634 research outputs found
Structural and electronic properties of Al nanowires: an ab initio pseudopotential study
The stability and electronic structure of a single monatomic Al wire has been
studied using the ab initio pseudopotential method. The Al wire undergoes two
structural rearrangements under compression, i.e., zigzag configurations at
angles of and . The evolution of electronic structures of the Al
chain as a function of structural phase transition has been investigated. The
relationship between electronic structure and geometric stability is also
discussed. The 2p bands in the Al nanowire are shown to play a critical role in
its stability. The effects of density functionals (GGA and LDA) on cohesive
energy and bond length of Al nanostructures (dimmer, chains, and monolayers)
are also examined. The link between low dimensional 0D structure (dimmer) to
high dimensional 3D bulk Al is estimated. An example of optimized tip-suspended
finite atomic chain is presented to bridge the gap between hypothetical
infinite chains and experimental finite chains.Comment: 11 pages, 5 figure
A synthetic Escherichia coli predator–prey ecosystem
We have constructed a synthetic ecosystem consisting of two Escherichia coli populations, which communicate bi-directionally through quorum sensing and regulate each other's gene expression and survival via engineered gene circuits. Our synthetic ecosystem resembles canonical predator–prey systems in terms of logic and dynamics. The predator cells kill the prey by inducing expression of a killer protein in the prey, while the prey rescue the predators by eliciting expression of an antidote protein in the predator. Extinction, coexistence and oscillatory dynamics of the predator and prey populations are possible depending on the operating conditions as experimentally validated by long-term culturing of the system in microchemostats. A simple mathematical model is developed to capture these system dynamics. Coherent interplay between experiments and mathematical analysis enables exploration of the dynamics of interacting populations in a predictable manner
Vertical structure models of the 1990 equatorial disturbance on Saturn
In September 1990, an atmospheric disturbance in the form of an abnormally high albedo area developed in the equatorial region of Saturn. Events of this nature are exceedingly rare for this planet as they have been detected in the equatorial region on only two other occasions in over a century. In ongoing monitoring of the atmospheres of the outer planets, CCD imaging observations of Saturn by New Mexico State University's Tortugas Mountain Station were made before, during, and after the disturbance's formation through both broad-band filters and narrow-band visible/near-IR filters centered in methane absorption bands. Also, multispectral Hubble Space Telescope observations were made within weeks of the event and later in 1991. These observations were calibrated and scans of reflectivity at constant latitude are being modeled with a vertically inhomogeneous, multiple scattering model previously used to model Jupiter's South Equatorial Belt brightening event in 1989. In addition, the reflectivity of the disturbance as a function of the scattering angles is being obtained so as to model this feature's vertical structure in particular. A preliminary report of the modeling results will be presented
The Bugaboo Man / music by J. A. Nicol; words by R. A. Barnet
Cover: drawing of a Caucasian woman telling a story to an African American girl; the drawing is lined with jack-o-lanterns; description reads: Supplement to the St. Louis Post-Dispatch Sunday, June 10, 1900; Publisher: Arthur W. Tams (New York)https://egrove.olemiss.edu/sharris_b/1000/thumbnail.jp
NNI-Form Quark Mass Matrix Expressed by the Observable Quantities
It is pointed out that the phase convention of the CKM matrix V affects
texture analysis of the quark mass matrices (M_u, M_d) when we try to describe
(M_u, M_d) by the observable quantities (quark masses and CKM matrix
parameters) only. This is demonstrated for a case of the non-Hermitian
Fritzsch-type mass matrix (tilde{M}_u, tilde{M}_d), which is a general
expression of quark mass matrix (M_u, M_d) and is described by twelve
parameters. We find that we can always choose a phase convention of V which
yields tilde{M}_{u32} = 0, so that the remaining ten parameters in (tilde{M}_u,
tilde{M}_d) can completely be expressed by the ten observable quantities.Comment: 11 pages (LaTeX); Title was change
International capital mobility in an era of globalisation: adding a political dimension to the 'Feldstein–Horioka Puzzle'
The debate about the scope of feasible policy-making in an era of globalisation continues to be set within the context of an assumption that national capital markets are now perfectly integrated at the international level. However, the empirical evidence on international capital mobility contradicts such an assumption. As a consequence, a significant puzzle remains. Why is it, in a world in which the observed pattern of capital flows is indicative of a far from globalised reality, that public policy continues to be constructed in line with more extreme variants of the globalisation hypothesis? I attempt to solve this puzzle by arguing that ideas about global capital market integration have an independent causal impact on political outcomes which extends beyond that which can be attributed to the extent of their actual integration
Enantioselective Hydroxylation of Benzylic C(sp; 3; )-H Bonds by an Artificial Iron Hydroxylase Based on the Biotin-Streptavidin Technology
The selective hydroxylation of C-H bonds is of great interest to the synthetic community. Both homogeneous catalysts and enzymes offer complementary means to tackle this challenge. Herein, we show that biotinylated Fe(TAML)-complexes (TAML = Tetra Amido Macrocyclic Ligand) can be used as cofactors for incorporation into streptavidin to assemble artificial hydroxylases. Chemo-genetic optimization of both cofactor and streptavidin allowed optimizing the performance of the hydroxylase. Using H; 2; O; 2; as oxidant, up to ∼300 turnovers for the oxidation of benzylic C-H bonds were obtained. Upgrading the ee was achieved by kinetic resolution of the resulting benzylic alcohol to afford up to >98% ee for (; R; )-tetralol. X-ray analysis of artificial hydroxylases highlights critical details of the second coordination sphere around the Fe(TAML) cofactor
Elliptic Curves over Real Quadratic Fields are Modular
We prove that all elliptic curves defined over real quadratic fields are
modular.Comment: 38 pages. Magma scripts available as ancillary files with this arXiv
versio
Eta-Helium Quasi-Bound States
The cross section and tensor analysing power t_20 of the d\vec{d}->eta 4He
reaction have been measured at six c.m. momenta, 10 < p(eta) < 90 MeV/c. The
threshold value of t_20 is consistent with 1/\sqrt{2}, which follows from
parity conservation and Bose symmetry. The much slower momentum variation
observed for the reaction amplitude, as compared to that for the analogous
pd->eta 3He case, suggests strongly the existence of a quasi-bound state in the
eta-4He system and optical model fits indicate that this probably also the case
for eta-3He.Comment: LaTeX, uses elsart.sty, 10 pages, 3 Postscript figures, Submitted to
Physics Letters
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