Estimando evapotranspiración en Puerto Rico

The United Nations Food and Agriculture Organization (FAO) has recommended the Penman-Monteith method as the single method for estimating reference evapotranspiration throughout the world. A disadvantage of the method, however, is its relatively high data requirement. Measurements of wind speed, humidity (or dew point temperature) and radiation tend to be the least available of the required parameters; therefore, the FAO has presented estimation procedures for these parameters. The purpose of this study was to evaluate estimation procedures for climate data to be used in the Penman-Monteith method for estimating long-term daily reference evapotranspiration, and to verify the accuracy of the procedures at four locations in Puerto Rico. Comparison of reference evapotranspiration determined by using the estimated and measured climate data shows reasonably good agreement. The methods presented in this paper are potentially valuable for calculating the long-term average daily reference evapotranspiration at any location in Puerto Rico. An example is provided to illustrate the use of the proposed estimation procedures for climate parameters. This study presents a comparison of reference evapotranspiration calculated by the Penman-Monteith method, with estimates previously made by using the Hargreaves-Samani method, for thirty-four locations in Puerto Rico. In addition, estimated peak evapotranspiration from the Soil Conservation Service (SCS) (now Natural Resources Conservation Service) Irrigation Guide for the Caribbean Area, the SCS Blaney-Criddle method and the Penman-Monteith method were compared for six vegetable crops at three locations in Puerto Rico. The results suggest that some irrigation systems may have been under-designed in terms of flow capacity in Puerto Rico.La Organización de Alimentos y Agricultura de las Naciones Unidas (FAO, por sus siglas en inglés) ha recomendado el método de Penman-Monteith como el único método de calculación que se debería usar para estimar evapotranspiración de referencia a través del mundo. Sin embargo, una desventaja del método es que requiere un número alto de datos. Las medidas de la velocidad del viento, la humedad (o la temperatura de punto de rocío) y la radiación tienden a ser los parámetros requeridos más difíciles de obtener; por ello, la FAO ofrece procedimientos alternos de estimación para estos parámetros. El propósito de este estudio fue evaluar los procedimientos de estimación de los datos del clima requeridos por el método de Penman-Monteith para estimar (a evapotranspiración de referencia promedio diaria a largo plazo y verificar la exactitud de los procedimientos en cuatro zonas de Puerto Rico. Se encontró una alta correlación entre la evapotranspiración de referencia calculada con los datos estimados (FAO) y la calculada con los datos observados del clima. Los métodos presentados son potenciatmente valiosos para calcular la evapotranspiración de referencia promedio diaria en cualquier zona de Puerto Rico. Se provee un ejemplo para ilustrar el uso del procedimiento propuesto para estimar parámetros del clima. Se presenta una comparación de la evapotranspiración de referencia calculada por el método de Penman-Monteith y resultados estimados previamente por el método de Hargreaves-Samani para 34 zonas en Puerto Rico. Además, el estimado máximo de evapotranspiración de la Guía de Riego del Servicio de Conservación de Suelos (SCS) (ahora Servicio de Conservación de Recursos Naturales) para el Área def Caribe, el método de Blaney-Criddfe (SCS) y él método de Penman-Monteith se compararon para seis vegetales en tres localidades en Puerto Rico. Los resultados indican que algunos sistemas de riego no tienen suficiente capacidad para suplir agua en Puerto Rico

Turning renewable feedstocks into a valuable and efficient chiral phosphate salt catalyst

Solketal, the chiral acetonide of glycerol, has been employed as the starting material in the design of a novel punctually chiral phosphate sodium salt for catalytic applications in organic and asymmetric synthesis. The racemate and the two enantiomers of the substrate are economic and commercially available, straightforwardly prepared in high yields from naturally occurring feedstocks. Therefore, remarkably, both enantiomers of the final catalyst can be synthesized by simple procedures in high yield and in compliance with several principles of green chemistry. To further demonstrate the usefulness of the novel catalyst, its application in a solventless protocol for cyanohydrin synthesis from a series of aldehydes has been presented

Comparison between two packages for pectoral muscle removal on mammographic images

Background: Pectoral muscle removal is a fundamental preliminary step in computer-aided diagnosis systems for full-field digital mammography (FFDM). Currently, two open-source publicly available packages (LIBRA and OpenBreast) provide algorithms for pectoral muscle removal within Matlab environment. Purpose: To compare performance of the two packages on a single database of FFDM images. Methods: Only mediolateral oblique (MLO) FFDM was considered because of large presence of pectoral muscle on this type of projection. For obtaining ground truth, pectoral muscle has been manually segmented by two radiologists in consensus. Both LIBRA’s and OpenBreast’s removal performance with respect to ground truth were compared using Dice similarity coefficient and Cohen-kappa reliability coefficient; Wilcoxon signed-rank test has been used for assessing differences in performances; Kruskal–Wallis test has been used to verify possible dependence of the performance from the breast density or image laterality. Results: FFDMs from 168 consecutive women at our institution have been included in the study. Both LIBRA’s Dice-index and Cohen-kappa were significantly higher than OpenBreast (Wilcoxon signed-rank test P < 0.05). No dependence on breast density or laterality has been found (Kruskal–Wallis test P > 0.05). Conclusion: Libra has a better performance than OpenBreast in pectoral muscle delineation so that, although our study has not a direct clinical application, these results are useful in the choice of packages for the development of complex systems for computer-aided breast evaluation

Drug excipient interaction study with polymorphic forms of tibolone.

