Diffusion-controlled and replacement microtextures in alkali feldspars from two pegmatites: Perth, Ontario and Keystone, South Dakota

Macro- and micro-perthitic microclines from pegmatites from Perth, Ontario (Wards catalogue 46 E 0510) and Keystone, South Dakota (Wards 46 E 5125) have been studied using light and electron microscopy. A sample of the type perthite from Perth, Ontario (Hunterian Museum, Glasgow, M2361) was compared using light microscopy. It differs in bulk composition and microtexture from the Wards sample. The Perth sample from Wards is a mesoperthite, with sub-periodic ~mm-thick albite veins near (100), with irregular surfaces. The microcline has regular tartan twins and formed from orthoclase by a continuous process. The Keystone sample is a microperthite, with non-periodic albite veins mainly in {110}. Irregular tartan twins, volumes of irregular microcline and subgrains suggest that the microcline formed by dissolution–reprecipitation. Microcline in both samples contains semicoherent cryptoperthitic albite films that formed after the development of tartan twins. The bulk compositions of these intergrowths imply exsolution below ~400°C. Diffusion parameters imply sustained heating for between 0.11 My at 400°C, 1.5 GPa and 8.4 My at 300°C, 1 GPa. Unrealistic times are required at 200°C. Subsequently, the crystals reacted with a fluid leading to replacive growth of the vein perthites. Unusually, Albite twin composition planes in replacive subgrains have sub-periodic dislocations, formed by coalescence of advancing growth twins. Processes that might lead to periodic, replacive intergrowths are discussed. The Perth and Keystone feldspars have been used for experimental work on dissolution during weathering and on anomalous thermoluminescence fading. Their microtextures make them unsuitable for obtaining properties that can be extrapolated to feldspars in general

Geology of the loch Ailsh complex, Assynt

The Loch Ailsh intrusion, Assynt, was interpreted by Phemister (1926) as a stratified laccolite, the basal ultrabasic, intermediate, and upper leucocratic portions being differentiated at depth and intruded separately. The whole complex rested on a thrust plane. The leuco-syenites are here divided into three intrusions, SI, S2 and S3. S3 is latest and roofs S1-2. Their contacts are sharp or gradational, when feldspars of S1-2 type are enclosed as xenocrysts in S3. Basic alkaline rocks form a discontinuous zone at the top of S2; calc-silicate rocks occur at the same horizon. Similar basic types grade into limestone xenoliths in the north of the intrusion. A magnetometer survey showed anomalies corresponding to the outcrop of the ultrabasic rocks allowing their continuation to be traced. The magnetic properties of these rocks require that the induced component of the magnetization be used in interpretation of the anomalies. They are caused by a steeply inclined sheet. Further ultrabasic masses were proved by excavation. Brief petrographic description of the rook types is made with modal data. Cell dimensions of pyroxenes from metamorphosed limestones and basic and ultrabasic types are identical. The mafic aggregates in the basic rocks represent the remains of material of metamorphic origin. The alkali feldspars are described in terms of their appearance in thin section, optic axial angle, bulk composition and X-ray powder and single crystal properties. They are low albite-microcline and low albite-orthoclase perthites in the compositional range Or(_27)-Or(_41). Only S1 and S2 have mono-clinic material in the potassium phase. There may be a systematic distribution of microcline obliquities with locality. Little modification of feldspars was found at contacts between syenites and xenocrysts preserve higher temperature features than host material. Minimum crystallization temperatures are suggested. The variation depended on concentration of volatiles during cooling. A mechanism is suggested for the metastable preservation of orthoclase. The ultrabasic rocks are a skarn between limestone and syenite. The basic alkaline rocks are hybrids of feldspathic magma contaminated by metamorphic material, and represent the remains of a roof to S2, disrupted by S3, The mass does not have a major thrust at its contacts and is a stock like body with stoping its mode of emplacement

Routine characterization and interpretation of complex alkali feldspar intergrowths

