Critical evaluation of stability constants for alpha-hydroxycarboxylic acid complexes with protons and metal ions and the accompanying enthalpy changes. Part II. Aliphatic 2-hydroxycarboxylic acids (IUPAC Technical Report)

Abstract Stability constants for different aliphatic 2-hydroxycarboxylic acid complexes in aqueous solutions with protons and metal ions published between 1960 and the end of 1994 have been critically evaluated

Northern Bobwhite Nest Site Selection in Field Borders

Field borders are used to supplement early successional habitat critical for northern bobwhite (Colinus virginianus) nesting that is lost to modern intensive agricultural practices. The suitability of field border habitat for nesting may be affected by microhabitat characteristics at the site and patch scale and placement relative to various land-cover types at the landscape scale. We sought to determine whether bobwhite select nest locations at site, patch, and landscape scales. We collected microhabitat data (stem density, percent cover, and ground composition) and distance to land-cover type data (woody edge, crop, ditch, and road) from 26 bobwhite nests and 26 control sites in field borders in North Carolina, USA, during 2010 and 2011. We modeled nest site selection by comparing nests with random locations using conditional logistic regression at the site scale and logistic regression at the combined patch–landscape scale. We performed model selection using the small sample Akaike’s Information Criterion (AICc). The top site-scale model showed that bobwhite selected for the presence of woody cover and avoided open soil at the nest. There was no clear top model at the combined patch–landscape level. In an agriculture-dominated landscape, managers should focus on microhabitat characteristics of field borders to improve suitability for bobwhite nesting

Northern Bobwhite Nest Site Selection in Field Borders

Field borders are used to supplement early successional habitat critical for northern bobwhite (Colinus virginianus) nesting that is lost to modern intensive agricultural practices. The suitability of field border habitat for nesting may be affected by microhabitat characteristics at the site and patch scale and placement relative to various land-cover types at the landscape scale. We sought to determine whether bobwhite select nest locations at site, patch, and landscape scales. We collected microhabitat data (stem density, percent cover, and ground composition) and distance to land-cover type data (woody edge, crop, ditch, and road) from 26 bobwhite nests and 26 control sites in field borders in North Carolina, USA, during 2010 and 2011. We modeled nest site selection by comparing nests with random locations using conditional logistic regression at the site scale and logistic regression at the combined patch–landscape scale. We performed model selection using the small sample Akaike’s Information Criterion (AICc). The top site-scale model showed that bobwhite selected for the presence of woody cover and avoided open soil at the nest. There was no clear top model at the combined patch–landscape level. In an agriculture-dominated landscape, managers should focus on microhabitat characteristics of field borders to improve suitability for bobwhite nesting

Assessment of Alertness and Cognitive Performance of Closed Circuit Rebreather Divers With the Critical Flicker Fusion Frequency Test in Arctic Diving Conditions

Introduction: Cold water imposes many risks to the diver. These risks include decompression illness, physical and cognitive impairment, and hypothermia. Cognitive impairment can be estimated using a critical flicker fusion frequency (CFFF) test, but this method has only been used in a few studies conducted in an open water environment. We studied the effect of the cold and a helium-containing mixed breathing gas on the cognition of closed circuit rebreather (CCR) divers. Materials and Methods: Twenty-three divers performed an identical dive with controlled trimix gas with a CCR device in an ice-covered quarry. They assessed their thermal comfort at four time points during the dive. In addition, their skin temperature was measured at 5-min intervals throughout the dive. The divers performed the CFFF test before the dive, at target depth, and after the dive. Results: A statistically significant increase of 111.7% in CFFF values was recorded during the dive compared to the pre-dive values (p < 0.0001). The values returned to the baseline after surfacing. There was a significant drop in the divers' skin temperature of 0.48 degrees C every 10 min during the dive (p < 0.001). The divers' subjectively assessed thermal comfort also decreased during the dive (p = 0.01). Conclusion: Our findings showed that neither extreme cold water nor helium-containing mixed breathing gas had any influence on the general CFFF profile described in the previous studies from warmer water and where divers used other breathing gases. We hypothesize that cold-water diving and helium-containing breathing gases do not in these diving conditions cause clinically relevant cerebral impairment. Therefore, we conclude that CCR diving in these conditions is safe from the perspective of alertness and cognitive performance.Peer reviewe

