Intra-molecular origin of the fast relaxations observed in the Brillouin light scattering spectra of molecular glass-formers

The Brillouin light scattering spectra of the o-terphenyl single crystal are compared with those of the liquid and the glass phases. This shows: i) the direct evidence of a fast relaxation at 5 GHz in both the single crystal and the glass; ii) a similar temperature dependence for the attenuation of the longitudinal sound waves in the single crystal and the glass; and iii) the absence of coupling between the fast relaxation and the transverse acoustic waves. These results allow us to assign such a relaxation to the coupling between the longitudinal acoustic waves and intra-molecular vibrations, and therefore to exclude any relationship between it and the glass transition.Comment: 4 Pages, 4 Figure

Non-dynamic origin of the acoustic attenuation at high frequency in glasses

The sound attenuation in the THz region is studied down to T=16 K in glassy glycerol by inelastic x-ray scattering. At striking variance with the decrease found below 100 K in the GHz data, the attenuation in the THz range does not show any T dependence. This result i) indicates the presence of two different attenuation mechanisms, active respectively in the high and low frequency limits; ii) demonstrates the non-dynamic origin of the attenuation of THz sound waves, and confirms a similar conclusion obtained in SiO2 glass by molecular dynamics; and iii) supports the low frequency attenuation mechanism proposed by Fabian and Allen (Phys.Rev.Lett. 82, 1478 (1999)).Comment: 3 pages, 5 Figures, To be published in PR

Proteolytic and lipolytic starter cultures and their effect on traditional fermented sausages ripening and sensory traits

In this study, three starter formulations including Lactobacillus curvatus and Staphylococcus xylosus strains selected in vitro on the basis of their lipolytic and proteolytic activities were employed for the manufacture of traditional fermented sausages of southern Italy. Microbial population, proteolysis, lipolysis, changes in free amino acids (FAA) and free fatty acids (FFA) and development of characteristic taste and flavor of the final product were investigated. Proteolysis and lipolysis were observed in sausages inoculated with proteolytic and lipolytic S. xylosus coupled with L. curvatus, while the sausage started with only S. xylosus without lactobacilli was identical to the non-inoculated control, indicating that the proteolysis could be due to both microbial activity and endogenous proteases activated by the decrease in pH. The statistical analysis applied to the instrumental and sensory data showed that there was an effect of the starter used on the characteristics of the sausage obtained. In particular, the control samples showed very close features different from the sausages obtained by adding starter cultures. Finally, analyzing the sensory parameters the sausages ripened without starter addition and those started without the L. curvatus AVL3 showed similar features indicating an influence of the presence of the lactobacilli on the final organoleptic quality of the sausages. An appropriate choice of a combination of strains in a starter formulation is fundamental to obtain products of the expected quality

Effects of a natural extract from Mangifera indica L, and its active compound, mangiferin, on energy state and lipid peroxidation of red blood cells

Following oxidative stress, modifications of several biologically important macromolecules have been demonstrated. In this study we investigated the effect of a natural extract from Mangifera indica L (Vimang), its main ingredient mangiferin and epigallocatechin gallate (EGCG) on energy metabolism, energy state and malondialdehyde (MDA) production in a red blood cell system. Analysis of NIDA, high energy phosphates and ascorbate was carried out by high performance liquid chromatography (HPLC). Under the experimental conditions, concentrations of NIDA and ATP catabolites were affected in a dose-dependent way by H2O2. Incubation with Vimang (0.1, 1, 10, 50 and 100 mu g/mL), mangiferin (1, 10, 100 mu g/mL) and EGCG (0.01, 0.1, 1, 10 mu M) significantly enhances erythrocyte resistance to H2O2-induced reactive oxygen species production. In particular, we demonstrate the protective activity of these compounds on ATP, GTP and total nucleotides (NT) depletion after H2O2-induced damage and a reduction of NAD and ADP, which both increase because of the energy consumption following H2O2 addition. Energy charge potential, decreased in H2O2-treated erythrocytes, was also restored in a dose-dependent way by these substances. Their protective effects might be related to the strong free radical scavenging ability described for polyphenols. (c) 2006 Elsevier B.V All rights reserved

Vibrational origin of the fast relaxation processes in molecular glass-formers

We study the interaction of the relaxation processes with the density fluctuations by molecular dynamics simulation of a flexible molecule model for o-terphenyl (oTP) in the liquid and supercooled phases. We find evidence, besides the structural relaxation, of a secondary vibrational relaxation whose characteristic time, few ps, is slightly temperature dependent. This i) confirms the result by Monaco et al. [Phys. Rev, E 62, 7595 (2000)] of the vibrational nature of the fast relaxation observed in Brillouin Light Scattering (BLS) experiments in oTP; and ii) poses a caveat on the interpretation of the BLS spectra of molecular systems in terms of a purely center of mass dynamics.Comment: RevTeX, 5 pages, 4 eps figure

Elastic constant dishomogeneity and Q2Q^2 dependence of the broadening of the dynamical structure factor in disordered systems

