building Materials. 38:903-911. doi:10.1016/j.conbuildmat.2012.09.052S9039113

Origin of the coloured karst fills in the neogene extensional system of ne iberia (Spain)

Karst fills from the onshore Penedès Basin and offshore València Trough display red, pink, orange and ochre colours. Their Mössbauer spectra indicate that Fe3+ contained in goethite is the dominant species in reddish-pink fills, whereas Fe2+ contained in dolomite and clays is more dominant in the orange and ochre ones. The lower δ 13C values and higher 87Sr/86Sr ratios of the karst fills with respect to their host carbonates can reflect the input of soil-derived CO2 and an external radiogenic source into the karst system. This geochemical composition, together with the non-carbonate fraction of the fills, consists of authigenic and transported illite, illite-smectite interlayers, as well as kaolinite, chlorite, pyrite, quartz, ilmenite, magnetite, apatite and feldspar, account for a mixed residual-detrital origin of fills. This polygenic origin agrees with that of the terra rossa sediments described worldwide. The different colours of karst fills are attributed to fluctuations in the water table, which control the Eh/pH conditions in the karst system. Thus, reddish colours reflect low water table levels and oxidising episodes, and orange and ochre ones reflect high water table levels and more reducing episodes. The greenish colours of fills could be related to fluctuations in the Fe3+/Fe2+ ratio

Interpretación de los contenidos en elementos minoritarios en la sal de mesa mediante FRX.

La sal de mesa es el único mineral comestible que se consume diariamente. El interés por este producto ha crecido en las últimas décadas en la cultura gastronómica, presentándose como un producto gourmet, muy apreciado en la alta cocina

Megrim (Lepidorhombus whiffiagonis) weight-length relationships in the northern Bay of Biscay and Celtic Sea

The weight-length relationships are of a great interest in fish biology, stock assessment and fishery management, by predicting weight from length information and allowing to estimate the stock biomass. Weight-length relationships of megrim (Lepidorhombus whiffiagonis), an economically relevant flatfish species, are studied for two decades (2001 to 2019) in northern Bay of Biscay and Celtic Sea (ICES stock Div. 7.b-k, 8.abd), two important European fishing areas. More than 22000 specimens collected from commercial landings by AZTI and IEO were sampled. Total fish length, total weight and commercial gutted weight were obtained. Four five-year periods (quinquennium) (2000-04; 2005-09; 2010-14; 2015-19) were defined in the studied time-series. Both the large sample size and time-series available, as well as the collaboration between both institutions collecting complementary information from this stock, allowed obtaining robust somatic parameters and analyzing their temporal variations. A weight-length relationship model was fitted and the quinquennium and semester factors, which are of interest biologically and for assessment purposes, and their interactions were significant in the preliminary model. The weight-length relationships, both for total and gutted weight and for the combined sexes of the most recent quinquennium are presented in this work and considered the most suitable to be used in the oncoming annual assessment process of the status of this stock in northern Bay of Biscay and Celtic Sea in ICES

Consensus of experts from the Spanish pharmacogenetics and pharmacogenomics society and the Spanish society of medical oncology for the genotyping of DPYD in cancer patients who are candidates for treatment with fluoropyrimidines

5-Fluorouracil (5-FU) and oral fluoropyrimidines, such as capecitabine, are widely used in the treatment of cancer, especially gastrointestinal tumors and breast cancer, but their administration can produce serious and even lethal toxicity. This toxicity is often related to the partial or complete deficiency of the dihydropyrimidine dehydrogenase (DPD) enzyme, which causes a reduction in clearance and a longer half-life of 5-FU. It is advisable to determine if a DPD deficiency exists before administering these drugs by genotyping DPYD gene polymorphisms. The objective of this consensus of experts, in which representatives from the Spanish Pharmacogenetics and Pharmacogenomics Society and the Spanish Society of Medical Oncology participated, is to establish clear recommendations for the implementation of genotype and/or phenotype testing for DPD deficiency in patients who are candidates to receive fluoropyrimidines. The genotyping of DPYD previous to treatment classifies individuals as normal, intermediate, or poor metabolizers. Normal metabolizers do not require changes in the initial dose, intermediate metabolizers should start treatment with fluoropyrimidines at doses reduced to 50%, and poor metabolizers are contraindicated for fluoropyrimidinesThis project has been financed with SEOM and SEFF resource

Consensus of experts from the Spanish Pharmacogenetics and Pharmacogenomics Society and the Spanish Society of Medical Oncology for the genotyping of DPYD in cancer patients who are candidates for treatment with fluoropyrimidines