Sources of nonlinearities, chatter generation and suppression in metal cutting

The mechanics of chip formation has been revisited in order to understand functional relationships between the process and the technological parameters. This has led to the necessity of considering the chip-formation process as highly nonlinear, with complex interrelations between its dynamics and thermodynamics. In this paper a critical review of the state of the art of modelling and the experimental investigations is outlined with a view to how the nonlinear dynamics perception can help to capture the major phenomena causing instabilities (chatter) in machining operations. The paper is concluded with a case study, where stability of a milling process is investigated in detail, using an analytical model which results in an explicit relation for the stability limit. The model is very practical for the generation of the stability lobe diagrams, which is time consuming when using numerical methods. The extension of the model to the stability analysis of variable pitch cutting tools is also given. The application and verification of the method are demonstrated by several examples

Hsp90 orchestrates transcriptional regulation by Hsf1 and cell wall remodelling by MAPK signalling during thermal adaptation in a pathogenic yeast

Acknowledgments We thank Rebecca Shapiro for creating CaLC1819, CaLC1855 and CaLC1875, Gillian Milne for help with EM, Aaron Mitchell for generously providing the transposon insertion mutant library, Jesus Pla for generously providing the hog1 hst7 mutant, and Cathy Collins for technical assistance.Peer reviewedPublisher PD

Heavy metal and nitrogen concentrations in mosses are declining across Europe whilst some “hotspots” remain in 2010

In recent decades, naturally growing mosses have been used successfully as biomonitors of atmospheric deposition of heavy metals and nitrogen. Since 1990, the European moss survey has been repeated at five-yearly intervals. In 2010, the lowest concentrations of metals and nitrogen in mosses were generally found in northern Europe, whereas the highest concentrations were observed in (south-)eastern Europe for metals and the central belt for nitrogen. Averaged across Europe, since 1990, the median concentration in mosses has declined the most for lead (77%), followed by vanadium (55%), cadmium (51%), chromium (43%), zinc (34%), nickel (33%), iron (27%), arsenic (21%, since 1995), mercury (14%, since 1995) and copper (11%). Between 2005 and 2010, the decline ranged from 6% for copper to 36% for lead; for nitrogen the decline was 5%. Despite the Europe-wide decline, no changes or increases have been observed between 2005 and 2010 in some (regions of) countries

Seasonal Dynamics of Mobile Carbon Supply in Quercus aquifolioides at the Upper Elevational Limit

Many studies have tried to explain the physiological mechanisms of the alpine treeline phenomenon, but the debate on the alpine treeline formation remains controversial due to opposite results from different studies. The present study explored the carbon-physiology of an alpine shrub species (Quercus aquifolioides) grown at its upper elevational limit compared to lower elevations, to test whether the elevational limit of alpine shrubs (<3 m in height) are determined by carbon limitation or growth limitation. We studied the seasonal variations in non-structural carbohydrate (NSC) and its pool size in Q. aquifolioides grown at 3000 m, 3500 m, and at its elevational limit of 3950 m above sea level (a.s.l.) on Zheduo Mt., SW China. The tissue NSC concentrations along the elevational gradient varied significantly with season, reflecting the season-dependent carbon balance. The NSC levels in tissues were lowest at the beginning of the growing season, indicating that plants used the winter reserve storage for re-growth in the early spring. During the growing season, plants grown at the elevational limit did not show lower NSC concentrations compared to plants at lower elevations, but during the winter season, storage tissues, especially roots, had significantly lower NSC concentrations in plants at the elevational limit compared to lower elevations. The present results suggest the significance of winter reserve in storage tissues, which may determine the winter survival and early-spring re-growth of Q. aquifolioides shrubs at high elevation, leading to the formation of the uppermost distribution limit. This result is consistent with a recent hypothesis for the alpine treeline formation