43 research outputs found

    Blacklisting as Foreign Policy: The Politics and Law of Listing Terror States

    Get PDF
    Lithium-ion batteries are today finding use in automobiles aiming at reducing fuel consumption and emissions within transportation. The requirements on batteries used in vehicles are high regarding performance and lifetime, and a better understanding of the interior processes that dictate energy and power capabilities is a key to strategic development. This thesis concerns aging in lithium-ion cells using electrochemical tools to characterize electrode and electrolyte properties that affect performance and performance loss in the cells.   A central difficulty regarding battery aging is to manage the coupled effects of temperature and cycling conditions on the various degradation processes that determine the lifetime of a cell. In this thesis, post-mortem analyses on harvested electrode samples from small pouch cells and larger cylindrical cells aged under different conditions form the basis of aging evaluation. The characterization is focused on electrochemical impedance spectroscopy (EIS) measurements and physics-based EIS modeling supported by several material characterization techniques to investigate degradation in terms of properties that directly affect performance. The results suggest that increased temperature alter electrode degradation and limitations relate in several cases to electrolyte transport. Variations in electrode properties sampled from different locations in the cylindrical cells show that temperature and current distributions from cycling cause uneven material utilization and aging, in several dimensions. The correlation between cell performance and localized utilization/degradation is an important aspect in meeting the challenges of battery aging in vehicle applications.   The use of in-situ nuclear magnetic resonance (NMR) imaging to directly capture the development of concentration gradients in a battery electrolyte during operation is successfully demonstrated. The salt diffusion coefficient and transport number for a sample electrolyte are obtained from Li+ concentration profiles using a physics-based mass-transport model. The method allows visualization of performance limitations and can be a useful tool in the study of electrochemical systems.QC 20140512</p

    The K spectra of element 61 /

    No full text
    The K lines of the x-ray spectra of element 61 were obtained on a transmission type spectrograph. The wavelength of the lines and the experimental method is discussed. X-ray spectra have been widely used in establishing positive identification of the elements from the time of Moseley's first investigations. It is known that x-ray spectra are simple and that wavelengths can be readily calculated from the Moseley law.Work performed at the Carbide and Carbon Chemicals Corporation."Date Declassified: July 9, 1948."Includes bibliographical references (p. 6).The K lines of the x-ray spectra of element 61 were obtained on a transmission type spectrograph. The wavelength of the lines and the experimental method is discussed. X-ray spectra have been widely used in establishing positive identification of the elements from the time of Moseley's first investigations. It is known that x-ray spectra are simple and that wavelengths can be readily calculated from the Moseley law.Mode of access: Internet

    Demonstration of programmable optical pulse pattern generator for 100 Gbit/s networks

    No full text
    A programmable 100 Gbit/s optical pulse pattern generator based on planar silica delay lines and semiconductor laser amplifier switches is demonstrated experimentally. The technology has key applications in ultrafast all-optical networks
    corecore