69 research outputs found
On the verge of Umdeutung in Minnesota: Van Vleck and the correspondence principle (Part One)
In October 1924, the Physical Review, a relatively minor journal at the time,
published a remarkable two-part paper by John H. Van Vleck, working in virtual
isolation at the University of Minnesota. Van Vleck combined advanced
techniques of classical mechanics with Bohr's correspondence principle and
Einstein's quantum theory of radiation to find quantum analogues of classical
expressions for the emission, absorption, and dispersion of radiation. For
modern readers Van Vleck's paper is much easier to follow than the famous paper
by Kramers and Heisenberg on dispersion theory, which covers similar terrain
and is widely credited to have led directly to Heisenberg's "Umdeutung" paper.
This makes Van Vleck's paper extremely valuable for the reconstruction of the
genesis of matrix mechanics. It also makes it tempting to ask why Van Vleck did
not take the next step and develop matrix mechanics himself.Comment: 82 page
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PORE SIZE AND GROWTH KINETICS IN GLASSY CARBON USING SMALL ANGLE X-RAY SCATTERING
Visualisierungsprozeduren diskontinuierlicher Erregungsausbreitung in mikroskopischen Dimensionen
Deactivation processes in isolated aromatic heterocycles and pyrenes
In der vorliegenden Arbeit wurde erfolgreich eine neue Gasphasen-Apparatur fĂŒr
Photoelektronen-Imaging-Experimente simuliert, aufgebaut und in Verbindung mit einem ps-Lasersystem in Betrieb genommen.
Neben dem Aufbau der Apparatur stand die AufklĂ€rung der Dynamik angeregter ZustĂ€nde von aromatischen Heterocyclen und Pyrenen im Fokus dieser Arbeit. Die untersuchten MolekĂŒle wurden durch ResonanzverstĂ€rkte Mehrphotonenionisation in einem Molekularstrahlexperiment sowohl zeit-, als auch frequenzaufgelöst untersucht.In the presented work a new gas phase apparatus for photoelectron imaging experiments was succesfully simulated, constructed and together with a ps laser system
put into operation.
Besides the building of the new apparatus, the focus of this work was set to elucidate the excited state dynamics of selected aromatic heterocycles and pyrenes. The
examined molecules were investigated by frequency- and time-resolved resonance enhanced multi photon ionisation spectroscopy using a molecular beam experiment
Convolute lamination in modern sands of the estuary of the Oosterschelde, the Netherlands, formed as the result of entrapped air*
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