Nucleation and Growth of the Zn-Fe Alloy from a Chloride Electrolyte

In this study, the kinetics of Zn-Fe codeposition was investigated in chloride acidic solution using cyclic voltammetry. Anomalous codeposition is detected and this mechanism depends on the Zn(II) / Fe(II) concentration ratio in the electrolytic bath. The study of early stages of electrodeposition showed that Zn- Fe follows a theoretical response to instantaneous nucleation evolves into a progressive nucleation according to the model of Scharifker and Hills. The morphology and structure of the coatings is discussed using characterization techniques. Dense, uniform, and singlephased Zn-Fe coatings could be obtained with a Zn-Fe ratio of 1/3. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/3531

Designing Secure Ethereum Smart Contracts: A Finite State Machine Based Approach

The adoption of blockchain-based distributed computation platforms is growing fast. Some of these platforms, such as Ethereum, provide support for implementing smart contracts, which are envisioned to have novel applications in a broad range of areas, including finance and Internet-of-Things. However, a significant number of smart contracts deployed in practice suffer from security vulnerabilities, which enable malicious users to steal assets from a contract or to cause damage. Vulnerabilities present a serious issue since contracts may handle financial assets of considerable value, and contract bugs are non-fixable by design. To help developers create more secure smart contracts, we introduce FSolidM, a framework rooted in rigorous semantics for designing con- tracts as Finite State Machines (FSM). We present a tool for creating FSM on an easy-to-use graphical interface and for automatically generating Ethereum contracts. Further, we introduce a set of design patterns, which we implement as plugins that developers can easily add to their contracts to enhance security and functionality

A theory of normed simulations

In existing simulation proof techniques, a single step in a lower-level specification may be simulated by an extended execution fragment in a higher-level one. As a result, it is cumbersome to mechanize these techniques using general purpose theorem provers. Moreover, it is undecidable whether a given relation is a simulation, even if tautology checking is decidable for the underlying specification logic. This paper introduces various types of normed simulations. In a normed simulation, each step in a lower-level specification can be simulated by at most one step in the higher-level one, for any related pair of states. In earlier work we demonstrated that normed simulations are quite useful as a vehicle for the formalization of refinement proofs via theorem provers. Here we show that normed simulations also have pleasant theoretical properties: (1) under some reasonable assumptions, it is decidable whether a given relation is a normed forward simulation, provided tautology checking is decidable for the underlying logic; (2) at the semantic level, normed forward and backward simulations together form a complete proof method for establishing behavior inclusion, provided that the higher-level specification has finite invisible nondeterminism.Comment: 31 pages, 10figure

Structure and Microstructure Properties of Ball Milled Fe-Zn

Nanocrystalline Fe10 %Zn and Fe30 %Zn alloys have been prepared from pure elemental powders by mechanical alloying processing in a high energy planetary ball-mill. Microstructural, structural, and magnetic characterizations of the powders were investigated by X-ray diffraction, and vibrating sample magnometer. The crystallite size reduction to the nanometer scale is accompanied by an increase in the atomic level strain. The reaction between Fe and Zn leads to the formation of a bcc Fe(Zn) solid solution with a lattice parameter close to (0.2912 nm for Fe30 %Zn and 0,2885 nm for Fe10 %Zn) after 5 h of milling. The complete dissolution of the elemental Zn powders in the a-Fe lattice gives rise to the formation of a highly disordered Fe(Zn) solid solution, where a-Fe(Zn) nanograins have a crystallite size of (229,29 Å for Fe10 %Zn (24 h) 30,09 Å for Fe30 %Zn (24 h), on prolonged milling time. The coercivity and magnetization values are 18,90 (Fe10 %Zn)Oe and 26,59 (Fe30 %Zn) emu/g, respectively, after 24 h of milling. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/3514

