Rapid deconvolution of low-resolution time-of-flight data using Bayesian inference

The deconvolution of low-resolution time-of-flight data has numerous advantages, including the ability to extract additional information from the experimental data. We augment the well-known Lucy-Richardson deconvolution algorithm using various Bayesian prior distributions and show that a prior of second-differences of the signal outperforms the standard Lucy-Richardson algorithm, accelerating the rate of convergence by more than a factor of four, while preserving the peak amplitude ratios of a similar fraction of the total peaks. A novel stopping criterion and boosting mechanism are implemented to ensure that these methods converge to a similar final entropy and local minima are avoided. Improvement by a factor of two in mass resolution allows more accurate quantification of the spectra. The general method is demonstrated in this paper through the deconvolution of fragmentation peaks of the 2,5-dihydroxybenzoic acid matrix and the benzyltriphenylphosphonium thermometer ion, following femtosecond ultraviolet laser desorption

High field CdS detector for infrared radiation

New and highly sensitive method of detecting infrared irradiation makes possible solid state infrared detector which is more sensitive near room temperature than usual photoconductive low band gap semiconductor devices. Reconfiguration of high field domains in cadmium sulphide crystals provides basis for discovery

Modification of the simple mass balance equation for calculation of critical loads of acidity.

Over the last few years, the simple mass balance equation for the calculation of critical loads of acidity has been gradually modified as the underlying critical load concepts have developed and as problems with particular forms of the equation have been identified, through application in particular countries. The first major update of the equation took place following a workshop held in Vienna, Austria (Hojesky et al. 1993). The workshop was held to discuss problems which had been identified when the then current form of the equation was applied in countries with high rainfall. The problems had largely arisen because of simplifications and assumptions incorporated into the early formulation of the equation. The equation was reformulated to overcome the problems identified at the workshop. However, further problems were identified when the reformulated equation was applied in the UK in situations with a combination of high rainfall, large marine inputs and widespread occurrence of organic soils. A small workshop was, therefore held in Grange-over-Sands, UK in late 1993 to dicuss the problems and to further re-evaluate the equation. The problems had arisen in the UK because of simplifications and assumptions made in the formulation concerning, in particular, cation leaching and uptake. As a result, a more rigorous treatment of these variables was incorporated into the equation. The reformulation of the equation, as derived at the September 1993 workshop is described below

Hybrid functional calculations of the Al impurity in silica: Hole localization and electron paramagnetic resonance parameters

We performed first-principle calculations based on the supercell and cluster approaches to investigate the neutral Al impurity in smoky quartz. Electron paramagnetic resonance measurements suggest that the oxygens around the Al center undergo a polaronic distortion which localizes the hole being on one of the four oxygen atoms. We find that the screened exchange hybrid functional successfully describes this localization and improves on standard local density approaches or on hybrid functionals that do not include enough exact exchange such as B3LYP. We find a defect level at about 2.5 eV above the valence band maximum, corresponding to a localized hole in a O 2p orbital. The calculated values of the g tensor and the hyperfine splittings are in excellent agreement with experiment.Comment: 5 pages, 2 figures, 1 tabl

Closed Trapped Surfaces in Cosmology

The existence of closed trapped surfaces need not imply a cosmological singularity when the spatial hypersurfaces are compact. This is illustrated by a variety of examples, in particular de Sitter spacetime admits many closed trapped surfaces and obeys the null convergence condition but is non-singular in the k=+1 frame.Comment: 11 pages. To appear in GRG, Vol 35 (August issue

Parent-only interventions in the treatment of childhood obesity: a systematic review of randomized controlled trials

Background An effective and cost-effective treatment is required for the treatment of childhood obesity. Comparing parent-only interventions with interventions including the child may help determine this. Methods A systematic review of published and ongoing studies until 2013, using electronic database and manual searches. Inclusion criteria: randomized controlled trials, overweight/obese children aged 5-12 years, parent-only intervention compared with an intervention that included the child, 6 months or more follow-up. Outcomes included measures of overweight. Results Ten papers from 6 completed studies, and 2 protocols for ongoing studies, were identified. Parent-only groups are either more effective than or similarly effective as child-only or parent-child interventions, in the change in degree of overweight. Most studies were at unclear risk of bias for randomization, allocation concealment and blinding of outcome assessors. Two trials were at high risk of bias for incomplete outcome data. Four studies showed higher dropout from parent-only interventions. One study examined programme costs and found parent-only interventions to be cheaper. Conclusions Parent-only interventions appear to be as effective as parent-child interventions in the treatment of childhood overweight/obesity, and may be less expensive. Reasons for higher attrition rates in parent-only interventions need further investigatio

THE WAIT-AND-SEE OPTION IN ASCENDING PRICE AUCTIONS

Cake-cutting protocols aim at dividing a ``cake'' (i.e., a divisible resource) and assigning the resulting portions to several players in a way that each of the players feels to have received a ``fair'' amount of the cake. An important notion of fairness is envy-freeness: No player wishes to switch the portion of the cake received with another player's portion. Despite intense efforts in the past, it is still an open question whether there is a \emph{finite bounded} envy-free cake-cutting protocol for an arbitrary number of players, and even for four players. We introduce the notion of degree of guaranteed envy-freeness (DGEF) as a measure of how good a cake-cutting protocol can approximate the ideal of envy-freeness while keeping the protocol finite bounded (trading being disregarded). We propose a new finite bounded proportional protocol for any number n \geq 3 of players, and show that this protocol has a DGEF of 1 + \lceil (n^2)/2 \rceil. This is the currently best DGEF among known finite bounded cake-cutting protocols for an arbitrary number of players. We will make the case that improving the DGEF even further is a tough challenge, and determine, for comparison, the DGEF of selected known finite bounded cake-cutting protocols.Comment: 37 pages, 4 figure