24 research outputs found
Spatially valid data of atmospheric deposition of heavy metals and nitrogen derived by moss surveys for pollution risk assessments of ecosystems
For analysing element input into ecosystems and associated risks due to atmospheric deposition, element concentrations
in moss provide complementary and time-integrated data at high spatial resolution every 5 years since 1990. The paper reviews (1) minimum sample sizes needed for reliable, statistical estimation of mean values at four different
spatial scales (European and national level as well as
landscape-specific level covering Europe and single countries); (2) trends of heavy metal (HM) and nitrogen (N)
concentrations in moss in Europe (1990–2010); (3) correlations between concentrations of HM in moss and soil specimens collected across Norway (1990–2010); and (4) canopy drip-induced site-specific variation of N concentration in moss sampled in seven European countries (1990–2013). While the minimum sample sizes on the European and national level were achieved without exception, for some ecological land classes and elements, the coverage with sampling sites should be improved. The decline in emission and subsequent atmospheric deposition of HM across Europe has resulted in decreasing HM concentrations in moss between 1990 and 2010. In contrast, hardly any changes were observed for N in moss between 2005, when N was included into the survey for the first time, and 2010. In Norway, both, the moss and the soil survey data sets, were correlated, indicating a decrease of HM concentrations in moss and soil. At the site level, the average N deposition inside of forests was almost three times higher than the average N deposition outside of forests
Modelling and mapping heavy metal and nitrogen concentrations in moss in 2010 throughout Europe by applying Random Forests models
Objective: This study explores the statistical relations between the concentration of nine heavy metals(HM) (arsenic (As), cadmium (Cd), chromium (Cr), copper (Cu), mercury (Hg), nickel (Ni), lead (Pb),vanadium (V), zinc (Zn)), and nitrogen (N) in moss and potential explanatory variables (predictors)which were then used for mapping spatial patterns across Europe. Based on moss specimens collected
in 2010 throughout Europe, the statistical relation between a set of potential predictors (such as the atmospheric deposition calculated by use of two chemical transport models (CTM), distance from emission sources, density of different land uses, population density, elevation, precipitation, clay content of soils) and concentrations of HMs and nitrogen (N) in moss (response variables) were evaluated by the use of Random Forests (RF) and Classification and Regression Trees (CART). Four spatial scales were regarded: Europe as a whole, ecological land classes covering Europe, single countries participating in the European Moss Survey (EMS), and moss species at sampling sites. Spatial patterns were estimated by applying a series of RF models on data on potential predictors covering Europe. Statistical values and resulting maps were used to investigate to what extent the models are specific for countries, units of the Ecological Land Classification of Europe (ELCE), and moss species.
Results: Land use, atmospheric deposition and distance to technical emission sources mainly influence the element concentration in moss. The explanatory power of calculated RF models varies according to elements measured in moss specimens, country, ecological land class, and moss species. Measured and predicted medians of element concentrations agree fairly well while minima and maxima show considerable differences. The European maps derived from the RF models provide smoothed surfaces of element concentrations (As, Cd, Cr, Cu, N, Ni, Pb, Hg, V, Zn), each explained by a multivariate RF model and verified by CART, and thereby more information than the dot maps depicting the spatial patterns of measured values.
Conclusions: RF is an eligible method identifying and ranking boundary conditions of element concentrations in moss and related mapping including the influence of the environmental factors
Twenty years of nitrogen deposition to Norway spruce forests in Sweden
The yearly, total (dry+wet) deposition of inorganic nitrogen (inorg-N) to Norway spruce forests was estimated with a full spatial coverage over Sweden for a twenty-year period, 2001–2020, based on combined measurements with Teflon string samplers, throughfall deposition and bulk deposition to the open field. The results were based on a novel method to apply estimates of the dry deposition based on measurements at a limited number of sites, to a larger number of sites with only bulk deposition measurements, in turn based on the existence of a strong geographical gradient in the dry deposition of inorg-N from southwest to northeast Sweden. The method should be applicable for other geographical regions where gaseous NH3, NO2 and HNO3 are not main drivers of N dry deposition and where geographical gradients in dry deposition could be defined. It was shown that Norway spruce forests in south Sweden receive more N from deposition than has been previously estimated, based on modelling. Clear time trends were demonstrated for decreased deposition of inorg-N to Norway spruce forests in all parts of Sweden. The decreases were somewhat larger than what could be expected from the decrease in the reported emissions of inorg-N from Europe. The results emphasize that estimates of the total deposition are necessary in order to map levels and follow the development of N deposition in forests