Almost all alkali feldspar crystals contain a rich inventory of exsolution, twin, and domain microtextures that form subsequent to crystal growth and provide a record of the thermal history of the crystal and often of its involvement in replacement reactions, sometimes multiple. Microtextures strongly influence the subsequent behavior of feldspars at low temperatures during diagenesis and weathering. They are central to the retention or exchange of trace elements and of radiogenic and stable isotopes. This review is aimed at petrologists and geochemists who wish to use alkali feldspar microtextures to solve geological problems or who need to understand how microtextures influence a particular process. We suggest a systematic approach that employs methods available in most well founded laboratories. The crystallographic relationships of complex feldspar intergrowths were established by the 1970s, mainly using single-crystal X-ray diffraction, but such methods give limited information on the spatial relationships of the different elements of the microtexture, or of the mode and chronology of their formation, which require the use of microscopy. We suggest a combination of techniques with a range of spatial resolution and strongly recommend the use of orientated sections. Sections cut parallel to the perfect (001) and (010) cleavages are the easiest to locate and most informative. Techniques described are light microscopy; scanning electron microscopy using both backscattered and secondary electrons, including the use of surfaces etched in the laboratory; electron-probe microanalysis and analysis by energy-dispersive spectrometry in a scanning electron microscope; transmission electron microscopy. We discuss the use of cathodoluminescence as an auxiliary technique, but do not recommend electron-backscattered diffraction for feldspar work. We review recent publications that provide examples of the need for great care and attention to pre-existing work in microtextural studies, and suggest several topics for future work

Carbon Brainprint Case Study: optimising defouling schedules for oil- refinerypreheat trains

In an oil refinery, crude oil is heated to 360-370°C before entering a distillation columnoperating at atmospheric pressure where the gas fraction and several liquid fractions withdifferent boiling points (e.g. gasoline, kerosene, diesel, gas oil, heavy gas oil) are separated off.The crude oil is heated in two stages. The preheat train - a series of heat exchangers - heats itfrom ambient temperature to about 270°C when it enters the furnace, known as the coil inlettemperature. The furnace then heats the oil to the temperature required for distillation.The purpose of the preheat train is to recover heat from the liquid products extracted in thedistillation column. Without this, 2-3% of the crude oil throughput would be used for heating thefurnace; with the preheat train up to 70% of the required heat is recovered. It also serves tocool the refined products: further cooling normally uses air or water. Over time, fouling reduces the performance of the heat exchangers, increasing the amount ofenergy that has to be supplied. It is possible to bypass units to allow them to be cleaned, withan associated cost and temporary loss of performance. The cleaning schedule thus has animpact on the overall efficiency, cost of operation and emissions. The group at the Department of Chemical Engineering and Biotechnology at Cambridgedeveloped a scheduling algorithm for this non-linear optimisation problem. It yields a good,though not-necessarily optimal, schedule and can handle additional constraints, such as thepresence of desalters with specific temperature requirements within the preheat train. This isnow being developed into a commercial software product. Data from two refineries - one operated by Repsol YPF in Argentina and the Esso FawleyRefinery in the UK - were used to model the systems and test the algorithm. For the Repsol YPF refinery, when compared with current practice and including a constrainton the desalter inlet temperature, the most conservative estimate of the emissions reductionwas 773 t CO2/year. This assumed a furnace efficiency of 90%. The emissions reductionincreased to 927 t CO2/year at 75% efficiency and 1730 t CO2/year at 40%. These were basedon a stoichiometric estimate of the emissions from the furnace. Using a standard emissionfactor increased them by 7.4%. For Esso Fawley, the estimated emission reduction compared to no maintenance was1435 t CO2/year at 90% furnace efficiency. This increased to 1725 t CO2/year at 75% and3225 t CO2/year at 40% efficien

Gas distribution in shallow packed beds

Packed beds have many industrial applications and are increasingly used in the process industries due to their low pressure drop. With the introduction of more efficient packings, novel packing materials (i.e. adsorbents) and new applications (i.e. flue gas desulphurisation); the aspect ratio (height to diameter) of such beds is decreasing. Obtaining uniform gas distribution in such beds is of crucial importance in minimising operating costs and optimising plant performance. Since to some extent a packed bed acts as its own distributor the importance of obtaining uniform gas distribution has increased as aspect ratios (bed height to diameter) decrease. There is no rigorous design method for distributors due to a limited understanding of the fluid flow phenomena and in particular of the effect of the bed base / free fluid interface. This study is based on a combined theoretical and modelling approach. The starting point is the Ergun Equation which is used to determine the pressure drop over a bed where the flow is uni-directional. This equation has been applied in a vectorial form so it can be applied to maldistributed and multi-directional flows and has been realised in the Computational Fluid Dynamics code PHOENICS. The use of this equation and its application has been verified by modelling experimental measurements of maldistributed gas flows, where there is no free fluid / bed base interface. A novel, two-dimensional experiment has been designed to investigate the fluid mechanics of maldistributed gas flows in shallow packed beds. The flow through the outlet of the duct below the bed can be controlled, permitting a rigorous investigation. The results from this apparatus provide useful insights into the fluid mechanics of flow in and around a shallow packed bed and show the critical effect of the bed base. The PHOENICS/vectorial Ergun Equation model has been adapted to model this situation. The model has been improved by the inclusion of spatial voidage variations in the bed and the prescription of a novel bed base boundary condition. This boundary condition is based on the logarithmic law for velocities near walls without restricting the velocity at the bed base to zero and is applied within a turbulence model. The flow in a curved bed section, which is three-dimensional in nature, is examined experimentally. The effect of the walls and the changes in gas direction on the gas flow are shown to be particularly significant. As before, the relative amounts of gas flowing through the bed and duct outlet can be controlled. The model and improved understanding of the underlying physical phenomena form the basis for the development of new distributors and rigorous design methods for them