Coordination of Dynamic Software Components with JavaBIP

JavaBIP allows the coordination of software components by clearly separating the functional and coordination aspects of the system behavior. JavaBIP implements the principles of the BIP component framework rooted in rigorous operational semantics. Recent work both on BIP and JavaBIP allows the coordination of static components defined prior to system deployment, i.e., the architecture of the coordinated system is fixed in terms of its component instances. Nevertheless, modern systems, often make use of components that can register and deregister dynamically during system execution. In this paper, we present an extension of JavaBIP that can handle this type of dynamicity. We use first-order interaction logic to define synchronization constraints based on component types. Additionally, we use directed graphs with edge coloring to model dependencies among components that determine the validity of an online system. We present the software architecture of our implementation, provide and discuss performance evaluation results.Comment: Technical report that accompanies the paper accepted at the 14th International Conference on Formal Aspects of Component Softwar

Rigorous System Design: The BIP Approach

Rigorous system design requires the use of a single powerful component framework allowing the representation of the designed system at different levels of detail, from application software to its implementation. This is essential for ensuring the overall coherency and correctness. The paper introduces a rigorous design flow based on the BIP (Behavior, Interaction, Priority) component framework. This design flow relies on several, tool-supported, source-to-source transformations allowing to progressively and correctly transform high level application software towards efficient implementations for specific platforms

Optical performance of the JWST MIRI flight model: characterization of the point spread function at high-resolution

The Mid Infra Red Instrument (MIRI) is one of the four instruments onboard the James Webb Space Telescope (JWST), providing imaging, coronagraphy and spectroscopy over the 5-28 microns band. To verify the optical performance of the instrument, extensive tests were performed at CEA on the flight model (FM) of the Mid-InfraRed IMager (MIRIM) at cryogenic temperatures and in the infrared. This paper reports on the point spread function (PSF) measurements at 5.6 microns, the shortest operating wavelength for imaging. At 5.6 microns the PSF is not Nyquist-sampled, so we use am original technique that combines a microscanning measurement strategy with a deconvolution algorithm to obtain an over-resolved MIRIM PSF. The microscanning consists in a sub-pixel scan of a point source on the focal plane. A data inversion method is used to reconstruct PSF images that are over-resolved by a factor of 7 compared to the native resolution of MIRI. We show that the FWHM of the high-resolution PSFs were 5-10% wider than that obtained with Zemax simulations. The main cause was identified as an out-of-specification tilt of the M4 mirror. After correction, two additional test campaigns were carried out, and we show that the shape of the PSF is conform to expectations. The FWHM of the PSFs are 0.18-0.20 arcsec, in agreement with simulations. 56.1-59.2% of the total encircled energy (normalized to a 5 arcsec radius) is contained within the first dark Airy ring, over the whole field of view. At longer wavelengths (7.7-25.5 microns), this percentage is 57-68%. MIRIM is thus compliant with the optical quality requirements. This characterization of the MIRIM PSF, as well as the deconvolution method presented here, are of particular importance, not only for the verification of the optical quality and the MIRI calibration, but also for scientific applications.Comment: 13 pages, submitted to SPIE Proceedings vol. 7731, Space Telescopes and Instrumentation 2010: Optical, Infrared, and Millimeter Wav

A Theory Agenda for Component-Based Design

The aim of the paper is to present a theory agenda for component-based design based on results that motivated the development of the BIP component framework, to identify open problems and discuss further research directions. The focus is on proposing a semantically sound theoretical and general framework for modelling component-based systems and their properties both behavioural and architectural as well for achieving correctness by using scalable specific techniques. We discuss the problem of composing components by proposing the concept of glue as a set of stateless composition operators defined by a certain type of operational semantics rules. We provide an overview of results about glue expressiveness and minimality. We show how interactions and associated transfer of data can be described by using connectors and in particular, how dynamic connectors can be defined as an extension of static connectors. We present two approaches for achieving correctness for component-based systems. One is by compositional inference of global properties of a composite component from properties of its constituents and interaction constraints implied by composition operators. The other is by using and composing architectures that enforce specific coordination properties. Finally, we discuss recent results on architecture specification by studying two types of logics: 1) interaction logics for the specification of sets of allowed interactions; 2) configuration logics for the characterisation of architecture styles