Asymptotics of surface-plasmon redshift saturation at sub-nanometric separations

Many promising nanophotonics endeavours hinge upon the unique plasmonic properties of nanometallic structures with narrow non-metallic gaps, which support super-concentrated bonding modes that singularly redshift with decreasing separations. In this letter, we present a descriptive physical picture, complemented by elementary asymptotic formulae, of a nonlocal mechanism for plasmon-redshift saturation at subnanometric gap widths. Thus, by considering the electron-charge and field distributions in the close vicinity of the metal-vacuum interface, we show that nonlocality is asymptotically manifested as an effective potential discontinuity. For bonding modes in the near-contact limit, the latter discontinuity is shown to be effectively equivalent to a widening of the gap. As a consequence, the resonance-frequency near-contact asymptotics are a renormalisation of the corresponding local ones. Specifically, the renormalisation furnishes an asymptotic plasmon-frequency lower bound that scales with the $1/4$-power of the Fermi wavelength. We demonstrate these remarkable features in the prototypical cases of nanowire and nanosphere dimers, showing agreement between our elementary expressions and previously reported numerical computations

NLO QCD corrections to W+ W- b anti-b production with leptonic decays in the light of top quark mass and asymmetry measurements

We present the NLO QCD corrections to the processes p p and p anti-p to W+ W- b anti-b including leptonic decays of the W bosons. Non-resonant contributions as well as diagrams with doubly resonant and singly resonant top quark propagators are fully taken into account. We employ the narrow width approximation to perform the decays of the W bosons; spin correlations are however preserved. We also calculate observables relevant for top quark mass measurements, and study the impact of kinematical requirements and different scale choices on t anti-t asymmetries.Comment: 29 pages, 14 figures, version submitted to and accepted by JHE

Surface-plasmon resonances of arbitrarily shaped nanometallic structures in the small-screening-length limit

According to the hydrodynamic Drude model, surface-plasmon resonances of metallic nanostructures blueshift owing to the nonlocal response of the metal's electron gas. The screening length characterising the nonlocal effect is often small relative to the overall dimensions of the metallic structure, which enables us to derive a coarse-grained nonlocal description using matched asymptotic expansions; a perturbation theory for the blueshifts of arbitrary shaped nanometallic structures is then developed. The effect of nonlocality is not always a perturbation and we present a detailed analysis of the "bonding" modes of a dimer of nearly touching nanowires where the leading-order eigenfrequencies and eigenmode distributions are shown to be a renormalisation of those predicted assuming a local metal permittivity

Device and Physical Data Independence for Multimedia Presentations

Multimedia computing promises access to any type of visual or aural medium on the desktop. But in this networked future, will every type of media be accessible from every terminal device? Current multimedia standards do not allow content that is authored for high-bandwidth workstations to scale down for low-bandwidth applications. The problem is that application requests are commonly interpreted as requests for the highest possible quality and resource overloads are handled by ad hoc methods. We can begin to solve this problem by specifying Quality of Service (QOS) requirements based on functionality rather than on content encoding and device capabilities

Three-dimensional transient heat, mass, momentum, and species transfer in the stored grain ecosystem: Part I. Model development and evaluation

A 3D transient heat, mass, momentum, and species transfer model for the stored grain ecosystem was developed using the finite element method. Hourly weather data such as ambient temperature and relative humidity, solar radiation, and wind speed were used as input in the model. The 3D model has different components that predict grain temperature and moisture content, dry matter loss, insect population, and species (CO2 and fumigant) concentration. The 3D model was evaluated using linear elements with three different numbers of nodes and quadratic elements with three different numbers of nodes. The accuracy of prediction for each category was evaluated using the observed and predicted temperature values. The linear model with 384 nodes and the quadratic model with 415 nodes were found to be the best based on the lowest standard error compared to other combinations. Four different time discretization schemes were used to evaluate model accuracy over time. The Crank-Nicolson time discretization scheme was found to be the best of the four

Probing metal ion binding and conformational properties of the colicin E9 endonuclease by electrospray ionization time-of-flight mass spectrometry

Nano-electrospray ionization time-of-flight mass spectrometry (ESI-MS) was used to study the conformational consequences of metal ion binding to the colicin E9 endonuclease (E9 DNase) by taking advantage of the unique capability of ESI-MS to allow simultaneous assessment of conformational heterogeneity and metal ion binding. Alterations of charge state distributions on metal ion binding/release were correlated with spectral changes observed in far- and near-UV circular dichroism (CD) and intrinsic tryptophan fluorescence. In addition, hydrogen/deuterium (H/D) exchange experiments were used to probe structural integrity. The present study shows that ESI-MS is sensitive to changes of the thermodynamic stability of E9 DNase as a result of metal ion binding/release in a manner consistent with that deduced from proteolysis and calorimetric experiments. Interestingly, acid-induced release of the metal ion from the E9 DNase causes dramatic conformational instability associated with a loss of fixed tertiary structure, but secondary structure is retained. Furthermore, ESI-MS enabled the direct observation of the noncovalent protein complex of E9 DNase bound to its cognate immunity protein Im9 in the presence and absence of Zn2+. Gas-phase dissociation experiments of the deuterium-labeled binary and ternary complexes revealed that metal ion binding, not Im9, results in a dramatic exchange protection of E9 DNase in the complex. In addition, our metal ion binding studies and gas-phase dissociation experiments of the ternary E9 DNase-Zn2+-Im9 complex have provided further evidence that electrostatic interactions govern the gas phase ion stability

Electrically-tunable hole g-factor of an optically-active quantum dot for fast spin rotations

We report a large g-factor tunability of a single hole spin in an InGaAs quantum dot via an electric field. The magnetic field lies in the in-plane direction x, the direction required for a coherent hole spin. The electrical field lies along the growth direction z and is changed over a large range, 100 kV/cm. Both electron and hole g-factors are determined by high resolution laser spectroscopy with resonance fluorescence detection. This, along with the low electrical-noise environment, gives very high quality experimental results. The hole g-factor g_xh depends linearly on the electric field Fz, dg_xh/dFz = (8.3 +/- 1.2)* 10^-4 cm/kV, whereas the electron g-factor g_xe is independent of electric field, dg_xe/dFz = (0.1 +/- 0.3)* 10^-4 cm/kV (results averaged over a number of quantum dots). The dependence of g_xh on Fz is well reproduced by a 4x4 k.p model demonstrating that the electric field sensitivity arises from a combination of soft hole confining potential, an In concentration gradient and a strong dependence of material parameters on In concentration. The electric field sensitivity of the hole spin can be exploited for electrically-driven hole spin rotations via the g-tensor modulation technique and based on these results, a hole spin coupling as large as ~ 1 GHz is expected to be envisaged.Comment: 8 pages, 4 figure

Methylmalonic aciduria cblB type: characterization of two novel mutations and mitochondrial dysfunction studies

Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/111812/1/cge12426.pd