Variations saisonnières des formes de phosphores dans une station de traitement des eaux usées par lagunage, sous climat aride de Marrakech (Maroc)

L'objectif de ce travail est d'étudier dans un premier temps la dynamique du phosphore dans un système de traitement d 'eaux usées par lagunage facultatif, en relation avec les compartiments biologiques: phytoplancton, zooplancton et bactéries, dans un deuxième temps, d'évaluer, sous les conditions du climat aride, les performances épuratoires de ce système en ce qui concerne les formes du phosphore. Un intérêt particulier est porté au phénomène du relargage du phosphore par les sédiments. Les résultats montrent qu'il y a une évolution saisonnière et cyclique du phosphore dans les bassins de lagunage, en étroite corrélation avec le phytoplancton et le zooplancton. Le phytoplancton représente la part importante des formes organiques du phosphore particulaire. Les meilleures performances d'élimination du phosphore sont notées au printemps (77% pour les PO4 et 64 % pour le phosphore total). La période la moins performante est la période automne-hiver où les rendements moyens ne dépassent pas 38%. Le phosphore éliminé est stocké dans les sédiments. En période estivale, des phénomènes de relargage du phosphore à partir des sédiments ont été mis en évidence, favorisés par une zonation verticale des eaux à cette période. Des essais aulaboratoire ont montré la grande aptitude des sédiments de la station de lagunage étudiée à relarguer le phosphore, avec intervention de l'activité biologique du sédiment.Assimilation, sedimentation and release are the principal mechanisms controlling the behavior of phosphorus in aquatic ecosystems. There are numerous investigations of the phosphorus cycle in lakes and rivers in relation to the eutrophication process. There are, however, few studies about phosphorus cycling in waste stabilization ponds and most of these have discussed phosphorus removal. The aims of this paper were: 1) to study phosphorus dynamics in relation to the biomass compartment (zooplancton, phytoplancton and bacteria); and 2) to evaluate the phosphorus removal efficiency of the treatment plant under arid climatic conditions. Of particular interest was the remobilization of phosphorus from the pond sediment, both under laboratory conditions and in the field. The experimental installation consisted of two ponds receiving domestic wastewater (mean flow=120.4+5.8 m3.day-1 and specific organic load=56 kgBOD.ha-1. day-1; pond area=0.5 ha and depth=1.5 m). Samples were taken twice monthly from the surface, B1(S) and B2(S), and from the 1.5 m layers, B1(F) and B2(F). Composite (24 h) samples were taken from the inflow and the outflowof the plant to determine the removal efficiencies. In each sample, soluble reactive phosphorus (PO4), total phosphorus (PT) and total soluble phosphorus (PTD) were determined. Particulate phosphorus (PTP) was calculated as (PT-PTD) and soluble organic phosphorus (POD) as (PTD-PO4). Phosphorus release was measured in a plexiglas flask containing sediment (collected by corer from the pond bottom) overlaid with distilled water. Over 15 days, daily measurements were made of PO4 and total phosphorus. Sediment dry weight (%), volatile matter, organic carbon (%) and total phosphorus were measured before and after each test. Phosphorus contents of the phytoplankton, zooplankton and bacteria were estimated using the methods of BOUGIS (1974).The results show that cyclical and seasonal variations of phosphorus content were closely correlated with variations in the biological components. Significant correlation coefficients were noted between chlorophyll-a and particulate organic phosphorus. Organic phosphorus in algal cells was the more important form of particulate organic phosphorus. Under the arid climate, the waste stabilization ponds were more efficient at phosphate removal during the spring-summer period (77% of PO4 and 64% of total phosphorus in spring). The first pond may play the major role in phosphate removal. Phosphorus is only eliminated from stabilization ponds through accumulation in the sediment. However, part of the phosphorus which accumulates in pond sediments remains potentially mobile. During the summer period, phosphorus release from the sediment, observed in situ, was favored by stratification of the overlying water. The same phenomenon was noted during the autumn, particularly the release of POD. Laboratory studies have shown that phosphorus release may amount to 55 mg P m-2d-1. Biological activity may play a significant role in this mobilization

