Engineering analysis and design of a mechanism to simulate a sonic boom

Mechanism simulating vibrational and acoustic properties of sonic boom

Utilization and Application of Business Computing Systems in Corporate Real Estate

This study reports on the utilization of business computing systems by corporate real estate executives. A survey was undertaken to examine four issues: types of property data collected, MIS report generation, hardware/software usage, and decision models and experts employed. NACORE members were surveyed and reported extensive usage of well-known business computing systems (e.g., transaction processing and management information systems), while newer systems (e.g., decision support and expert systems) are just beginning to be introduced into corporate real estate. Empirical analysis revealed differences among industries in the types of reports and property financial data that are maintained.

The Acquisition and Disposition of Real Estate by Corporate Executives: A Survey

Rising property values as well as corporate restructuring have given real estate greater importance in corporate asset management. Previous research has examined the capital budgeting procedures of corporations and institutional investors for real estate. However, these studies have not examined both the capital budgeting and disposition criteria used by service, retail, and manufacturing corporations for real estate. This study surveys the acquisition and disposition rules used by executives as well as the use of leasing. This survey covers the size of real estate investments, use of real property leasing, use of real estate sale/leaseback arrangements and the real estate asset acquisition and disposition criteria of corporations.

Mopra CO Observations of the Bubble HII Region RCW120

We use the Mopra radio telescope to test for expansion of the molecular gas associated with the bubble HII region RCW120. A ring, or bubble, morphology is common for Galactic HII regions, but the three-dimensional geometry of such objects is still unclear. Detected near- and far-side expansion of the associated molecular material would be consistent with a three-dimensional spherical object. We map the $J = 1\rightarrow 0$ transitions of $^{12}$CO, $^{13}$CO, C$^{18}$O, and C$^{17}$O, and detect emission from all isotopologues. We do not detect the $0_0\rightarrow 1_{-1} E$ masing lines of CH$_3$OH at 108.8939 GHz. The strongest CO emission is from the photodissociation region (PDR), and there is a deficit of emission toward the bubble interior. We find no evidence for expansion of the molecular material associated with RCW120 and therefore can make no claims about its geometry. The lack of detected expansion is roughly in agreement with models for the time-evolution of an HII region like RCW120, and is consistent with an expansion speed of $< 1.5\, {\rm km\, s^{-1}}$. Single-position CO spectra show signatures of expansion, which underscores the importance of mapped spectra for such work. Dust temperature enhancements outside the PDR of RCW120 coincide with a deficit of emission in CO, confirming that these temperature enhancements are due to holes in the RCW120 PDR. H$\alpha$ emission shows that RCW120 is leaking $\sim5\%$ of the ionizing photons into the interstellar medium (ISM) through PDR holes at the locations of the temperature enhancements. H-alpha emission also shows a diffuse "halo" from leaked photons not associated with discrete holes in the PDR. Overall $25\pm10\%$ of all ionizing photons are leaking into the nearby ISM.Comment: 35 pages, 14 figures. Accepted to Ap

Coordinated thermal and optical observations of Trans-Neptunian object (20000) Varuna from Sierra Nevada

We report on coordinated thermal and optical measurements of trans-Neptunian object (20000) Varuna obtained in January-February 2002, respectively from the IRAM 30-m and IAA 1.5 m telescopes. The optical data show a lightcurve with a period of 3.176+/-0.010 hr, a mean V magnitude of 20.37+/-0.08 and a 0.42+/-0.01 magnitude amplitude. They also tentatively indicate that the lightcurve is asymmetric and double-peaked. The thermal observations indicate a 1.12+/-0.41 mJy flux, averaged over the object's rotation. Combining the two datasets, we infer that Varuna has a mean 1060(+180/-220) km diameter and a mean 0.038(+0.022/-0.010) V geometric albedo, in general agreement with an earlier determination using the same technique.Comment: Accepted for publication in Astronomy & Astrophysics (7 pages, including 3 figures

Observations on the Formation of Massive Stars by Accretion

Observations of the H66a recombination line from the ionized gas in the cluster of newly formed massive stars, G10.6-0.4, show that most of the continuum emission derives from the dense gas in an ionized accretion flow that forms an ionized disk or torus around a group of stars in the center of the cluster. The inward motion observed in the accretion flow suggests that despite the equivalent luminosity and ionizing radiation of several O stars, neither radiation pressure nor thermal pressure has reversed the accretion flow. The observations indicate why the radiation pressure of the stars and the thermal pressure of the HII region are not effective in reversing the accretion flow. The observed rate of the accretion flow, 0.001 solar masses/yr, is sufficient to form massive stars within the time scale imposed by their short main sequence lifetimes. A simple model of disk accretion relates quenched HII regions, trapped hypercompact HII regions, and photo-evaporating disks in an evolutionary sequence

