Root Cause Failure Analysis for Machinery and Piping Part 1: Introduction to RCFA

Short Cours

Electrolyte Coatings for High Adhesion Interfaces in Solid-state Batteries from First Principles

We introduce an adhesion parameter that enables rapid screening for materials interfaces with high adhesion. This parameter is obtained by density functional theory calculations of individual single-material slabs rather than slabs consisting of combinations of two materials, eliminating the need to calculate all configurations of a prohibitively vast space of possible interface configurations. Cleavage energy calculations are used as an upper bound for electrolyte and coating energies and implemented in an adapted contact angle equation to derive the adhesion parameter. In addition to good adhesion, we impose further constraints in electrochemical stability window, abundance, bulk reactivity, and stability to screen for coating materials for next-generation solid-state batteries. Good adhesion is critical in combating delamination and resistance to Lithium diffusivity in solid-state batteries. Here, we identify several promising coating candidates for the Li7La3Zr2O12 and sulfide electrolyte systems including the previously investigated electrode coating materials LiAlSiO4 and Li5AlO8, making them especially attractive for experimental optimization and commercialization

Discovery of a New Transient Magnetar Candidate: XTE J1810-197

We report the discovery of a new X-ray pulsar, XTE J1810-197. The source was serendipitously discovered on 2003 July 15 by the Rossi X-ray Timing Explorer (RXTE) while observing the soft gamma repeater SGR 1806-20. The pulsar has a 5.54 s spin-period and a soft spectrum (photon index ~ 4). We detect the source in earlier RXTE observations back to 2003 January. These show that a transient outburst began between 2002 November 17 and 2003 January 23 and that the pulsar has been spinning down since then, with a high rate Pdot ~ 10^-11 s/s showing significant timing noise, but no evidence for Doppler shifts due to a binary companion. The rapid spin-down rate and slow spin-period imply a super-critical magnetic field B=3x10^14 G and a young characteristic age < 7600 yr. These properties are strikingly similar to those of anomalous X-ray pulsars and soft gamma repeaters, making the source a likely new magnetar. A follow-up Chandra observation provided a 2".5 radius error circle within which the 1.5 m Russian-Turkish Optical Telescope RTT150 found a limiting magnitude of R_c=21.5, in accord with other recently reported limits. The source is present in archival ASCA and ROSAT data as well, at a level 100 times fainter than the \~ 3 mCrab seen in 2003. This suggests that other X-ray sources that are currently in a state similar to the inactive phase of XTE J1810-197 may also be unidentified magnetars awaiting detection via a similar activity.Comment: Submitted to ApJL; 4 pages; 4 figure

Nitrogen Fertilization and Glyphosate-Resistant Alfalfa Termination Method Effects on First-Year Silage Corn

Tillage type/timing and herbicide application date may change the amount and timing of N mineralization, altering fertilizer N needs for first-year corn (Zea mays L.) following glyphosate [N-(phosphonomethyl)glycine]-resistant (GR) alfalfa (Medicago sativa L.). Studies were conducted in 2012 and 2013 in Utah. Yield, quality, and economic return of silage corn as affected by five tillage type/timings (fall conventional till, spring conventional till, fall strip-till, spring strip-till, and no-till), three herbicide application dates for alfalfa termination (fall, spring, and in-crop), and four N rates (0, 56, 112, and 224 kg ha−1) were evaluated. Silage corn yield and quality following GR alfalfa was economically optimized without N fertilization regardless of tillage type/timing and herbicide application date. Thus, N from decomposing alfalfa can provide the full N requirement of first-year silage corn following GR alfalfa. Estimated animal milk production ha−1 of silage corn was greatest and similar for all herbicide application dates with conventional tillage and spring herbicide application with strip-till and no-till (26–38 Mg milk ha−1), whereas an in-crop herbicide application with strip-till and no-till resulted in the lowest estimated milk production (21–29 Mg milk ha−1). Increased economic return for the in-crop herbicide date by including economics from harvesting the first alfalfa cutting before planting corn mostly offset the reduced economic return of the lower silage corn yield. Therefore, an application of 2,4-D (2,4-dichlorophenoxyacetic acid) and dicamba (3,6-dichloro-2-methoxybenzoic acid) in the fall, spring, or in-crop to control GR alfalfa are good economic options for conventional tillage, strip-till, and no-till systems

A mobile ecology of resources for Covid-19 learning

Mobile devices and a vast array of accompanying applications offer significant affordances to create, consume, share, collaborate and communicate—affordances that could be easily leveraged to facilitate meaningful learning. A positive disruption arising from Covid-19 that aligns with the affordances of mobile learning is the uncoupling of time and space in the learning process. Traditionally formal learning is a process that is predominately viewed as an experience that is ‘timetabled’— scheduled to eventuate at a ‘place’—lecture or a tutorial (or similar) in a room or lecture theatre. In this concise paper, an ecology of resources is discussed along with guiding principles for designing and facilitating uncoupled authentic and student-determined learning post the emergency remote teaching phase

Finding short GRB remnants in globular clusters: the VHE gamma-ray source in Terzan 5