Evolution annuelle du peuplement zooplanctonique dans un lagunage à haut rendement et incidence du temps de séjour

Proposé au début des années soixante par W.J. OSWALD, le lagunage dit « à haut rendement », utilisé pour l'épuration d'eaux usées domestiques, représente un écosystème hypereutrophe. Il se distingue considérablement du lagunage naturel par des temps de séjour très courts (2 à 12 jours), de très faibles profondeurs (< 1 m) et par une agitation constante de façon à favoriser le développement algal.Cette étude a pour objectifs de : 1) caractériser les successions saisonnières du zooplancton dans un écosystème où celles-ci n'ont pratiquement pas été étudiées et 2) étudier l'impact, sur la structure du peuplement et au fil des saisons, du temps de séjour des eaux à traiter.Le suivi du peuplement zooplanctonique a été réalisé pendant une période de deux ans dans deux bassins à haut rendement (nommés A et B) de même configuration alimentés en eaux usées. Les temps de résidence des eaux à traiter sont constants et de huit jours dans l'un, variable et ajusté selon l'ensoleillement et la charge entrante dans l'autre.Les résultats obtenus sont analysés par une classification hiérarchique avec contrainte de contiguïté temporelle. Les groupes obtenus sont ensuite testés par l'analyse discriminante. Les résultats sont regroupés chronologiquement : en six groupes pour le bassin B et en dix groupes pour le bassin A. L'analyse discriminante montre que les Crustacés et les Rotifères sont respectivement responsables des regroupements dans les bassins B et A. Pendant la période de démarrage du lagunage ainsi qu'en automne et en hiver, le zooplancton est principalement composé de Protozoaires : Ciliés libres ou fixés en fortes densités (jusqu'à 2,7.107 ind. 1-1) et Rhizopodes (Amibes). Au printemps et en été, lorsque le rayonnement solaire devient important, la production primaire étant optimale, les Protozoaires sont remplacés par des brouteurs herbivores métazoaires. La production de Rotifères et de Daphnies dont les exigences en nourriture (microalgues) sont considérables est importante au printemps ou bien en été uniquement dans le bassin à temps de séjour court. Le développement des Crustacés Copépodes et Ostracodes est favorisé en été dans le bassin à temps de séjour plus long.Tous ces organismes participent activement à réparation. ils se nourrissent pour la plupart en filtrant les éléments en suspension dans le milieu et participent directement à l'élimination des MES et de la DCO (PIZAY-PARENTY, 1985).II devient donc envisageable, par suite du rôle non négligeable joué par le zooplancton et surtout par Daphnia magna, de concevoir une gestion du lagunage qui favoriserait le développement de ce Cladocère. Cette biomasse facilement récupérable par tamisage peut être valorisée en aquaculture.High rate ponds for wastewater treatment have been the focus of much attention since their creation by W.J. OSWALD in the early 1960's. These aquatic ecosystems are hypereutrophic because of massive nutrient introduction by wastewater influents. These kinds of ponds are very different front natural biological ponds because of short residence times (2 to 12 days), shallow depths (<1 m) and constant mechanical mixing which improve alga : growth.This study presents the following objectives : 1) to characterize seasonal successions of zooplankton in this ecosystem where they are unknown and 2) to study residence time influence on zooplanktonic successions in function of seasons. Our investigation consists in studying two similar high rate ponds of 48 m2 surface area and 35 cm depth constantly stirred by paddle wheels.Only residence time is different. The first pond has eight days residence time and in the second one, it changes with solar radiations and organic matter concentrations. The influents come from a primary pond of eight days residence time, fed continuously with domestic influents front a small town, Mèze. The aim of this experiment is to compare seasonal successions in these two high rate ponds (called A and B) with different residence times. Zooplanktonic investigation has been carried out for two years. One sample was collected twice a week in primary pond effluent and two others samples collected once a week into the two high rate ponds near the outflow areas. The results of chronological clustering take inter account the discontinuities of zooplanktonic structure. We obtain six sequences in B pond and ten groups in A pond. Stepwise discriminant analysis shows that Crustaceans and Rotifers are respectively responsible for chronological clustering in B and in A pond. During the sterling period of wastewater treatment and in autumn and in winter, photosynthesis is low and zooplankton is composed mainly of Protozoa : free-living or fixed Ciliates in great concentrations (until 2,7.107 ind. l-1) and Rhizopods (Amæba sp.). These organisms have important food needs (bacteria and algal detritus). During spring and summer, as solar radiations become important, Protozoa are replaced by metazoan grazers. Spring or summer with short residence times increase Rotifers or Daphnia magna production white summer with longer residence times increase Cyclops sp and cypris ovum production. All these organisms are active components of wastewater treatment : the consumption of particulates by zooplankton Increases TSS and COD removal efficiencies (PIZAY-PARENTY, 1985).Therefore, because of the filtering activity of Crustaceans (especially of Daphnia magna), it seems possible to conceive a new pond managment, with residence time changes, favourable to exponential algal growth and consequently to crustacean biomass production. It is easier to harvest this biomass (with nets) than to harvest algal biomass, which still presents problems

