Classical and quantum-linearized descriptions of degenerate optomechanical parametric oscillators

Recent advances in the development of modern quantum technologies have opened the possibility of studying the interplay between spontaneous parametric down-conversion and optomechanics, two of the most fundamental nonlinear optical processes. Apart from practical reasons, such scenario is very interesting from a fundamental point of view, because it allows exploring the optomechanical interaction in the presence of a strongly quantum-correlated field, the spontaneously down-converted mode. In this work we analyze such problem from two approximate but valuable perspectives: the classical limit and the limit of small quantum fluctuations. We show that, in the presence of optomechanical coupling, the well-known classical phase diagram of the optical problem gets modified by the appearance of new dynamical instabilities. As for the quantum-mechanical description, we prove the ability of the squeezed down-converted field to cool down the mechanical motion not only to thermal but also to squeezed thermal mechanical states, and in a way that can be much less sensitive to parameters (e.g., detuning of the driving laser) than standard sideband cooling.Comment: New version including the quantum linearized description of the system and appendices. Accepted in Physical Review

Circular dichroism of anthocyanidin 3-glucoside self-aggregates

“NOTICE: this is the author’s version of a work that was accepted for publication in Phytochemistry. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Phytochemistry Volume 88, April 2013, Pages 92–98. DOI 10.1016/j.phytochem.2012.12.011 ."“NOTICE: this is the author’s version of a work that was accepted for publication in Phytochemistry. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Phytochemistry Volume 88, April 2013, Pages 92–98. DOI 10.1016/j.phytochem.2012.12.011 .""Self-association constants for the flavylium cations of the six most common anthocyanidin 3-glucosides were determined by circular dichroism (CD) and UV–Vis spectroscopy. Along with previous 1H NMR results, all measurements were consistent with a monomer–dimer model. The CD spectra of the antho-cyanidin 3-glucosides were similar to the analogues 3,5-diglucosides. All dimers of the anthocyanidin 3-glucosides exhibited left-handed CD signals, with petunidin-3-glucoside and myrtillin having the most intense signals. In addition, the magnitude of the molar ellipticity, [h], was generally higher for the 3-glucosides than for the 3,5-diglucosides. For all six anthocyanins studied, the CD absorption spectra of their dimers showed evidence of the splitting of the monomer absorption into lower (J) and higher (H) energy bands. The angle and the distance between the dipolar moments of the two monomers comprising the dimer were obtained from the lower energy absorption band. While the angle was more or less similar in all six dimers, the separation distance between the monomer dipole moments differed dramatically. The intensity of the CD signal displayed a linear dependence with the inverse square of the dipole moment distances.

Chemical evolution of the colour systems generated by riccionidin A, 3-deoxyanthocyanidins and anthocyanins

UIDB/50006/2020 MEX/Ref. 288188The kinetics and thermodynamics (in acidic solutions) of the five chemical species reversibly interconnected by external stimuli (a multistate), such as pH and light, generated by the liverworts colorant riccionidin A were investigated. The degradation products of the multistate formed after 10 days at neutral pH were identified. The behaviour of riccionidin A multistate was compared with previous results reported for the equivalent systems based on 3-deoxyanthocyanidins (found in mosses and ferns) and anthocyanins (ubiquitous in angiosperms). The five chemical species have mutatis mutandis similar structures in the three multistates. The most dramatic difference is the extremely slow interconversion rate between flavylium cation and trans-chalcone in riccionidin A and related compounds multistates (tens of days) when compared with deoxyanthocyanins (a few days) and anthocyanins (several hours), at room temperature. The mole fraction distribution of the five species that constitute the multistate as a function of pH is also different in the three families of compounds. Some considerations regarding the chemical evolution of the three systems are given.authorsversionpublishe

Dynamic Elastic Modulus Variability in Anisotropic and Isotropic Materials: Comparison by Acoustic Emission

This study compared the variation of the dynamic elastic modulus (E) of three types of composite pipes made by the filament winding process and a steel alloy specimen, according to signal source changes. The specimens were produced with three different winding angles, i.e., ±50°, ±52.5°, and ±55°. The moduli were obtained through a known signal source and the angular variation, according to two sensors positioned over the specimen's surface. In a previous article, the variation in the velocity of acoustic emission (AE) signals, performed in the same type of pipes, was discussed based on the standards for glass fiber-reinforced epoxy (GFRE) filament wound specimens. This work took these preliminary findings to compare with the results found for steel alloy pipes (SAE 1020). This data was used with appropriate equations to determine the dynamic elastic moduli of each material. It was found that, even for small angular differences, the modulus changes position concerning the lamination angle. Thus, the lower the quality control, the lower the final product with composite materials. As expected, for isotropic materials such as steel alloys, the modulus remains constant along the angles, while for anisotropic ones, it is dependent on the principal directions of stress and strain, or on the other hand, dependent on the correlation between the angular wave velocity of the AE signals

Anatase as an alternative application for preventing biodeterioration of mortars: evaluation and comparison with other biocides

International Biodeterioration & Biodegradation 64(2010)388 e 396The aim of this study is the comparison between different treatments(anatase and two conventional biocides:Biotin T and Anios)for preventing biodeterioration of mortars.The treatments were applied both in the laboratory on mortar slabs and in situ on walls of Palácio Nacional da Pena(Sintra,Portugal). Mortar slabs treated with anatase (pure and Fe3þ doped)applied as acoating or by mixing within the mortar were prepared,and their surfaces characterized by different methodologies.The mortars were inoculated with cyanobacteria and chlorophyta species,incubated for a period of 4 months and the chlorophyll content quantified by extraction method and fluorescence emission.For comparison purposes untreated mortar slabs were inoculated,incubated and finally treated with the biocides.After two weeks the respective chlorophyll contents was quantified. In situ studies in two external walls of Palácio Nacional da Pena covered by organisms were also performed by direct application of aqueous solutions of the three products,and the efficiency of the treatment monitored by spectrophotometry using the CIELAB method.Lichens and other phototrophic microorganisms were identified by direct observation with a microscope and cyanobacteria,green microalgae, bacteria and fungi by DNA-based molecular analysis targeting the 16S and 18S ribosomal RNAgenes. The results show that anatase is a better agent for preventing biodeterioration than the two tested conventional biocides,both in mortars slabsand in situ studies.In fact,photographic and colorimetric records made in two external walls of Palácio Nacional da Pena after two weeks of treatments application showed that lichens and other phototrophic microorganisms disappear from the places where anatase was applied

Uma fáunula de moluscos bivaives do calcário mocambo, formação Piauí, carbonífero superior da Bacia do Maranhão: município de José de Freitas, estado do Piauí

Resum

Elemento de estudo para a unidade curricular de mecânica: conceitos gerais da mecânica vetorial para iniciantes

info:eu-repo/semantics/publishedVersio

The Effect of the Copigment on the pH-Dependent Reversible and Irreversible Processes

no 219201Intermolecular copigmentation of malvidin-3-O-glucoside with caffeine was studied using a holistic procedure that includes the extension to basic pH values. In moderately basic solutions (7.5 < pH < 9.5) and independently of the copigment presence, there is a pH region where degradation of the quinoidal base and anionic quinoidal bases is faster than hydration and OH-nucleophilic addition, preventing the system from reaching the equilibrium. Intermolecular copigmentation with caffeine reduces significantly the degradation rate of quinoidal bases. In a more basic medium, the equilibrium is reached and degradation occurs from the anionic chalcones. In this case, the addition of caffeine also reduces the degradation rate in the interval 10 < pH < 11.5.publishersversionpublishe