A thermodynamic model of mixed organic-inorganic aerosols to predict activity coefficients

Tropospheric aerosols contain mixtures of inorganic salts, acids, water, and a large variety of organic compounds. Interactions between these substances in liquid mixtures lead to discrepancies from ideal thermodynamic behaviour. By means of activity coefficients, non-ideal behaviour can be taken into account. We present here a thermodynamic model named AIOMFAC (Aerosol Inorganic-Organic Mixtures Functional groups Activity Coefficients) that is able to calculate activity coefficients covering inorganic, organic, and organic-inorganic interactions in aqueous solutions over a wide concentration range. This model is based on the activity coefficient model LIFAC by Yan et al. (1999) that we modified and reparametrised to better describe atmospherically relevant conditions and mixture compositions. Focusing on atmospheric applications we considered H^+, Li^+, Na^+, K^+, NH^+_4, Mg^(2+), Ca^(2+), Cl^−, Br^−, NO^−_3, HSO^−_4, and SO^(2−)_4 as cations and anions and a wide range of alcohols/polyols composed of the functional groups CH_n and OH as organic compounds. With AIOMFAC, the activities of the components within an aqueous electrolyte solution are well represented up to high ionic strength. Most notably, a semi-empirical middle-range parametrisation of direct organic-inorganic interactions in alcohol+water+salt solutions strongly improves the agreement between experimental and modelled activity coefficients. At room temperature, this novel thermodynamic model offers the possibility to compute equilibrium relative humidities, gas/particle partitioning and liquid-liquid phase separations with high accuracy. In further studies, other organic functional groups will be introduced. The model framework is not restricted to specific ions or organic compounds and is therefore also applicable for other research topics

Corrigendum to "A thermodynamic model of mixed organic–inorganic aerosols to predict activity coefficients" published in Atmos. Chem. Phys., 8, 4559–4593, 2008

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Flavor-Symmetry Restoration and Symanzik Improvement for Staggered Quarks

We resolve contradictions in the literature concerning the origins and size of unphysical flavor-changing strong interactions generated by the staggered-quark discretization of QCD. We show that the leading contributions are tree-level in \order(a^2) and that they can be removed by adding three correction terms to the link operator in the standard action. These corrections are part of the systematic Symanzik improvement of the staggered-quark action. We present a new improved action for staggered quarks that is accurate up to errors of \order(a^4,a^2\alpha_s) --- more accurate than most, if not all, other discretizations of light-quark dynamics.Comment: 7 page

SAGE II Measurements of Stratospheric Aerosol Properties at Non-Volcanic Levels

Since 2000, stratospheric aerosol levels have been relatively stable and at the lowest levels observed in the historical record. Given the challenges of making satellite measurements of aerosol properties at these levels, we have performed a study of the sensitivity of the product to the major components of the processing algorithm used in the production of SAGE II aerosol extinction measurements and the retrieval process that produces the operational surface area density (SAD) product. We find that the aerosol extinction measurements, particularly at 1020 nm, remain robust and reliable at the observed aerosol levels. On the other hand, during background periods, the SAD operational product has an uncertainty of at least a factor of 2 during due to the lack of sensitivity to particles with radii less than 100 nm

The impact of cirrus clouds on tropical troposphere-to-stratosphere transport

International audienceAlthough it is well known that air enters the stratosphere preferentially through upwelling in the tropics, the exact mechanisms of troposphere-to-stratosphere transport (TST) are still unknown. Previously proposed mechanisms have been found either to be too slow (e.g., clear sky upwelling) to provide agreement with in situ tracer measurements, or to be insufficient in mass flux to act as a major supply for the Brewer-Dobson circulation (e.g., convective overshooting). In this study we evaluate whether the lofting of air via cirrus cloud-radiation interaction might offer an alternative path for TST, which is responsible for a significant fraction of the observed air mass transport. We find that a combination of deep convection and subsequent upwelling associated with cirrus clouds and clear sky can explain the supply of air for the Brewer-Dobson circulation. Thus, upwelling associated with cirrus clouds offers a mechanism for the missing second stage, which links the first stage of TST, deep convection, to the third stage, the Brewer-Dobson circulation

Analysis of electromagnetic interference from power system processing and transmission components for Space Station Freedom

The goal of this research project was to analyze the potential effects of electromagnetic interference (EMI) originating from power system processing and transmission components for Space Station Freedom. The approach consists of four steps: (1) developing analytical tools (models and computer programs); (2) conducting parameterization (what if?) studies; (3) predicting the global space station EMI environment; and (4) providing a basis for modification of EMI standards

A novel model to predict the physical state of atmospheric H2SO4/NH3/H2O aerosol particles