Industry 4.0 – LabVIEW Based Industrial IoT Condition Monitoring System

As a result of a substantial shift in focus towards a more digital industry, multiple sectors of industry are now realising the potential of Industry 4.0 and Internet of Things (IoT) technology. The manufacturing industry in particular is subject to unexpected machine downtime from component wear over an extended period. With Industrial IoT (IIoT) technology implemented, there is the potential for gathering large quantities of data, which can be used for preventative maintenance. This research article addresses some of the technological requirements for developing an IoT industrial condition monitoring network, whose composition makes use of wireless devices along with conventional wired methods to enable a series of data capture and control operations in amongst a network of nodes. To provide a platform to host these operations, the industry standard fieldbus protocol Modbus TCP was used in conjunction with the LabVIEW development environment, where a bespoke graphical user interface was developed to provide control and a visual representation of the data collected. In addition, one of the nodes acted as the output for hardware displays, which in turn correlated the alarm status of the user interface. By using industry standard communication protocols, it was also possible to enable connectivity between real industry hardware, further extending the capabilities of the system

Bilan du carbone dans le lagunage anaérobie appliqué sous climat méditerranéen

Ce travail a porté sur l'application du lagunage anaérobie pour le traitement primaire des eaux résiduaires urbaines sous climat méditerranéen. Il a été réalisé sur les lagunes anaérobies de l' Ecosite de Mèze (Hérault, France). Les lagunes anaérobies constituent un traitement primaire satisfaisant avec des rendements moyens de 55% pour les MES et 30% pour la DBO5, pour une faible emprise au sol. Le taux d'accumulation des boues est de seulement 0,017 m3 /EH.an, notamment du fait de l'efficacité de la dégradation anaérobie. L'équilibre du métabolisme anaérobie des boues est atteint après un an de fonctionnement. L'accumulation des boues se fait alors de façon saisonnière avec une forte accumulation en hiver et une digestion du stock en été. Cette évolution est liée à l'influence de la température sur la méthanogénèse. La production de biogaz (83% CH4) a pu être mesurée par des collecteurs à gaz mis au point pour cette étude et dépend également fortement de la température. Le bilan du carbone montre que 74% du carbone organique épuré est converti en CH4, 13% en carbone inorganique dissous et seulement 15% est stocké dans les boues. Toutefois, les lagunes anaérobies présentent un risque de créer des nuisances olfactives dues à l'émission de H2 S.This project examined the application of anaerobic ponds for the primary treatment of urban wastewater under a Mediterranean climate. The objectives of the study were to determine removal performances and to study sludge accumulation and the production of biogas. Together, these results allowed us to calculate the carbon mass balance in the anaerobic ponds.This work was carried out in the two large primary anaerobic ponds of the waste stabilization pond system at the Ecosite of Mèze (Hérault, France), treating domestic wastewater for 13,800 person-equivalents (PE). Anaerobic ponds were 5,000 m3 in volume, 3.1 m in depth and presented a retention time of 4.6 d with a mean volumetric organic loading of 83 g BOD5 /m3 ×d× The characteristics of the influent and effluent (including: suspended solids (SS); chemical oxygen demand (COD); biological oxygen demand (BOD5); bicarbonate (HCO3 -); total organic carbon (TOC); and volatile fatty acids (VFA)) were determined twice-monthly. The volume of sludge and its characteristics (including: SS; volatile solids (VS); TOC; and VFA) were measured monthly. The production of biogas and its composition (CH4, CO2, H2 S) were measured with gas collectors specially developed for this study.Results showed that the anaerobic ponds constituted a good primary treatment with mean removal rates of 55% for SS, 30% for BOD and 