The size range of bubbles that produce ash during explosive volcanic eruptions

Volcanic eruptions can produce ash particles with a range of sizes and morphologies. Here we morphologically distinguish two textural types: Simple (generally smaller) ash particles, where the observable surface displays a single measureable bubble because there is at most one vesicle imprint preserved on each facet of the particle; and complex ash particles, which display multiple vesicle imprints on their surfaces for measurement and may contain complete, unfragmented vesicles in their interiors. Digital elevation models from stereo-scanning electron microscopic images of complex ash particles from the 14 October 1974 sub-Plinian eruption of Volcán Fuego, Guatemala and the 18 May 1980 Plinian eruption of Mount St. Helens, Washington, U.S.A. reveal size distributions of bubbles that burst during magma fragmentation. Results were compared between these two well-characterized eruptions of different explosivities and magma compositions and indicate that bubble size distributions (BSDs) are bimodal, suggesting a minimum of two nucleation events during both eruptions. The larger size mode has a much lower bubble number density (BND) than the smaller size mode, yet these few larger bubbles represent the bulk of the total bubble volume. We infer that the larger bubbles reflect an earlier nucleation event (at depth within the conduit) with subsequent diffusive and decompressive bubble growth and possible coalescence during magma ascent, while the smaller bubbles reflect a relatively later nucleation event occurring closer in time to the point of fragmentation. Bubbles in the Mount St. Helens complex ash particles are generally smaller, but have a total number density roughly one order of magnitude higher, compared to the Fuego samples. Results demonstrate that because ash from explosive eruptions preserves the size of bubbles that nucleated in the magma, grew, and then burst during fragmentation, the analysis of the ash-sized component of tephra can provide insights into the spatial distribution of bubbles in the magma prior to fragmentation, enabling better parameterization of numerical eruption models and improved understanding of ash transport phenomena that result in pyroclastic volcanic hazards. Additionally, the fact that the ash-sized component of tephra preserves BSDs and BNDs consistent with those preserved in larger pyroclasts indicates that these values can be obtained in cases where only distal ash samples from particular eruptions are obtainable

Submarine deposits from pumiceous pyroclastic density currents traveling over water: an outstanding example from offshore Montserrat (IODP 340)

Pyroclastic density currents have been observed to both enter the sea, and to travel over water for tens of kilometers. Here, we identified a 1.2-m-thick, stratified pumice lapilli-ash cored at Site U1396 offshore Montserrat (Integrated Ocean Drilling Program [IODP] Expedition 340) as being the first deposit to provide evidence that it was formed by submarine deposition from pumice-rich pyroclastic density currents that traveled above the water surface. The age of the submarine deposit is ca. 4 Ma, and its magma source is similar to those for much younger Soufrière Hills deposits, indicating that the island experienced large-magnitude, subaerial caldera-forming explosive eruptions much earlier than recorded in land deposits. The deposit’s combined sedimentological characteristics are incompatible with deposition from a submarine eruption, pyroclastic fall over water, or a submarine seafloor-hugging turbidity current derived from a subaerial pyroclastic density current that entered water at the shoreline. The stratified pumice lapilli-ash unit can be subdivided into at least three depositional units, with the lowermost one being clast supported. The unit contains grains in five separate size modes and has a >12 phi range. Particles are chiefly subrounded pumice clasts, lithic clasts, crystal fragments, and glass shards. Pumice clasts are very poorly segregated from other particle types, and lithic clasts occur throughout the deposit; fine particles are weakly density graded. We interpret the unit to record multiple closely spaced (<2 d) hot pyroclastic density currents that flowed over the ocean, releasing pyroclasts onto the water surface, and settling of the various pyroclasts into the water column. Our settling and hot and cold flotation experiments show that waterlogging of pumice clasts at the water surface would have been immediate. The overall poor hydraulic sorting of the deposit resulted from mixing of particles from multiple pulses of vertical settling in the water column, attesting to complex sedimentation. Slow-settling particles were deposited on the seafloor together with faster-descending particles that were delivered at the water surface by subsequent pyroclastic flows. The final sediment pulses were eventually deflected upon their arrival on the seafloor and were deposited in laterally continuous facies. This study emphasizes the interaction between products of explosive volcanism and the ocean and discusses sedimentological complexities and hydrodynamics associated with particle delivery to water