5-Fluorouracil (5-FU) and oral fluoropyrimidines, such as capecitabine, are widely used in the treatment of cancer, especially gastrointestinal tumors and breast cancer, but their administration can produce serious and even lethal toxicity. This toxicity is often related to the partial or complete deficiency of the dihydropyrimidine dehydrogenase (DPD) enzyme, which causes a reduction in clearance and a longer half-life of 5-FU. It is advisable to determine if a DPD deficiency exists before administering these drugs by genotyping DPYD gene polymorphisms. The objective of this consensus of experts, in which representatives from the Spanish Pharmacogenetics and Pharmacogenomics Society and the Spanish Society of Medical Oncology participated, is to establish clear recommendations for the implementation of genotype and/or phenotype testing for DPD deficiency in patients who are candidates to receive fluoropyrimidines. The genotyping of DPYD previous to treatment classifies individuals as normal, intermediate, or poor metabolizers. Normal metabolizers do not require changes in the initial dose, intermediate metabolizers should start treatment with fluoropyrimidines at doses reduced to 50%, and poor metabolizers are contraindicated for fluoropyrimidines

Modelling the mid-late Holocene evolution of the Huelva Estuary and its human colonization, South-Western Spain

The major changes that occurred in the southwestern estuaries of the Spanish Atlantic coast during the last 6500 yr BP were simultaneous to human settlement and therefore the understanding of their coastal evolution will help interpreting human patterns in these areas. The study of the morpho-sedimentary features of new outcrops appearing in the middle sector of Saltés Island (Huelva Estuary, Spain) has been used to develop a model to understand the complex evolution of sand barriers than can be applied to similar inlets along the Atlantic Iberian coast. The first human settlements (6000–4000 yr BP) in the early Huelva Estuary (Tinto and Odiel rivers) were located in the ancient coastal banks or in the nearby hills. From 4000 yr BP onwards, the estuarine sediments started to emerge as sand barriers and chenier plains, prograding towards the mouth. As the littoral strands stabilized morphologically, they were colonized by human settlements in successive periods, the oldest inland (Almendral) and more recent outward (Cascajera). The study of the upper sedimentary layers of La Cascajera barrier display a tempestitic sequence of landward progradational washover-fans. The calibrated and modelled AMS dates in marine shells provide a storminess time range between the second half of first century BCE and the entire first century CE. Sedimentary records are useful to evaluate environmental changes, either from natural or anthropogenic causes, such as global and climate change. The interrelationship between the archaeological findings (mainly salting fish factories and old ports) and the morpho sedimentary evolution at the mouth of the Tinto and Odiel rivers allows us to highlight not only the Huelva Estuary's dynamics evolution, but also the possible regional patterns of human habitation from the beginning of the present sea-level highstand (middle Holocene).Ministerio de Economía y Competitividad CGL2010-15810/BTEEuropean Union (UE) EU Excellence Project of the Andalusia Board SEJ-477

Stereoselective preparation of quaternary 2-vinyl sphingosines and ceramides and their effect on basal sphingolipid metabolism

The dicyclohexylborane-mediated addition of allene 1 to (E)-2-tridecenal affords a quaternary protected 2-amino-2-vinyl-1,3-diol in good yield as a single diastereomer. This compound is readily transformed into the four stereoisomers of the quaternary (E)-2-vinyl analogs of sphingosine. The metabolic fate and the effect of these compounds on the basal sphingolipid metabolism in human A549 lung adenocarcinoma cells has been studied, together with the ceramide analog of the most relevant vinylsphingosine derivative

Open access in Southern European countries

The Spanish Foundation for Science and Technology (FECYT) is a public foundation under the Spanish Ministry of Science and Innovation whose mission is to strengthen the value chain of knowledge by fostering science and innovation and trying to integrate them and bring them closer to society, in response to the needs and expectations of the Spanish science, technology and enterprise system. The Foundation’s goal is to be recognized by Spanish society as a key reference in the dissemination, information and measurement of science and innovation. It also wishes to contribute to the development of a knowledge-based economy. One of the main challenges of the Foundation is to lead the integration and rationalization of scientific information and science, technology and innovation metrics, described as the “integrate and measure vector” in its 2010- 2012 strategic plan. FECYT already has considerable experience in managing national scientific information. It is the national licensee of the Thomson Reuters Web of Knowledge accessed by the Spanish scientific community. It is also firmly committed to establishing itself as the Spanish hub in favour of the open access (OA) movement (for free access to scientific information available on the Internet), in combination with supporting the traditional markets of scientific information. In 2010 FECYT organized the 5th International Conference on Open Repositories in Madrid, with the aim of positioning Spain in the debate on emerging trends in the management of scientific information. The authorities are opening the door to the open access movement, under the belief that publicly funded research should be freely available. Among other initiatives, the 2010 Spanish Bill on Science, Technology and Innovation urges researchers to deposit their research papers produced with public funding in institutional repositories