22% for COD. Removal performances were relatively constant over the year. Indeed, removal rates were essentially due to the removal of particulate organic matter by sedimentation. Anaerobic degradation occurred essentially in the sludge layer and the removal of soluble COD was low.The study of sludge characteristics showed that anaerobic digestion equilibrium was reached after one year of operation. The beginning of methanogenesis could be observed by the decrease in the concentration of volatile fatty acids. The accumulation of sludge showed seasonal variation with an important accumulation in winter and the digestion of the accumulated stock in summer. This evolution could be related to the influence of temperature on methanogenesis. The mean rate of sludge accumulation was only 3.8 g SS/P-E×d or 0.017 m3/P-E×yr. This rate was significantly lower than for the primary settling tank (50-60 g SS/P-E×d) and for the facultative ponds (0.085 m3 /P-E×yr) due to the intensive anaerobic degradation.The production of biogas was measured by gas collectors specially developed for this study. The biogas contained essentially CH4 (83%); CO2 was less than 4% because it dissolved in the water column and was converted into bicarbonate alkalinity. The concentration of H2 S was less than 1% (between 75 and 4770 ppm) but was the cause of unpleasant odours. The biogas production rate was strongly dependent on temperature. A non-linear relationship was obtained (Ebiogas=4.8451 × e0.1203T, r2=0.92, n=16). The mean annual biogas production rate was calculated to be 49 L/m2 ×d. Seasonal variation in the biogas production rate could be related to seasonal variations in sludge accumulation.The carbon mass balance showed that 74% of the removed organic carbon was converted into CH4, 13% into dissolved inorganic carbon (bicarbonates) and only 15% was stored in sludge. The mass balance was well equilibrated and did not show the entry of atmospheric CO2, which occurs in aerobic ponds where CO2 is used by algae to produce their cell biomass. In an anaerobic pond, the low production of sludge was due to the efficiency of the anaerobic degradation but also to the low internal biomass production.To conclude, the use of a primary anaerobic pond was advantageous and permitted a reduction in the required surface area for a waste stabilization pond system. This process produced effluent for secondary treatment in a facultative pond with essentially the removal of the particulate organic matter. However, However, anaerobic ponds may cause odor problems linked to the emission of H2 S

French developments for improving In Service Inspection of SFRs

International audienceIn Service Inspection (ISI) is a major issue to be taken into account for future Sodium Fast Reactors safety, thus, a large R&D work is performed since 2010 in France for the future SFRs. ISI requirements have been taken into account since the early pre-conceptual design phase (specific rules for design have been merged into RCC-MRx design rules until 2012), then consolidated through the basic design phase with more detailed specifications leading to increase the ISI tools ability for immersed sodium structures of SFRs, at about 200°C (shut down conditions). Inspection within the main vessel are planned with transducers immersed in sodium and also with transducers located out of sodium medium. Finally, the qualification of ISI ultrasonic transducers (for Non Destructive Examination, Telemetry and Imaging) is being performed with experimental water and sodium testing, to be compared to simulation with CIVA software platform results. A pluri-annual R&D program mainly deals with the reactor block structures, the primary components and circuit, and the Power Conversion System. Specific developments have been performed for NDE of thick austenitic steel welds, NDE using guided Lamb waves, telemetry from the outside of reactor vessel, imaging of immersed structures and components within the large primary vessel (in a pool type reactor concept) and associated in sodium robotics (with in-sodium tightness). Some results of testing and simulation are given for some ASTRID project applications