We propose an explanation for the quadratic dependence on the momentum $Q$, of the broadening of the acoustic excitation peak recently found in the study of the dynamic structure factor of many real and simulated glasses. We ascribe the observed $Q^2$ law to the spatial fluctuations of the local wavelength of the collective vibrational modes, in turn produced by the dishomegeneity of the inter-particle elastic constants. This explanation is analitically shown to hold for 1-dimensional disordered chains and satisfatorily numerically tested in both 1 and 3 dimensions.Comment: 4 pages, RevTeX, 5 postscript figure

Wide and deep near-UV (360nm) galaxy counts and the extragalactic background light with the Large Binocular Camera

Deep multicolour surveys are the main tool to explore the formation and evolution of the faint galaxies which are beyond the spectroscopic limit with the present technology. The photometric properties of these faint galaxies are usually compared with current renditions of semianalytical models to provide constraints on the fundamental physical processes involved in galaxy formation and evolution, namely the mass assembly and the star formation. Galaxy counts over large sky areas in the near-UV band are important because they are difficult to obtain given the low efficiency of near-UV instrumentation, even at 8m class telescopes. A large instrumental field of view helps in minimizing the biases due to the cosmic variance. We have obtained deep images in the 360nm U band provided by the blue channel of the Large Binocular Camera at the prime focus of the Large Binocular Telescope. We have derived over an area of ~0.4 sq. deg. the galaxy number counts down to U=27 in the Vega system (corresponding to U=27.86 in the AB system) at a completeness level of 30% reaching the faintest current limit for this wavelength and sky area. The shape of the galaxy counts in the U band can be described by a double power-law, the bright side being consistent with the shape of shallower surveys of comparable or greater areas. The slope bends over significantly at U>23.5 ensuring the convergence of the contribution by star forming galaxies to the EBL in the near-UV band to a value which is more than 70% of the most recent upper limits derived for this band. We have jointly compared our near-UV and K band counts collected from the literature with few selected hierarchical CDM models emphasizing critical issues in the physical description of the galaxy formation and evolution.Comment: Accepted for publication in A&A. Uses aa.cls, 9 pages, 4 figures. Citations update

Relaxation processes in harmonic glasses?

A relaxation process, with the associated phenomenology of sound attenuation and sound velocity dispersion, is found in a simulated harmonic Lennard-Jones glass. We propose to identify this process with the so called microscopic (or instantaneous) relaxation process observed in real glasses and supercooled liquids. A model based on the memory function approach accounts for the observation, and allows to relate to each others: 1) the characteristic time and strength of this process, 2) the low frequency limit of the dynamic structure factor of the glass, and 3) the high frequency sound attenuation coefficient, with its observed quadratic dependence on the momentum transfer.Comment: 11 pages, 3 figure

Formation of Multiple Populations in Globular Clusters: Another Possible Scenario

While chemical composition spreads are now believed to be a universal characteristic of globular clusters (GCs), not all of them present multiple populations in their color-magnitude diagrams (CMDs). Here we present a new scenario for the formation of GCs, in an attempt to qualitatively explain this otherwise intriguing observational framework. Our scenario divides GCs into three groups, depending on the initial mass (M_I) of the progenitor structure (PS), as follows. i) Massive PSs can retain the gas ejected by massive stars, including the ejecta of core-collapse SNe. ii) Intermediate-mass PSs can retain at least a fraction of the fast winds of massive stars, but none of the core-collapse SNe ejecta. iii) Low-mass PSs can only retain the slow winds of intermediate-mass stars. Members of the first group would include omega Centauri (NGC 5139), M54 (NGC 6715), M22 (NGC 6656), and Terzan 5, whereas NGC 2808 (and possibly NGC 2419) would be members of the second group. The remaining GCs which only present a spread in light elements, such as O and Na, would be members of the third group. According to our scenario, the different components in omega Cen should not display a sizeable spread in age. We argue that this is consistent with the available observations. We give other simple arguments in favor of our scenario, which can be described in terms of two main analytical relations: i) Between the actual observed ratio between first and second generation stars (R_SG^FG) and the fraction of first generation stars that have been lost by the GC (S_L); and ii) Between S_L and M_I. We also suggest a series of future improvements and empirical tests that may help decide whether the proposed scenario properly describes the chemical evolution of GCs.Comment: Accepted for publication in Astronomy and Astrophysic

Search for anisotropies in cosmic-ray positrons detected by the PAMELA experiment

The PAMELA detector was launched on board of the Russian Resurs-DK1 satellite on June 15, 2006. Data collected during the first four years have been used to search for large-scale anisotropies in the arrival directions of cosmic-ray positrons. The PAMELA experiment allows for a full sky investigation, with sensitivity to global anisotropies in any angular window of the celestial sphere. Data samples of positrons in the rigidity range 10 GV $\leq$ R $\leq$ 200 GV were analyzed. This article discusses the method and the results of the search for possible local sources through analysis of anisotropy in positron data compared to the proton background. The resulting distributions of arrival directions are found to be isotropic. Starting from the angular power spectrum, a dipole anisotropy upper limit \delta = 0.166 at 95% C.L. is determined. Additional search is carried out around the Sun. No evidence of an excess correlated with that direction was found.Comment: The value of the dipole anisotropy upper limit has been changed. The method is correct but there was a miscalculation in the relative formul