Simulation-aided design of tubular polymeric capsules for self-healing concrete

Polymeric capsules can have an advantage over glass capsules used up to now as proof-of-concept carriers in self-healing concrete. They allow easier processing and afford the possibility to fine tune their mechanical properties. Out of the multiple requirements for capsules used in this context, the capability of rupturing when crossed by a crack in concrete of a typical size is one of the most relevant, as without it no healing agent is released into the crack. This study assessed the fitness of five types of polymeric capsules to fulfill this requirement by using a numerical model to screen the best performing ones and verifying their fitness with experimental methods. Capsules made of a specific type of poly(methyl methacrylate) (PMMA) were considered fit for the intended application, rupturing at average crack sizes of 69 and 128 μm, respectively for a wall thickness of ~0.3 and ~0.7 mm. Thicker walls were considered unfit, as they ruptured for crack sizes much higher than 100 μm. Other types of PMMA used and polylactic acid were equally unfit for the same reason. There was overall good fitting between model output and experimental results and an elongation at break of 1.5% is recommended regarding polymers for this application

Développement de compositions polymères biosourcées sur base PLA pour des applications automobiles

National audiencePLA is a bio-based and biodegradable polymer with high tensile strength and rigidity. Nevertheless, its low impact toughness and its brittleness are obstacles for a use in highly loaded parts. To overcome these drawbacks, the influence of several additives is studied. First of all, PLA plasticization by TBC leads to a marked increase of ductility, however counterbalanced by a drop of tensile strength and rigidity. The formation of copolymers PLA-impact modifier (BS) allows to increase impact toughness but not ductility. Finally, quaternary compositions PLA-BS-TBC-clay nano-reinforcements have interesting tensile and impact properties compared to a mineral filled PP frequently used for automotive applications.Le PLA est un polymère biosourcé, biodégradable et à hautes rigidité et résistance en traction. Toutefois, sa faible résilience et sa fragilité sont des obstacles à son utilisation pour des pièces fortement sollicitées. Pour y remédier, cette étude s'intéresse à l'enrichissement progressif de compositions à base de PLA. Dans un premier temps, l'ajout de plastifiant (TBC) permet une nette augmentation de la ductilité du matériau, mais dégrade les autres propriétés en traction. La formation de copolymères PLA-modificateur d'impact (BS) permet un fort accroissement de la résilience, mais pas de la ductilité. Enfin, les compositions quaternaires PLA-BS-TBC-nanocharges d'argile constituent une piste viable pour une utilisation sous fortes sollicitations, grâce à des propriétés mécaniques en traction et à l'impact prometteuses, comparées à celles d'un PP chargé, classiquement utilisé dans l'automobile

Reactive melt crosslinking of cellulose nanocrystals/poly(ε-caprolactone) for heat-shrinkable network

Focusing on the challenge of non-biodegradable plastics replacement, we propose a design for peroxide-initiated crosslinking of biodegradable poly(ε-caprolactone) (PCL) and renewable cellulose nanocrystals (CNCs) bionanocomposites. An industrially scalable water-assisted reactive melt-processing (REx) is studied to explore the hypothesis of synergy between simultaneous effects of water on improving CNC dispersion and boosting PCL branching/crosslinking. We demonstrate that the melt processing control enables the preparation of targeted thermoplastic/thermoset bionanocomposites with gel content up to ≈ 40 %, identified as the limit of their melt-processability. Structural characterization reveals that ≈ 70 wt% of the initial CNC content is irreversibly incorporated in a percolating network, enhancing the crosslinked bionanocomposites properties. The bionanocomposites\u27 complex viscosity and elastic character increase with the gel content, thus improving PCL melt performance. Furthermore, the irreversible entrapment of CNCs in the 3D percolating network provides heat-shrinkability, indicating a potential of the reacted bionanocomposites for heat-triggered shape-memory

Interphase Design of Cellulose Nanocrystals/Poly(hydroxybutyrate- ran-valerate) Bionanocomposites for Mechanical and Thermal Properties Tuning

Poly[(3-hydroxybutyrate)-ran-(3-hydroxyvalerate)] (PHBV) is a bacterial polyester with a strong potential as a substitute for oil-based thermoplastics due to its biodegradability and renewability. However, its inherent slow crystallization rate limits its thermomechanical properties and therefore its applications. In this work, surface-modified cellulose nanocrystals (CNCs) have been investigated as green and biosourced nucleating and reinforcing agent for PHBV matrix. Different ester moieties from the CNCs were thereby produced through a green one-pot hydrolysis/Fisher esterification. Beyond the improved dispersion, the CNCs surface esterification affected the thermal and thermomechanical properties of PHBV. The results demonstrate that butyrate-modified CNCs, mimicking the PHBV chemical structure, brought a considerable improvement toward the CNCs/matrix interface, leading to an enhancement of the PHBV thermomechanical properties via a more efficient stress transfer, especially above its glass transition

Green Topochemical Esterification Effects on the Supramolecular Structure of Chitin Nanocrystals: Implications for Highly Stable Pickering Emulsions

In nature, chitin is organized in hierarchical structures composed of nanoscale building blocks that show outstanding mechanical and optical properties attractive for nanomaterial design. For applications that benefit from a maximized interface such as nanocomposites and Pickering emulsions, individualized chitin nanocrystals (ChNCs) are of interest. However, when extracted in water suspension, their individualization is affected by ChNC self-assembly, requiring a large amount of water (above 90%) for ChNC transport and stock, which limits their widespread use. To master their individualization upon drying and after regeneration, we herein report a waterborne topochemical one-pot acid hydrolysis/Fischer esterification to extract ChNCs from chitin and simultaneously decorate their surface with lactate or butyrate moieties. Controlled reaction conditions were designed to obtain nanocrystals of a comparable aspect ratio of about 30 and a degree of modification of about 30% of the ChNC surface, under the rationale to assess the only effect of the topochemistry on ChNC supramolecular organization. The rheological analysis coupled with polarized light imaging shows how the nematic structuring is hindered by both surface ester moieties. The increased viscosity and elasticity of the modified ChNC colloids indicate a gel-like phase, where typical ChNC clusters of liquid crystalline phases are disrupted. Pickering emulsions have been prepared from lyophilized nanocrystals as a proof of concept. Our results demonstrate that only the emulsions stabilized by the modified ChNCs have excellent stability over time, highlighting that their individualization can be regenerated from the dry state