2,141 research outputs found

    A List of Wisconsin Springtails With New Records and Annotations (Hexapoda: Parainsecta: Collembola)

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    Twenty Collembola species new to Wisconsin were collected from soil at two agricultural sites in southern Wisconsin, including an undescribed species of Isotomidae. The state faunal list now contains 52 species representing seven families

    Slow on the Fast Track: A Mindful Oath to Management and a Ph.D. Survival Guide

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    As an entrepreneur, instructor, and new mother, becoming a student again was no easy task. It was important for me to find the right balance to energize my pursuit of learning, nurture my young family, and attend to work obligations all while achieving doctoral program outcomes. I could not conceive of program expectations thoroughly enough to prepare. Yet, by investing time to make a plan and establish routines, tools, and techniques at the onset, I managed obligations effectively and efficiently. My plan translated into a mindfulness routine that maintained consistent levels of motivation, and inspired me to apply methods to help me succeed. Drawing on my doctoral experiences and empirical research in mindfulness and motivation, this article illustrates approaches to assist students with managing personal, professional, and scholastic expectations. By dedicating time to be mindful and cultivating a mindset to manage priorities, students can engage in a healthy pursuit of learning and achievement, and strengthen their human potential

    Habitat structure: a fundamental concept and framework for urban soil ecology

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    Habitat structure is defined as the composition and arrangement of physical matter at a location. Although habitat structure is the physical template underlying ecological patterns and processes, the concept is relatively unappreciated and underdeveloped in ecology. However, it provides a fundamental concept for urban ecology because human activities in urban ecosystems are often targeted toward management of habitat structure. In addition, the concept emphasizes the fine-scale, on-the-ground perspective needed in the study of urban soil ecology. To illustrate this, urban soil ecology research is summarized from the perspective of habitat structure effects. Among the key conclusions emerging from the literature review are: (1) habitat structure provides a unifying theme for multivariate research about urban soil ecology; (2) heterogeneous urban habitat structures influence soil ecological variables in different ways; (3) more research is needed to understand relationships among sociological variables, habitat structure patterns and urban soil ecology. To stimulate urban soil ecology research, a conceptual framework is presented to show the direct and indirect relationships among habitat structure and ecological variables. Because habitat structure serves as a physical link between sociocultural and ecological systems, it can be used as a focus for interdisciplinary and applied research (e.g., pest management) about the multiple, interactive effects of urbanization on the ecology of soils

    Case report: Transcervical approach for removal of the tumor of the primary parapharyngeal space (PPS)

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    Tumors of the primary parapharyngeal space (PPS) account for less than 1% of all head and neck tumors. Because of the asymptomatic aspect of the disease, PPS tumors are usually detected in the advanced stage. In this case report, we present rare a PPS tumor and itstreatment

    A Quantitative Study of the Effects of Guest Flexibility on Binding Inside a Coordination Cage Host.

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    We have performed a systematic investigation of the effects of guest flexibility on their ability to bind in the cavity of a coordination cage host in water, using two sets of isomeric aliphatic ketones that differ only in the branching patterns of their alkyl chains. Apart from the expected increase in binding strength for C9 over C7 ketones associated with their greater hydrophobic surface area, within each isomeric set there is a clear inverse correlation between binding free energy and guest flexibility, associated with loss of conformational entropy. This can be parameterized by the number of rotatable C-C bonds in the guest, with each additional rotatable bond resulting in a penalty of around 2 kJ mol(-1) in the binding free energy, in good agreement with values obtained from protein/ligand binding studies. We used the binding data for the new flexible guests to improve the scoring function that we had previously developed that allowed us to predict binding constants of relatively rigid guests in the cage cavity using the molecular docking programme GOLD (Genetic Optimisation of Ligand Docking). This improved scoring function resulted in a significant improvement in the ability of GOLD to predict binding constants for flexible guests, without any detriment to its ability to predict binding for more rigid guests

    One-pot synthesis and AFM imaging of a triangular aramide macrocycle

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    Macrocyclizations in exceptionally good yields were observed during the self-condensation of N-benzylated phenyl p-aminobenzoates in the presence of LiHMDS to yield three-membered cyclic aramides that adopt a triangular shape. An ortho-alkyloxy side chain on the N-benzyl protecting group is necessary for the macrocyclization to occur. Linear polymers are formed exclusively in the absence of this Li-chelating group. A model that explains the lack of formation of other cyclic congeners and the demand for an N-(o-alkoxybenzyl) protecting group is provided on the basis of DFT calculations. High-resolution AFM imaging of the prepared molecular triangles on a calcite(10.4) surface shows individual molecules arranged in groups of four due to strong surface templating effects and hydrogen bonding between the molecular triangles
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