Colberg CA, Luo BP, Wernli H, Koop T, Peter T. A novel model to predict the physical state of atmospheric H2SO4/NH3/H2O aerosol particles. ATMOSPHERIC CHEMISTRY AND PHYSICS. 2003;3(4):909-924.The physical state of the tropospheric aerosol is largely unknown despite its importance for cloud formation and for the aerosol's radiative properties. Here we use detailed microphysical laboratory measurements to perform a systematic global modelling study of the physical state of the H2SO4/NH3/H2O aerosol, which constitutes an important class of aerosols in the free troposphere. The Aerosol Physical State Model (APSM) developed here is based on Lagrangian trajectories computed from ECMWF (European Centre for Medium Range Weather Forecasts) analyses, taking full account of the deliquescence/efflorescence hysteresis. As input APSM requires three data sets: (i) deliquescence and efflorescence relative humidities from laboratory measurements, (ii) ammonia-to-sulfate ratios (ASR) calculated by a global circulation model, and (iii) relative humidities determined from the ECMWF analyses. APSM results indicate that globally averaged a significant fraction (17-57%) of the ammoniated sulfate aerosol particles contain solids with the ratio of solid-containing to purely liquid particles increasing with altitude (between 2 and 10 km). In our calculations the most abundant solid is letovicite, (NH4)(3)H(SO4)(2), while there is only little ammonium sulfate, (NH4)(2)SO4. Since ammonium bisulfate, NH4HSO4, does not nucleate homogeneously, it can only form via heterogeneous crystallization. As the ammonia-to-sulfate ratios of the atmospheric H2SO4/NH3/H2O aerosol usually do not correspond to the stoichiometries of known crystalline substances, all solids are expected to occur in mixed-phase aerosol particles. This work highlights the potential importance of letovicite, whose role as cloud condensation nucleus (CCN) and as scatterer of solar radiation remains to be scrutinized

Further constraints on electron acceleration in solar noise storms

We reexamine the energetics of nonthermal electron acceleration in solar noise storms. A new result is obtained for the minimum nonthermal electron number density required to produce a Langmuir wave population of sufficient intensity to power the noise storm emission. We combine this constraint with the stochastic electron acceleration formalism developed by Subramanian & Becker (2005) to derive a rigorous estimate for the efficiency of the overall noise storm emission process, beginning with nonthermal electron acceleration and culminating in the observed radiation. We also calculate separate efficiencies for the electron acceleration -- Langmuir wave generation stage and the Langmuir wave -- noise storm production stage. In addition, we obtain a new theoretical estimate for the energy density of the Langmuir waves in noise storm continuum sources.Comment: Accepted for publication in Solar Physic

Deep+Wide Lensing Surveys will Provide Exquisite Measurements of the Dark Matter Halos of Dwarf Galaxies

The advent of new deep+wide photometric lensing surveys will open up the possibility of direct measurements of the dark matter halos of dwarf galaxies. The HSC wide survey will be the first with the statistical capability of measuring the lensing signal with high signal-to-noise at log(M*)=8. At this same mass scale, LSST will have the most overall constraining power with a predicted signal-to-noise for the galaxy-galaxy lensing signal around dwarfs of SN=200. WFIRST and LSST will have the greatest potential to push below the log(M*) = 7 mass scale thanks to the depth of their imaging data. Studies of the dark matter halos of dwarf galaxies at z=0.1 with gravitational lensing are soon within reach. However, further work will be required to develop optimized strategies for extracting dwarfs samples from these surveys, determining redshifts, and accurately measuring lensing on small radial scales. Dwarf lensing will be a new and powerful tool to constrain the halo masses and inner density slopes of dwarf galaxies and to distinguish between baryonic feedback and modified dark matter scenarios

Climatological and radiative properties of midlatitude cirrus clouds derived by automatic evaluation of lidar measurements

Cirrus, i.e., high, thin clouds that are fully glaciated, play an important role in the Earth's radiation budget as they interact with both long- and shortwave radiation and affect the water vapor budget of the upper troposphere and stratosphere. Here, we present a climatology of midlatitude cirrus clouds measured with the same type of ground-based lidar at three midlatitude research stations: at the Swiss high alpine Jungfraujoch station (3580 m a.s.l.), in Zürich (Switzerland, 510 m a.s.l.), and in Jülich (Germany, 100 m a.s.l.). The analysis is based on 13 000 h of measurements from 2010 to 2014. To automatically evaluate this extensive data set, we have developed the Fast LIdar Cirrus Algorithm (FLICA), which combines a pixel-based cloud-detection scheme with the classic lidar evaluation techniques. We find mean cirrus optical depths of 0.12 on Jungfraujoch and of 0.14 and 0.17 in Zürich and Jülich, respectively. Above Jungfraujoch, subvisible cirrus clouds (τ < 0.03) have been observed during 6 % of the observation time, whereas above Zürich and Jülich fewer clouds of that type were observed. Cirrus have been observed up to altitudes of 14.4 km a.s.l. above Jungfraujoch, whereas they have only been observed to about 1 km lower at the other stations. These features highlight the advantage of the high-altitude station Jungfraujoch, which is often in the free troposphere above the polluted boundary layer, thus enabling lidar measurements of thinner and higher clouds. In addition, the measurements suggest a change in cloud morphology at Jungfraujoch above ∼ 13 km, possibly because high particle number densities form in the observed cirrus clouds, when many ice crystals nucleate in the high supersaturations following rapid uplifts in lee waves above mountainous terrain. The retrieved optical properties are used as input for a radiative transfer model to estimate the net cloud radiative forcing, CRFNET, for the analyzed cirrus clouds. All cirrus detected here have a positive CRFNET. This confirms that these thin, high cirrus have a warming effect on the Earth's climate, whereas cooling clouds typically have cloud edges too low in altitude to satisfy the FLICA criterion of temperatures below −38 °C. We find CRFNET = 0.9 W m−2 for Jungfraujoch and 1.0 W m−2 (1.7 W m−2) for Zürich (Jülich). Further, we calculate that subvisible cirrus (τ < 0.03) contribute about 5 %, thin cirrus (0.03 < τ < 0.3) about 45 %, and opaque cirrus (0.3 < τ) about 50 % of the total cirrus radiative forcing