Using dissolved H₂O in rhyolitic glasses to estimate palaeo-ice thickness during a subglacial eruption at Bláhnúkur(Torfajökull, Iceland)

The last decade has seen the refinement of a technique for reconstructing palaeo-ice thicknesses based on using the retained H2O and CO2 content in glassy eruptive deposits to infer quenching pressures and therefore ice thicknesses. The method is here applied to Bláhnúkur, a subglacially erupted rhyolitic edifice in Iceland. A decrease in water content from ~0.7 wt.% at the base to ~0.3 wt.% at the top of the edifice suggests that the ice was 400 m thick at the time of the eruption. As Bláhnúkur rises 350 m above the surrounding terrain, this implies that the eruption occurred entirely within ice, which corroborates evidence obtained from earlier lithofacies studies. This paper presents the largest data set (40 samples) so far obtained for the retained volatile contents of deposits from a subglacial eruption. An important consequence is that it enables subtle but significant variations in water content to become evident. In particular, there are anomalous samples which are either water-rich (up to 1 wt.%) or water-poor (~0.2 wt.%), with the former being interpreted as forming intrusively within hyaloclastite and the latter representing batches of magma that were volatile-poor prior to eruption. The large data set also provides further insights into the strengths and weaknesses of using volatiles to infer palaeo-ice thicknesses and highlights many of the uncertainties involved. By using examples from Bláhnúkur, the quantitative use of this technique is evaluated. However, the relative pressure conditions which have shed light on Bláhnúkur’s eruption mechanisms and syn-eruptive glacier response show that, despite uncertainties in absolute values, the volatile approach can provide useful insight into the mechanisms of subglacial rhyolitic eruptions, which have never been observed

Confocal microscopy 3D imaging of diesel particulate matter

To date, diesel particulate matter (DPM) has been described as aggregates of spherule particles with a smooth appearing surface. We have used a new colour confocal microscope imaging method to study the 3D shape of diesel particulate matter (DPM); we observed that the particles can have sharp jagged appearing edges and consistent with these findings, 2D light microscopy demonstrated that DPM adheres to human lung epithelial cells. Importantly, the slide preparation and confocal microscopy method applied avoids possible alteration to the particles' surfaces and enables colour 3D visualisation of the particles. From twenty-one PM particles, the mean (standard deviation) major axis length was 5.6 (2.25) μm with corresponding values for the minor axis length of 3.8 (1.25) μm. These new findings may help explain why air pollution particulate matter (PM) has the ability to infiltrate human airway cells, potentially leading to respiratory tract, cardiovascular and neurological disease

A New 3D Method of Measuring Bubble Size Distributions from Vesicle Fragments Preserved On Surfaces of Volcanic Ash Particles

We have developed a novel method of measuring bubble size distributions from their remains expressed on the surfaces of volcanic ash particles. The morphology of the ash fragments retains a record of bubble size at the time of fragmentation in the curvature of the convex surfaces on the ash fragments. This curvature can be measured using stereo scanning electron microscopy (SSEM), and morphology can be represented using a digital elevation model (DEM) of ash particle surfaces. Due to the vagaries of the sensitivity of SSEM imagery to surface roughness, a three-point fit technique produces more robust results for curvature than a least-squares approach for curve-fitting of ellipsoids of revolution to ash surfaces. The method allows measurement of vesicles within a size range from one to over a million cubic microns. The inferred bubble size distributions so obtained can potentially provide valuable insights regarding magma dynamics and vesiculation that lead to the explosive eruptions that produce ash. An error analysis of the methodology indicates reasonably accurate reconstruction of bubble geometries and bubble size distributions (BSD). Accuracy is constrained primarily by the size of ash particles themselves since the mode of the BSD should be at least a standard deviation smaller than the dominant dimensions of the particles for robust results