Systematic characterization of thermodynamic and dynamical phase behavior in systems with short-ranged attraction

In this paper we demonstrate the feasibility and utility of an augmented version of the Gibbs ensemble Monte Carlo method for computing the phase behavior of systems with strong, extremely short-ranged attractions. For generic potential shapes, this approach allows for the investigation of narrower attractive widths than those previously reported. Direct comparison to previous self-consistent Ornstein-Zernike approximation calculations are made. A preliminary investigation of out-of-equilibrium behavior is also performed. Our results suggest that the recent observations of stable cluster phases in systems without long-ranged repulsions are intimately related to gas-crystal and metastable gas-liquid phase separation.Comment: 10 pages, 8 figure

Nonlinearities and Effects of Transverse Beam Size in Beam Position Monitors (revised)

The fields produced by a long beam with a given transverse charge distribution in a homogeneous vacuum chamber are studied. Signals induced by a displaced finite-size beam on electrodes of a beam position monitor (BPM) are calculated and compared to those produced by a pencil beam. The non-linearities and corrections to BPM signals due to a finite transverse beam size are calculated for an arbitrary chamber cross section. Simple analytical expressions are given for a few particular transverse distributions of the beam current in a circular or rectangular chamber. Of particular interest is a general proof that in an arbitrary homogeneous chamber the beam-size corrections vanish for any axisymmetric beam current distribution.Comment: REVTeX, 8 pages, 9 figures. Corrected Eqs. (7),(22),(25) and Figs. 2-9. Expande

A Simulation Method to Resolve Hydrodynamic Interactions in Colloidal Dispersions

A new computational method is presented to resolve hydrodynamic interactions acting on solid particles immersed in incompressible host fluids. In this method, boundaries between solid particles and host fluids are replaced with a continuous interface by assuming a smoothed profile. This enabled us to calculate hydrodynamic interactions both efficiently and accurately, without neglecting many-body interactions. The validity of the method was tested by calculating the drag force acting on a single cylindrical rod moving in an incompressible Newtonian fluid. This method was then applied in order to simulate sedimentation process of colloidal dispersions.Comment: 7pages, 7 figure

LONTalk as a Standard Protocol For Underwater Sensor Platforms

Proceedings IEEE, Oceans 97, Halifax, Oct. 1997 IEEE CD-ROM 0-7803-4111-

An order parameter equation for the dynamic yield stress in dense colloidal suspensions

We study the dynamic yield stress in dense colloidal suspensions by analyzing the time evolution of the pair distribution function for colloidal particles interacting through a Lennard-Jones potential. We find that the equilibrium pair distribution function is unstable with respect to a certain anisotropic perturbation in the regime of low temperature and high density. By applying a bifurcation analysis to a system near the critical state at which the stability changes, we derive an amplitude equation for the critical mode. This equation is analogous to order parameter equations used to describe phase transitions. It is found that this amplitude equation describes the appearance of the dynamic yield stress, and it gives a value of 2/3 for the shear thinning exponent. This value is related to the mean field value of the critical exponent $\delta$ in the Ising model.Comment: 8 pages, 2 figure

Embedding the concept of ecosystems services:The utilisation of ecological knowledge in different policy venues

The concept of ecosystem services is increasingly being promoted by academics and policy makers as a means to protect ecological systems through more informed decision making. A basic premise of this approach is that strengthening the ecological knowledge base will significantly enhance ecosystem health through more sensitive decision making. However, the existing literature on knowledge utilisation, and many previous attempts to improve decision making through better knowledge integration, suggest that producing ‘more knowledge’ is only ever a necessary but insufficient condition for greater policy success. We begin this paper by reviewing what is already known about the relationship between ecological knowledge development and utilisation, before introducing a set of theme issue papers that examine—for the very first time—how this politically and scientifically salient relationship plays out across a number of vital policy venues such as land-use planning, policy-level impact assessment, and cost–benefit analysis. Following a detailed synthesis of the key findings of all the papers, this paper identifies and explores new research and policy challenges in this important and dynamic area of environmental governance