Globular cluster are believed to boost the rate of compact binary mergers which may launch a certain type of cosmological gamma-ray bursts (GRBs). Therefore globular clusters appear to be potential sites to search for remnants of such GRBs. The very-high-energy (VHE) gamma-ray source HESS J1747-248 recently discovered in the direction of the Galactic globular cluster Terzan 5 is investigated for being a GRB remnant. Signatures created by the ultra-relativistic outflow, the sub-relativistic ejecta and the ionizing radiation of a short GRB are estimated for an expected age of such a remnant of t > 10^4 years. The kinetic energy of a short GRB could roughly be adequate to power the VHE source in a hadronic scenario. The age of the proposed remnant estimated from its extension possibly agrees with the occurrence of such events in the Galaxy. Sub-relativistic merger ejecta could shock-heat the ambient medium. Further VHE observations can probe the presence of a break towards lower energies expected for particle acceleration in ultra-relativistic shocks. Deep X-ray observations would have the potential to examine the presence of thermal plasma heated by the sub-relativistic ejecta. The identification of a GRB remnant in our own Galaxy may also help to explore the effect of such a highly energetic event on the Earth.Comment: 4 pages, accepted for publication in A&A Letter

Anemia is an independent risk for mortality after acute myocardial infarction in patients with and without diabetes

INTRODUCTION: Anemia and diabetes are risk factors for short-term mortality following an acute myocardial infarction(AMI). Anemia is more prevalent in patients with diabetes. We performed a retrospective study to assess the impact of the combination of diabetes and anemia on post-myocardial infarction outcomes. METHODS: Data relating to all consecutive patients hospitalized with AMI was obtained from a population-based disease-specific registry. Patients were divided into 4 groups: diabetes and anemia (group A, n = 716), diabetes and no anemia (group B, n = 1894), no diabetes and anemia (group C, n = 869), and no diabetes and no anemia (group D, n = 3987). Mortality at 30 days and 31 days to 36 months were the main outcome measures. RESULTS: 30-day mortality was 32.3% in group A, 16.1% in group B, 21.5% in group C, 6.6% in group D (all p < 0.001). 31-day to 36-month mortality was 47.6% in group A, 20.8% in group B, 34.3% in group C, and 10.4% in group D (all p < 0.001). Diabetes and anemia remained independent risk factors for mortality with odds ratios of 1.61 (1.41–1.85, p < 0.001) and 1.59 (1.38–1.85, p < 0.001) respectively at 36 months. Cardiovascular death from 31-days to 36-months was 43.7% of deaths in group A, 54.1% in group B, 47.0% in group C, 50.8% group D (A vs B, p < 0.05). INTERPRETATION: Patients with both diabetes and anemia have a significantly higher mortality than those with either diabetes or anemia alone. Cardiovascular death remained the most likely cause of mortality in all groups

Large High-precision X-Ray Timing of Three Millisecond Pulsars with NICER: Stability Estimates and Comparison with Radio

The Neutron Star Interior Composition Explorer (NICER) is an X-ray astrophysics payload on the International Space Station. It enables unprecedented high-precision timing of millisecond pulsars (MSPs) without the pulse broadening and delays due to dispersion and scattering within the interstellar medium that plague radio timing. We present initial timing results from a year of data on the MSPs PSR B1937+21 and PSR J0218+4232, and nine months of data on PSR B1821-24. NICER time-of-arrival uncertainties for the three pulsars are consistent with theoretical lower bounds and simulations based on their pulse shape templates and average source and background photon count rates. To estimate timing stability, we use the sigma(z) measure, which is based on the average of the cubic coefficients of polynomial fits to subsets of timing residuals. So far we are achieving timing stabilities sigma(z) approximate to 3 x 10(-14) for PSR B1937+21 and on the order of 10 (-12) for PSRs B1821-24 and J0218+4232. Within the span of our NICER data we do not yet see the characteristic break point in the slope of sigma(z); detection of such a break would indicate that further improvement in the cumulative root-mean-square timing residual is limited by timing noise. We see this break point in our comparison radio data sets for PSR B1821-24 and PSR B1937+21 on timescales of 2 yr

HCO3(-)-independent pH regulation in astrocytes in situ is dominated by V-ATPase.

The mechanisms of HCO3(-)-independent intracellular pH (pHi) regulation were examined in fibrous astrocytes within isolated neonatal rat optic nerve (RON) and in cultured cortical astrocytes. In agreement with previous studies, resting pHi in cultured astrocytes was 6.82 ± 0.06 and inhibition of the V-ATPase H(+) pump by Cl(-) removal or via the selective inhibitor bafilomycin had only a small effect upon resting pHi and recovery following an acid load. In contrast, resting pHi in RON astrocytes was 7.10 ± 0.04, significantly less acidic than that in cultured cells (p < 0.001), and responded to inhibition of V-ATPase with profound acidification to the 6.3-6.5 range. Fluorescent immuno-staining and immuno-gold labeling confirmed the presence V-ATPase in the cell membrane of RON astrocyte processes and somata. Using ammonia pulse recovery, pHi recovery in RON astrocyte was achieved largely via V-ATPase with sodium-proton exchange (NHE) playing a minor role. The findings indicate that astrocytes in a whole-mount preparation such as the optic nerve rely to a greater degree upon V-ATPase for HCO3(-)-independent pHi regulation than do cultured astrocytes, with important functional consequences for the regulation of pH in the CNS