Analytical Methodologies for the Control of Particle-Phase Polycyclic Aromatic Compounds from Diesel Engine Exhaust

International audienc

Linking initial soil bacterial diversity and polycyclic aromatic hydrocarbons (PAHs) degradation potential

International audienc

Prétraitement de sédiments de dragage par une méthode électrocinétique

Nous avons évalué sous différentes conditions les performances de la déshydratation d'un sédiment causée sous l'effet combiné de la gravité et d'un champ électrique par rapport à celle obtenue sous l'effet gravitaire. Les résultats montrent que la déshydratation et la consolidation d'un matériau sont nettement accélérées sous l'effet d'un champ électrique, ainsi qu'un front basique qui s'installe dans l'échantillon, durant l'essai. Les effluents recueillis seront analysés afin d'évalué l'atténuation des contaminations

Influence of a mixture of metals on PAHs biodegradation processes in soils

In order to assess the effect of mixed pollutants, the influence of different concentration levels of a mixture of metals (Cr, Co, Pb, Mn, Ni, Cu, Zn) on the biodegradation of some PAHs (phenanthrene, fluoranthene, pyrene, benzo[b]fluoranthene and benzo[a]pyrene) in soil samples was evaluated. To do so, groups of microcosms of a natural soil fromthe region of Sabadell (Barcelona, Spain)were prepared as a reproduction of the native environment at laboratory scale, under controlled conditions. Mixtures of PAHs and metals were carefully selected, according to soil characterization and microbiological growth preliminary assays, and were added to microcosms. These microcosms were analyzed at various times, along two months, to obtain PAHs dissipation time-courses. A first-order kinetic modelling allowed obtaining different rate constants and DT50 values as a function of the metal levels introduced in microcosms. As a general observation, the higher the concentration of metals, the lower the biodegradation of PAHs of 3–4 rings (phenanthrene, fluoranthene and pyrene). On the other hand, no important effect on the biodegradation of higher molecular weight PAHs (benzo[b]fluoranthene and benzo[a]pyrene) was observed at the different concentration levels of metals testedPostprint (author's final draft

Analysis of polycyclic aromatic hydrocarbons in atmospheric particulate samples by microwaveassisted extraction and liquid chromatography

A methodology based on microwave-assisted extraction (MAE) and LC with fluorescence detection (FLD) was investigated for the efficient determination of 15 polycyclic aromatic hydrocarbons (PAHs) regarded as priority pollutants by the US Environmental Protection Agency and dibenzo(a,l)pyrene in atmospheric particulate samples. PAHs were successfully extracted from real outdoor particulate matter (PM) samples with recoveries ranging from 81.4±8.8 to 112.0±1.1%, for all the compounds except for naphthalene (62.3±18.0%) and anthracene (67.3±5.7%), under the optimum MAE conditions (30.0 mL of ACN for 20 min at 110ºC). No clean-up steps were necessary prior to LC analysis. LOQs ranging from 0.0054 ng/m3 for benzo( a)anthracene to 0.089 ng/m3 for naphthalene were reached. The validated MAE methodology was applied to the determination of PAHs from a set of real world PM samples collected in Oporto (north of Portugal). The sum of particulate-bound PAHs in outdoor PM ranged from 2.5 and 28 ng/m3.http://recipp.ipp.pt/handle/10400.22/289

Novel Application of Cyclolipopeptide Amphisin: Feasibility Study as Additive to Remediate Polycyclic Aromatic Hydrocarbon (PAH) Contaminated Sediments

To decontaminate dredged harbor sediments by bioremediation or electromigration processes, adding biosurfactants could enhance the bioavailability or mobility of contaminants in an aqueous phase. Pure amphisin from Pseudomonas fluorescens DSS73 displays increased effectiveness in releasing polycyclic aromatic hydrocarbons (PAHs) strongly adsorbed to sediments when compared to a synthetic anionic surfactant. Amphisin production by the bacteria in the natural environment was also considered. DSS73’s growth is weakened by three model PAHs above saturation, but amphisin is still produced. Estuarine water feeding the dredged material disposal site of a Norman harbor (France) allows both P. fluorescens DSS73 growth and amphisin production

CARACTERISATION DE POLLUANTS DE TYPE HAP A L'ECHAPPEMENT DE MOTEURS DIESEL: PRELEVEMENT ET ANALYSE DE L'EFFLUENT GAZEUX

International audienc

Développement d'une nouvelle approche expérimentale pour évaluer la bio-accessibilité de contaminants organiques persistants dans des matrices sédimentaires

National audienc