Microalgae for municipal wastewater nutrient remediation: mechanisms, reactors and outlook for tertiary treatment

This review explores the use of microalgae for nutrient removal in municipal wastewater treatment, considering recent improvements in the understanding of removal mechanisms and developments of both suspended and non-suspended systems. Nutrient removal is associated to both direct and indirect uptake, with the former associated to the biomass concentration and growth environment (reactor). Importantly, direct uptake is influenced by the Nitrogen:Phosphorus content in both the cells and the surrounding wastewater, with opposite trends observed for N and P. Comparison of suspended and non-suspended systems revealed that whilst all were capable of achieving high levels of nutrient removal, only non-suspended immobilized systems could do so with reduced hydraulic retention times of less than 1 day. As microalgae are photosynthetic organisms, the metabolic processes associated with nutrient assimilation are driven by light. Optimization of light delivery remains a key area of development with examples of improved mixing in suspended systems and the use of pulsating lights to enhance light utilization and reduce costs. Recent data provide increased confidence in the use of microalgae for nutrient removal in municipal wastewater treatment, enabling effluent discharges below 1 mg L−1 to be met whilst generating added value in terms of bioproducts for energy production or nutrient recovery. Ultimately, the review suggests that future research should focus on non-suspended systems and the determination of the added value potential. In so doing, it is predicted that microalgae systems will be significant in the delivery of the circular economy

MRI measures of middle cerebral artery diameter in conscious humans during simulated orthostasis.

BACKGROUND AND PURPOSE: The relationship between middle cerebral artery (MCA) flow velocity (CFV) and cerebral blood flow (CBF) is uncertain because of unknown vessel diameter response to physiological stimuli. The purpose of this study was to directly examine the effect of a simulated orthostatic stress (lower body negative pressure [LBNP]) as well as increased or decreased end-tidal carbon dioxide partial pressure (P(ET)CO(2)) on MCA diameter and CFV. METHODS: Twelve subjects participated in a CO(2) manipulation protocol and/or an LBNP protocol. In the CO(2) manipulation protocol, subjects breathed room air (normocapnia) or 6% inspired CO(2) (hypercapnia), or they hyperventilated to approximately 25 mm Hg P(ET)CO(2) (hypocapnia). In the LBNP protocol, subjects experienced 10 minutes each of -20 and -40 mm Hg lower body suction. CFV and diameter of the MCA were measured by transcranial Doppler and MRI, respectively, during the experimental protocols. RESULTS: Compared with normocapnia, hypercapnia produced increases in both P(ET)CO(2) (from 36+/-3 to 40+/-4 mm Hg, P CONCLUSIONS: Under the conditions of this study, changes in MCA diameter were not detected. Therefore, we conclude that relative changes in CFV were representative of changes in CBF during the physiological stimuli of moderate LBNP or changes in P(ET)CO(2)

Monophyletic group of unclassified γ-Proteobacteria dominates in mixed culture biofilm of high-performing oxygen reducing biocathode

International audienceSeveral mixed microbial communities have been reported to show robust bioelectrocatalysis of oxygen reduction over time at applicable operation conditions. However, clarification of electron transfer mechanism(s) and identification of essential micro-organisms have not been realised. Therefore, the objective of this study was to shape oxygen reducing biocathodes with different microbial communities by means of surface modification using the electrochemical reduction of two different diazonium salts in order to discuss the relation of microbial composition and performance. The resulting oxygen reducing mixed culture biocathodes had complex bacterial biofilms variable in size and shape as observed by confocal and electron microscopy. Sequence analysis of ribosomal 16S rDNA revealed a putative correlation between the abundance of certain microbiota and biocathode performance. The best performing biocathode developed on the unmodified graphite electrode and reached a high current density for oxygen reducing biocathodes at neutral pH (0.9A/m(2)). This correlated with the highest domination (60.7%) of a monophyletic group of unclassified γ-Proteobacteria. These results corroborate earlier reports by other groups, however, higher current densities and higher presence of these unclassified bacteria were observed in this work. Therefore, members of this group are likely key-players for highly performing oxygen reducing biocathodes.[on SciFinder (R)