2,586 research outputs found
DFT Calculations as a Tool to Analyse Quadrupole Splittings of Spin Crossover Fe(II) complexes
Density functional methods have been applied to calculate the quadrupole
splitting of a series of iron(II) spin crossover complexes. Experimental and
calculated values are in reasonable agreement. In one case spin-orbit coupling
is necessary to explain the very small quadrupole splitting value of 0.77 mm/s
at 293 K for a high-spin isomer
Low-temperature magnetization in geometrically frustrated Tb2Ti2O7
The nature of the low temperature ground state of the pyrochlore compound
Tb2Ti2O7 remains a puzzling issue. Dynamic fluctuations and short-range
correlations persist down to 50 mK, as evidenced by microscopic probes. In
parallel, magnetization measurements show irreversibilities and glassy behavior
below 200 mK. We have performed magnetization and AC susceptibility
measurements on four single crystals down to 57 mK. We did not observe a clear
plateau in the magnetization as a function of field along the [111] direction,
as suggested by the quantum spin ice model. In addition to a freezing around
200 mK, slow dynamics are observed in the AC susceptibility up to 4 K. The
overall frequency dependence cannot be described by a canonical spin-glass
behavior.Comment: 5 pages, 4 figures + Supp. Mat (3 pages, 5 figures
Conservative Quantum Computing
Conservation laws limit the accuracy of physical implementations of
elementary quantum logic gates. If the computational basis is represented by a
component of spin and physical implementations obey the angular momentum
conservation law, any physically realizable unitary operators with size less
than n qubits cannot implement the controlled-NOT gate within the error
probability 1/(4n^2), where the size is defined as the total number of the
computational qubits and the ancilla qubits. An analogous limit for bosonic
ancillae is also obtained to show that the lower bound of the error probability
is inversely proportional to the average number of photons. Any set of
universal gates inevitably obeys a related limitation with error probability
O(1/n^2)$. To circumvent the above or related limitations yielded by
conservation laws, it is recommended that the computational basis should be
chosen as the one commuting with the additively conserved quantities.Comment: 5 pages, RevTex. Corrected to include a new statement that for
bosonic ancillae the lower bound of the error probability is inversely
proportional to the average number of photons, kindly suggested by Julio
Gea-Banacloch
Delta-like and gtl2 are reciprocally expressed, differentially methylated linked imprinted genes on mouse chromosome 12
AbstractThe distal portion of mouse chromosome 12 is imprinted. To date, however, Gtl2 is the only imprinted gene identified on chromosome 12. Gtl2 encodes multiple alternatively spliced transcripts with no apparent open reading frame. Using conceptuses with maternal or paternal uniparental disomy for chromosome 12 (UPD12), we found that Gtl2 is expressed from the maternal allele and methylated at the 5′ end of the silent paternal allele. A reciprocally imprinted gene, Delta-like (Dlk), with homology to genes involved in the Notch signalling pathway was identified 80kb upstream of Gtl2. Dlk was expressed exclusively from the paternal allele in both the embryo and placenta, but the CpG-island promoter of Dlk was completely unmethylated on both parental alleles. Rather, a paternally methylated region was identified in the last exon of the active Dlk allele. The proximity, reciprocal imprinting and methylation in this domain are reminiscent of the co-ordinately regulated Igf2–H19 imprinted domain on mouse chromosome 7. Like H19 and Igf2, Gtl2 and Dlk were found to be co-expressed in the same tissues throughout development, though not after birth. These results have implications for the regulation, function and evolution of imprinted domains
The question of declining sperm density revisited: an analysis of 101 studies published 1934-1996.
In 1992 Carlsen et al. reported a significant global decline in sperm density between 1938 and 1990 [Evidence for Decreasing Quality of Semen during Last 50 Years. Br Med J 305:609-613 (1992)]. We subsequently published a reanalysis of the studies included by Carlsen et al. [Swan et al. Have Sperm Densities Declined? A Reanalysis of Global Trend Data. Environ Health Perspect 105:1228-1232 (1997)]. In that analysis we found significant declines in sperm density in the United States and Europe/Australia after controlling for abstinence time, age, percent of men with proven fertility, and specimen collection method. The declines in sperm density in the United States (approximately 1.5%/year) and Europe/Australia (approximately 3%/year) were somewhat greater than the average decline reported by Carlsen et al. (approximately 1%/year). However, we found no decline in sperm density in non-Western countries, for which data were very limited. In the current study, we used similar methods to analyze an expanded set of studies. We added 47 English language studies published in 1934-1996 to those we had analyzed previously. The average decline in sperm count was virtually unchanged from that reported previously by Carlsen et al. (slope = -0.94 vs. -0.93). The slopes in the three geographic groupings were also similar to those we reported earlier. In North America, the slope was somewhat less than the slope we had found for the United States (slope = -0.80; 95% confidence interval (CI), -1.37--0.24). Similarly, the decline in Europe (slope = -2.35; CI, -3.66--1.05) was somewhat less than reported previously. As before, studies from other countries showed no trend (slope = -0.21; CI, -2.30-1.88). These results are consistent with those of Carlsen et al. and our previous results, suggesting that the reported trends are not dependent on the particular studies included by Carlsen et al. and that the observed trends previously reported for 1938-1990 are also seen in data from 1934-1996
Domain Wall Spin Dynamics in Kagome Antiferromagnets
We report magnetization and neutron scattering measurements down to 60 mK on
a new family of Fe based kagome antiferromagnets, in which a strong local spin
anisotropy combined with a low exchange path network connectivity lead to
domain walls intersecting the kagome planes through strings of free spins.
These produce unfamiliar slow spin dynamics in the ordered phase, evolving from
exchange-released spin-flips towards a cooperative behavior on decreasing the
temperature, probably due to the onset of long-range dipolar interaction. A
domain structure of independent magnetic grains is obtained that could be
generic to other frustrated magnets.Comment: 5 pages, 4 figure
Secure, Autonomous, Intelligent Controller for Integrating Distributed Emergency Response Satellite Operations
This report describes a Secure, Autonomous, and Intelligent Controller for Integrating Distributed Emergency Response Satellite Operations. It includes a description of current improvements to existing Virtual Mission Operations Center technology being used by US Department of Defense and originally developed under NASA funding. The report also highlights a technology demonstration performed in partnership with the United States Geological Service for Earth Resources Observation and Science using DigitalGlobe(Registered TradeMark) satellites to obtain space-based sensor data
Crystal growth, structure and ferromagnetic properties of a Ce3Pt23Si11 single crystal
A high-quality single crystal of Ce3Pt23Si11 has been grown using the
Czochralski method. The crystal structure is presented and the chemical
composition has been checked using an electron microprobe analyzer.
Measurements of the electrical resistivity and magnetic susceptibility
performed at low temperature show a ferromagnetic transition at Tc = 0.44 K.Comment: 12 pages, 9 figure
Typical local measurements in generalised probabilistic theories: emergence of quantum bipartite correlations
What singles out quantum mechanics as the fundamental theory of Nature? Here
we study local measurements in generalised probabilistic theories (GPTs) and
investigate how observational limitations affect the production of
correlations. We find that if only a subset of typical local measurements can
be made then all the bipartite correlations produced in a GPT can be simulated
to a high degree of accuracy by quantum mechanics. Our result makes use of a
generalisation of Dvoretzky's theorem for GPTs. The tripartite correlations can
go beyond those exhibited by quantum mechanics, however.Comment: 5 pages, 1 figure v2: more details in the proof of the main resul
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