Gas distribution in shallow packed beds

Packed beds have many industrial applications and are increasingly used in the process industries due to their low pressure drop. With the introduction of more efficient packings, novel packing materials (i.e. adsorbents) and new applications (i.e. flue gas desulphurisation); the aspect ratio (height to diameter) of such beds is decreasing. Obtaining uniform gas distribution in such beds is of crucial importance in minimising operating costs and optimising plant performance. Since to some extent a packed bed acts as its own distributor the importance of obtaining uniform gas distribution has increased as aspect ratios (bed height to diameter) decrease. There is no rigorous design method for distributors due to a limited understanding of the fluid flow phenomena and in particular of the effect of the bed base / free fluid interface. This study is based on a combined theoretical and modelling approach. The starting point is the Ergun Equation which is used to determine the pressure drop over a bed where the flow is uni-directional. This equation has been applied in a vectorial form so it can be applied to maldistributed and multi-directional flows and has been realised in the Computational Fluid Dynamics code PHOENICS. The use of this equation and its application has been verified by modelling experimental measurements of maldistributed gas flows, where there is no free fluid / bed base interface. A novel, two-dimensional experiment has been designed to investigate the fluid mechanics of maldistributed gas flows in shallow packed beds. The flow through the outlet of the duct below the bed can be controlled, permitting a rigorous investigation. The results from this apparatus provide useful insights into the fluid mechanics of flow in and around a shallow packed bed and show the critical effect of the bed base. The PHOENICS/vectorial Ergun Equation model has been adapted to model this situation. The model has been improved by the inclusion of spatial voidage variations in the bed and the prescription of a novel bed base boundary condition. This boundary condition is based on the logarithmic law for velocities near walls without restricting the velocity at the bed base to zero and is applied within a turbulence model. The flow in a curved bed section, which is three-dimensional in nature, is examined experimentally. The effect of the walls and the changes in gas direction on the gas flow are shown to be particularly significant. As before, the relative amounts of gas flowing through the bed and duct outlet can be controlled. The model and improved understanding of the underlying physical phenomena form the basis for the development of new distributors and rigorous design methods for them

Marshall University Department of Music presents Art and Music

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Regional variations in the link between drought indices and reported agricultural impacts of drought

Drought has wide ranging impacts on all sectors. Despite much effort to identify the best drought indicator to represents the occurrence of drought impacts in a particular sector, there is still no consensus among the scientific community on this. Using a more detailed and extensive impact dataset than in previous studies, this paper assesses the regional relationship between drought impacts occurrence in British agriculture and two of the most commonly used drought indices (SPI and SPEI). The largest qualitative dataset on reported drought impacts on British agriculture for the period 1975–2012 spanning all major recent droughts was collated. Logistic regression using generalised additive models was applied to investigate the association between drought indices and reported impacts at the regional level. Results show that SPEI calculated for the preceding six months is the best indicator to predict the probability of drought impacts on agriculture in the UK, although the variation in the response to SPEI6 differed between regions. However, this variation appears to result both from the method by which SPEI is derived, which means that similar values of the index equate to different soil moisture conditions in wet and dry regions, and from the variation in agriculture between regions. The study shows that SPEI alone has limited value as an indicator of agricultural droughts in heterogeneous areas and that such results cannot be usefully extrapolated between regions. However, given the drought sensitivity of agriculture, the integration of regional predictions within drought monitoring and forecasting would help to reduce the large on-farm economic damage of drought and increase the sector's resilience to future drought