The representation of scientific research in the national curriculum and secondary school pupils’ perceptions of research, its function, usefulness and value to their lives

Young people’s views on what research is, how it is conducted and whether it is important, influences the decisions they make about their further studies and career choices. In this paper we report the analysis of questionnaire data with a particular focus on pupil perceptions of research in the sciences and of the scientific method. The questionnaire was a 25-item Likert Scale (1-5) distributed to seven collaborating schools. We received 2634 returns from pupils across key stages 3, 4 and 5. We also asked teachers to complete the questionnaire in order to explore how they thought their pupils would respond. We received 54 teacher responses. Statistically significant differences in the responses were identified through a chi-square test on SPSS. As what is being taught influences secondary pupil views on research we also consider how the term ‘research’ appears in the national curriculum for England and Wales and the three main English exam boards. The main theoretical construct that informs our analysis of the questionnaire data and the national curriculum is Angela Brew’s 4-tier descriptor of perceptions of research (domino, trading, layer, journey). We use this framework in order to map what, when and how research is presented to school pupils in England and Wales. We also use this framework in order to highlight and discuss certain pupil views that emerged from the questionnaire data and which indicate areas where curriculum and pedagogy intervention may be necessary: pupils seem less confident in their understanding of research as involving the identification of a research question; and, they often see research as a means to confirm one’s own opinion. They do however understand research as involving the generation of new knowledge and the collection of new data, such as interviews and questionnaires as well as laboratory work, field trips and library searches and they appear relatively confident in their statements about their ability to do research, their school experiences of research and the importance of research in their future career choice

The Financing of Corporate Real Estate: A Survey

The management of real estate assets owned by corporations has grown in importance over the past decade. Surveys have been published concerning the evaluation and decisionmaking in the leasing and purchasing of corporate assets. Little research, however, has been conducted to determine how executives finance real estate and the criteria used to make lease and purchase decisions. This study surveyed corporate real estate executives about the sources of funds to acquire real estate, the use and evaluation of leases, the use and evaluation of sale-leaseback arrangements and the use of tax-deferred exchanges of real property.

Charge and Spin Transfer Dynamics in a Weakly Coupled Porphyrin Dimer

The dynamics of electron and spin transfer in the radical cation and photogenerated triplet states of a tetramethylbiphenyl-linked zinc-porphyrin dimer were investigated, so as to test the relevant parameters for the design of a single-molecule spin valve and the creation of a novel platform for the photogeneration of high-multiplicity spin states. We used a combination of multiple techniques, including variable-temperature continuous wave EPR, pulsed proton electron–nuclear double resonance (ENDOR), transient EPR, and optical spectroscopy. The conclusions are further supported by density functional theory (DFT) calculations and comparison to reference compounds. The low-temperature cw-EPR and room-temperature near-IR spectra of the dimer monocation demonstrate that the radical cation is spatially localized on one side of the dimer at any point in time, not coherently delocalized over both porphyrin units. The EPR spectra at 298 K reveal rapid hopping of the radical spin density between both sites of the dimer via reversible intramolecular electron transfer. The hyperfine interactions are modulated by electron transfer and can be quantified using ENDOR spectroscopy. This allowed simulation of the variable-temperature cw-EPR spectra with a two-site exchange model and provided information on the temperature-dependence of the electron transfer rate. The electron transfer rates range from about 10.0 MHz at 200 K to about 53.9 MHz at 298 K. The activation enthalpies Δ‡ H of the electron transfer were determined as Δ‡ H = 9.55 kJ mol–1 and Δ‡ H = 5.67 kJ mol–1 in a 1:1:1 solvent mixture of CD2Cl2/toluene-d 8/THF-d 8 and in 2-methyltetrahydrofuran, respectively, consistent with a Robin–Day class II mixed valence compound. These results indicate that the interporphyrin electronic coupling in a tetramethylbiphenyl-linked porphyrin dimer is suitable for the backbone of a single-molecule spin valve. Investigation of the spin density distribution of the photogenerated triplet state of the Zn-porphyrin dimer reveals localization of the triplet spin density on a nanosecond time scale on one-half of the dimer at 20 K in 2-methyltetrahydrofuran and at 250 K in a polyvinylcarbazole film. This establishes the porphyrin dimer as a molecular platform for the formation of a localized, photogenerated triplet state on one porphyrin unit that is coupled to a second redox-active, ground-state porphyrin unit, which can be explored for the formation of high-multiplicity spin states