464 research outputs found
Ecological model of extinctions
We present numerical results based on a simplified ecological system in
evolution, showing features of extinction similar to that claimed for the
biosystem on Earth. In the model each species consists of a population in
interaction with the others, that reproduces and evolves in time. Each species
is simultaneously a predator and a prey in a food chain. Mutations that change
the interactions are supposed to occur randomly at a low rate. Extinctions of
populations result naturally from the predator-prey dynamics. The model is not
pinned in a fitness variable, and natural selection arises from the dynamics.Comment: 16 pages (LaTeX type, RevTeX style), including 6 figures in gif
format. To be published in Phys. Rev. E (prob. Dic. 96
CsI(Tl) for WIMP dark matter searches
We report a study of CsI(Tl) scintillator to assess its applicability in
experiments to search for dark matter particles. Measurements of the mean
scintillation pulse shapes due to nuclear and electron recoils have been
performed. We find that, as with NaI(Tl), pulse shape analysis can be used to
discriminate between electron and nuclear recoils down to 4 keV. However, the
discrimination factor is typically (10-15)% better than in NaI(Tl) above 4 keV.
The quenching factor for caesium and iodine recoils was measured and found to
increase from 11% to ~17% with decreasing recoil energy from 60 to 12 keV.
Based on these results, the potential sensitivity of CsI(Tl) to dark matter
particles in the form of neutralinos was calculated. We find an improvement
over NaI(Tl) for the spin independent WIMP-nucleon interactions up to a factor
of 5 assuming comparable electron background levels in the two scintillators.Comment: 16 pages, 8 figures, to be published in Nucl. Instrum. and Meth. in
Phys. Res.
Iridium-catalyzed C–H borylation of pyridines
The iridium-catalysed C–H borylation is a valuable and attractive method for the preparation of aryl and heteroaryl boronates. However, application of this methodology for the preparation of pyridyl and related azinyl boronates can be challenged by low reactivity and propensity for rapid protodeborylation, particularly for a boronate ester ortho to the azinyl nitrogen. Competition experiments have revealed that the low reactivity is due to inhibition of the active catalyst through coordination of the azinyl nitrogen lone pair at the vacant site on the iridium. This effect can be overcome through the incorporation of a substituent at C-2. Moreover, when this is sufficiently electron-withdrawing protodeborylation is sufficiently slowed to permit isolation and purification of the C-6 boronate ester. Following functionalization, reduction of the directing C-2 substituent provides the product arising from formal ortho borylation of an unhindered pyridine ring
Current status of turbulent dynamo theory: From large-scale to small-scale dynamos
Several recent advances in turbulent dynamo theory are reviewed. High
resolution simulations of small-scale and large-scale dynamo action in periodic
domains are compared with each other and contrasted with similar results at low
magnetic Prandtl numbers. It is argued that all the different cases show
similarities at intermediate length scales. On the other hand, in the presence
of helicity of the turbulence, power develops on large scales, which is not
present in non-helical small-scale turbulent dynamos. At small length scales,
differences occur in connection with the dissipation cutoff scales associated
with the respective value of the magnetic Prandtl number. These differences are
found to be independent of whether or not there is large-scale dynamo action.
However, large-scale dynamos in homogeneous systems are shown to suffer from
resistive slow-down even at intermediate length scales. The results from
simulations are connected to mean field theory and its applications. Recent
work on helicity fluxes to alleviate large-scale dynamo quenching, shear
dynamos, nonlocal effects and magnetic structures from strong density
stratification are highlighted. Several insights which arise from analytic
considerations of small-scale dynamos are discussed.Comment: 36 pages, 11 figures, Spa. Sci. Rev., submitted to the special issue
"Magnetism in the Universe" (ed. A. Balogh
Multicomponent powder injection molding as method for mass production, joining, and material development for tungsten armour materials
Volatile organic compound emissions from the oil and natural gas industry in the Uintah Basin, Utah: Oil and gas well pad emissions compared to ambient air composition
Emissions of volatile organic compounds (VOCs) associated with oil and
natural gas production in the Uintah Basin, Utah were measured at a ground
site in Horse Pool and from a NOAA mobile laboratory with PTR-MS instruments.