Dynamics of Post-Injection Fuel Flow in Mini-Sac Diesel Injectors Part 1: Admission of 1 External Gases and Implications for Deposit Formation

Samples of unadditized, middle distillate diesel fuel were injected through real-size optically accessible mini-sac diesel injectors into ambient air at common rail pressures of 250 bar and 350 bar respectively. High-resolution images of white light scattered from the internal mini-sac and nozzle flow were captured on a high-speed monochrome video camera. Following the end of each injection, the momentum-driven evacuation of fuel liquid from the mini-sac and nozzle holes resulted in the formation of a vapour cloud and bubbles in the mini-sac, and vapour capsules in the nozzle holes. This permitted external gas to gain entrance to the nozzle holes. The diesel fuel in the mini-sac was observed to rotate with large initial vorticity, which decayed until the fuel became stationary. The diesel fuel remaining in the nozzle holes was observed to move inwards towards the mini-sac or outwards towards the nozzle exit in concert with the rotational flow in the mini-sac. The mini-sac bubbles’ internal pressure differences revealed that the bubbles must have contained previously dissolved oxygen and nitrogen. Under diesel engine operating conditions, this multi-phase mixture would be highly reactive and could initiate local pyrolysis and/or oxidation reactions. Finally, the dynamical behaviour of the diesel fuel in the nozzle holes would support the admission of external hot combustion gases into the nozzle holes, establishing the conditions for oxidation/pyrolysis reactions with surrounding liquid fuel films

Acoustic-Structure Interaction in Rocket Engines: Validation Testing

While analyzing a rocket engine component, it is often necessary to account for any effects that adjacent fluids (e.g., liquid fuels or oxidizers) might have on the structural dynamics of the component. To better characterize the fully coupled fluid-structure system responses, an analytical approach that models the system as a coupled expansion of rigid wall acoustic modes and in vacuo structural modes has been proposed. The present work seeks to experimentally validate this approach. To experimentally observe well-coupled system modes, the test article and fluid cavities are designed such that the uncoupled structural frequencies are comparable to the uncoupled acoustic frequencies. The test measures the natural frequencies, mode shapes, and forced response of cylindrical test articles in contact with fluid-filled cylindrical and/or annular cavities. The test article is excited with a stinger and the fluid-loaded response is acquired using a laser-doppler vibrometer. The experimentally determined fluid-loaded natural frequencies are compared directly to the results of the analytical model. Due to the geometric configuration of the test article, the analytical model is found to be valid for natural modes with circumferential wave numbers greater than four. In the case of these modes, the natural frequencies predicted by the analytical model demonstrate excellent agreement with the experimentally determined natural frequencies

Structure and dynamics of colloidal depletion gels: coincidence of transitions and heterogeneity

Transitions in structural heterogeneity of colloidal depletion gels formed through short-range attractive interactions are correlated with their dynamical arrest. The system is a density and refractive index matched suspension of 0.20 volume fraction poly(methyl methacyrlate) colloids with the non-adsorbing depletant polystyrene added at a size ratio of depletant to colloid of 0.043. As the strength of the short-range attractive interaction is increased, clusters become increasingly structurally heterogeneous, as characterized by number-density fluctuations, and dynamically immobilized, as characterized by the single-particle mean-squared displacement. The number of free colloids in the suspension also progressively declines. As an immobile cluster to gel transition is traversed, structural heterogeneity abruptly decreases. Simultaneously, the mean single-particle dynamics saturates at a localization length on the order of the short-range attractive potential range. Both immobile cluster and gel regimes show dynamical heterogeneity. Non-Gaussian distributions of single particle displacements reveal enhanced populations of dynamical trajectories localized on two different length scales. Similar dependencies of number density fluctuations, free particle number and dynamical length scales on the order of the range of short-range attraction suggests a collective structural origin of dynamic heterogeneity in colloidal gels.Comment: 14 pages, 10 figure