Powder mixtures (1:1) of tibolone polymorphic forms I (monoclinic) and II (triclinic) and excipients have been prepared and compacted. The samples were stored at 50 °C and 90% RH for one month and subsequently were evaluated using differential scanning calorimetry (DSC) and high-performance liquid chromatography (HPLC). The results indicate that during the compaction, the applied pressure reduced the chemical stability of tibolone in both polymorph forms. The triclinic form was more chemically unstable, both pure and in contact with excipients, than the monoclinic form. Lactose monohydrate was shown to reduce chemical degradation for both forms. Ascorbyl palmitate was shown to affect the tibolone stability differently depending on the polymorphic form used.Colegio de Farmacéuticos de la Provincia de Buenos Aire

Quantum critical lines in holographic phases with (un)broken symmetry

All possible scaling IR asymptotics in homogeneous, translation invariant holographic phases preserving or breaking a U(1) symmetry in the IR are classified. Scale invariant geometries where the scalar extremizes its effective potential are distinguished from hyperscaling violating geometries where the scalar runs logarithmically. It is shown that the general critical saddle-point solutions are characterized by three critical exponents ($\theta, z, \zeta$). Both exact solutions as well as leading behaviors are exhibited. Using them, neutral or charged geometries realizing both fractionalized or cohesive phases are found. The generic global IR picture emerging is that of quantum critical lines, separated by quantum critical points which correspond to the scale invariant solutions with a constant scalar.Comment: v3: 32+29 pages, 2 figures. Matches version published in JHEP. Important addition of an exponent characterizing the IR scaling of the electric potentia

Impact of Antioxidant Therapy on Natural Pregnancy Outcomes and Semen Parameters in Infertile Men: A Systematic Review and Meta-Analysis of Randomized Controlled Trials

Purpose: Seminal oxidative stress (OS) is a recognized factor potentially associated with male infertility, but the efficacy of antioxidant (AOX) therapy is controversial and there is no consensus on its utility. Primary outcomes of this study were to investigate the effect of AOX on spontaneous clinical pregnancy, live birth and miscarriage rates in male infertile patients. Secondary outcomes were conventional semen parameters, sperm DNA fragmentation (SDF) and seminal OS. Materials and methods: Literature search was performed using Scopus, PubMed, Ovid, Embase, and Cochrane databases. Only randomized controlled trials (RCTs) were included and the meta-analysis was conducted according to PRISMA guidelines. Results: We assessed for eligibility 1,307 abstracts, and 45 RCTs were finally included, for a total of 4,332 infertile patients. We found a significantly higher pregnancy rate in patients treated with AOX compared to placebo-treated or untreated controls, without significant inter-study heterogeneity. No effects on live-birth or miscarriage rates were observed in four studies. A significantly higher sperm concentration, sperm progressive motility, sperm total motility, and normal sperm morphology was found in patients compared to controls. We found no effect on SDF in analysis of three eligible studies. Seminal levels of total antioxidant capacity were significantly higher, while seminal malondialdehyde acid was significantly lower in patients than controls. These results did not change after exclusion of studies performed following varicocele repair. Conclusions: The present analysis upgrades the level of evidence favoring a recommendation for using AOX in male infertility to improve the spontaneous pregnancy rate and the conventional sperm parameters. The failure to demonstrate an increase in live-birth rate, despite an increase in pregnancy rates, is due to the very few RCTs specifically assessing the impact of AOX on live-birth rate. Therefore, further RCTs assessing the impact of AOX on live-birth rate and miscarriage rate, and SDF will be helpful

Towards leptogenesis at NLO: the right-handed neutrino interaction rate

We compute quantum and thermal corrections to the right-handed neutrino interaction rate in the early universe at next-to-leading order in all the relevant SM couplings (gauge, top Yukawa and higgs couplings). Previous computations considered 2 -> 2 scatterings, finding infra-red divergences. The KLN theorem demands that infra-red divergences cancel in the full result: after adding 1 -> 3 and one-loop virtual corrections that enter at the same order we find a simple result.Comment: 20 pages, 9 figures, error fixed in an equation right after Eqs. (18); v4: experimental value of the Higgs mass consistently include