The VOC compositions in the vicinity of individual gas and oil wells and
other point sources such as evaporation ponds, compressor stations and
injection wells are compared to the measurements at Horse Pool. High mixing
ratios of aromatics, alkanes, cycloalkanes and methanol were observed for
extended periods of time and for short-term spikes caused by local point
sources. The mixing ratios during the time the mobile laboratory spent on the
well pads were averaged. High mixing ratios were found close to all point
sources, but gas well pads with collection and dehydration on the well pad
were clearly associated with higher mixing ratios than other wells. The
comparison of the VOC composition of the emissions from the oil and natural
gas well pads showed that gas well pads without dehydration on the well pad
compared well with the majority of the data at Horse Pool, and that oil well
pads compared well with the rest of the ground site data. Oil well pads on
average emit heavier compounds than gas well pads. The mobile laboratory
measurements confirm the results from an emissions inventory: the main VOC
source categories from individual point sources are dehydrators, oil and
condensate tank flashing and pneumatic devices and pumps. Raw natural gas is
emitted from the pneumatic devices and pumps and heavier VOC mixes from the
tank flashings
Measurement of the B0-anti-B0-Oscillation Frequency with Inclusive Dilepton Events
The - oscillation frequency has been measured with a sample of
23 million \B\bar B pairs collected with the BABAR detector at the PEP-II
asymmetric B Factory at SLAC. In this sample, we select events in which both B
mesons decay semileptonically and use the charge of the leptons to identify the
flavor of each B meson. A simultaneous fit to the decay time difference
distributions for opposite- and same-sign dilepton events gives ps.Comment: 7 pages, 1 figure, submitted to Physical Review Letter
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Instrumentation and Measurement Strategy for the NOAA SENEX Aircraft Campaign as Part of the Southeast Atmosphere Study 2013
Natural emissions of ozone-and-aerosol-precursor gases such as isoprene and monoterpenes are high in the southeast of the US. In addition, anthropogenic emissions are significant in the Southeast US and summertime photochemistry is rapid. The NOAA-led SENEX (Southeast Nexus) aircraft campaign was one of the major components of the Southeast Atmosphere Study (SAS) and was focused on studying the interactions between biogenic and anthropogenic emissions to form secondary pollutants. During SENEX, the NOAA WP-3D aircraft conducted 20 research flights between 27 May and 10 July 2013 based out of Smyrna, TN. Here we describe the experimental approach, the science goals and early results of the NOAA SENEX campaign. The aircraft, its capabilities and standard measurements are described. The instrument payload is summarized including detection limits, accuracy, precision and time resolutions for all gas-and-aerosol phase instruments. The inter-comparisons of compounds measured with multiple instruments on the NOAA WP-3D are presented and were all within the stated uncertainties, except two of the three NO2 measurements. The SENEX flights included day- and nighttime flights in the Southeast as well as flights over areas with intense shale gas extraction (Marcellus, Fayetteville and Haynesville shale). We present one example flight on 16 June 2013, which was a daytime flight over the Atlanta region, where several crosswind transects of plumes from the city and nearby point sources, such as power plants, paper mills and landfills, were flown. The area around Atlanta has large biogenic isoprene emissions, which provided an excellent case for studying the interactions between biogenic and anthropogenic emissions. In this example flight, chemistry in and outside the Atlanta plumes was observed for several hours after emission. The analysis of this flight showcases the strategies implemented to answer some of the main SENEX science questions
The management of diabetic ketoacidosis in children
The object of this review is to provide the definitions, frequency, risk factors, pathophysiology, diagnostic considerations, and management recommendations for diabetic ketoacidosis (DKA) in children and adolescents, and to convey current knowledge of the causes of permanent disability or mortality from complications of DKA or its management, particularly the most common complication, cerebral edema (CE). DKA frequency at the time of diagnosis of pediatric diabetes is 10%–70%, varying with the availability of healthcare and the incidence of type 1 diabetes (T1D) in the community. Recurrent DKA rates are also dependent on medical services and socioeconomic circumstances. Management should be in centers with experience and where vital signs, neurologic status, and biochemistry can be monitored with sufficient frequency to prevent complications or, in the case of CE, to intervene rapidly with mannitol or hypertonic saline infusion. Fluid infusion should precede insulin administration (0.1 U/kg/h) by 1–2 hours; an initial bolus of 10–20 mL/kg 0.9% saline is followed by 0.45% saline calculated to supply maintenance and replace 5%–10% dehydration. Potassium (K) must be replaced early and sufficiently. Bicarbonate administration is contraindicated. The prevention of DKA at onset of diabetes requires an informed community and high index of suspicion; prevention of recurrent DKA, which is almost always due to insulin omission, necessitates a committed team effort
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