Carbonate Formation in Non-Aqueous Environments by Solid-Gas Carbonation of Silicates

We have produced synthetic analogues of cosmic silicates using the Sol Gel method, producing amorphous silicates of composition Mg(x)Ca(1-x)SiO3. Using synchrotron X-ray powder diffraction on Beamline I11 at the Diamond Light Source, together with a newly-commissioned gas cell, real-time powder diffraction scans have been taken of a range of silicates exposed to CO2 under non-ambient conditions. The SXPD is complemented by other techniques including Raman and Infrared Spectroscopy and SEM imaging.Comment: 5 pages, 3 figures. Contribution to the Proceedings of the First European Conference on Laboratory Astrophysics (ECLA

Transparent polymeric laminates

Laminate prepared from epoxy-boroxine and phenolphthalein polycarbonate has high mechanical strength at elevated temperature and is resistant to impact, fire, and high-energy thermal radiation. Polycarbonate is prepared by reaction of phenolphthalein with phosgene in presence of amine catalyst and immiscible organic solvent phase

The Generation of Magnetic Fields Through Driven Turbulence

We have tested the ability of driven turbulence to generate magnetic field structure from a weak uniform field using three dimensional numerical simulations of incompressible turbulence. We used a pseudo-spectral code with a numerical resolution of up to $144^3$ collocation points. We find that the magnetic fields are amplified through field line stretching at a rate proportional to the difference between the velocity and the magnetic field strength times a constant. Equipartition between the kinetic and magnetic energy densities occurs at a scale somewhat smaller than the kinetic energy peak. Above the equipartition scale the velocity structure is, as expected, nearly isotropic. The magnetic field structure at these scales is uncertain, but the field correlation function is very weak. At the equipartition scale the magnetic fields show only a moderate degree of anisotropy, so that the typical radius of curvature of field lines is comparable to the typical perpendicular scale for field reversal. In other words, there are few field reversals within eddies at the equipartition scale, and no fine-grained series of reversals at smaller scales. At scales below the equipartition scale, both velocity and magnetic structures are anisotropic; the eddies are stretched along the local magnetic field lines, and the magnetic energy dominates the kinetic energy on the same scale by a factor which increases at higher wavenumbers. We do not show a scale-free inertial range, but the power spectra are a function of resolution and/or the imposed viscosity and resistivity. Our results are consistent with the emergence of a scale-free inertial range at higher Reynolds numbers.Comment: 14 pages (8 NEW figures), ApJ, in press (July 20, 2000?

Series-hybrid bearing - An approach to extending bearing fatigue life at high speeds

Fluid film bearing of hybrid device consists of orifice compensated annular thrust bearing and self-acting journal bearing. In series hybrid bearing, both ball bearing and annular thrust bearing carry full system thrust load, but two bearings share speed. Operation of system is stable and automatically fail-safe

Hawking radiation by Kerr black holes and conformal symmetry

The exponential blueshift associated with the event horizon of a black hole makes conformal symmetry play a fundamental role in accounting for its thermal properties. Using a derivation based on two-point functions, we show that the spectrum of thermal radiation of scalar particles by Kerr (and Schwarzschild) black holes can be explicitly derived on the basis of a $2$-dimensional conformal symmetry arising in the wave equation near the horizon. This result reinforces the recently conjectured relation between Kerr geometry and a $2$-dimensional conformal field theory.Comment: Version published in Phys. Rev. Let

In situ apparatus for the study of clathrate hydrates relevant to solar system bodies using synchrotron X-ray diffraction and Raman spectroscopy

Clathrate hydrates are believed to play a significant role in various solar system environments, e.g. comets, and the surfaces and interiors of icy satellites, however the structural factors governing their formation and dissociation are poorly understood. We demonstrate the use of a high pressure gas cell, combined with variable temperature cooling and time-resolved data collection, to the in situ study of clathrate hydrates under conditions relevant to solar system environments. Clathrates formed and processed within the cell are monitored in situ using synchrotron X-ray powder diffraction and Raman spectroscopy. X-ray diffraction allows the formation of clathrate hydrates to be observed as CO2 gas is applied to ice formed within the cell. Complete conversion is obtained by annealing at temperatures just below the ice melting point. A subsequent rise in the quantity of clathrate is observed as the cell is thermally cycled. Four regions between 100-5000cm-1 are present in the Raman spectra that carry features characteristic of both ice and clathrate formation. This novel experimental arrangement is well suited to studying clathrate hydrates over a range of temperature (80-500K) and pressure (1-100bar) conditions and can be used with a variety of different gases and starting aqueous compositions. We propose the increase in clathrate formation observed during thermal cycling may be due to the formation of a quasi liquid-like phase that forms at temperatures below the ice melting point, but which allows easier formation of new clathrate cages, or the retention and delocalisation of previously formed clathrate structures, possibly as amorphous clathrate. The structural similarities between hexagonal ice, the quasi liquid-like phase, and crystalline CO2 hydrate mean that differences in the Raman spectrum are subtle; however, all features out to 5000cm-1 are diagnostic of clathrate structure.Comment: Astronomy & Astrophysics, in press. 6 page