629 research outputs found
Spectroelectrochemical characterisation of a poly[Ni(saltMe)] modified electrode
Electrogenerated polymers based on the nickel(II) compIex 2,3-dimetbyl- N,N -bis(salicylidene )butane-2,3- diaminatoniekel(II), poly[Ni(saltMe)], were characterized by in situ FTIR and UV/Vis spectroscopy and ex-situ EPR spectroscopy in order to gain insights into film structure, electronic states and charge conduction. The role of the nickel ions during film oxidation was probed by using EPR to study naturally abundant Ni and 61Ni-enriehed polymers
Automated Hippocampal Segmentation by Regional Fluid Registration of Serial MRI: Validation and Application in Alzheimer.s Disease
The application of voxel-level three-dimensional registration to serial magnetic resonance imaging (MRI) is described. This fluid registration determines deformation fields modeling brain change, which are consistent with a model describing a viscous fluid. The objective was to validate the measurement of hippocampal volumetric change by fluid registration in Alzheimer's disease (AD) against current methodologies. The hippocampus was chosen for this study because it is difficult to measure reproducibly by manual segmentation and is widely studied; however, the technique is applicable to any structure which can be delineated on a scan. First, suitable values for the viscosity-body-force-ratio, alpha (0.01), and the number of iterations (300), were established and the convergence, repeatability, linearity, and accuracy investigated and compared with expert manual segmentation. A simple model of hippocampal atrophy was used to compare simulated volumetric change against that obtained by fluid registration. Finally the serial segmentation was compared with the current gold standard technique-expert human labeling with a volume repeatability of similar to4%-in 27 subjects (15 normal controls, 12 clinically diagnosed with Alzheimer's disease). The scan-rescan volumetric consistency of serial segmentation by fluid-registration was shown to be superior to human serial segmentors (similar to2%). The mean absolute volume difference between fluid and manual segmentation was 0.7%. Fluid registration has potential importance for tracking longitudinal structural changes in brain particularly in the context of the clinical trial where large numbers of subjects may have multiple MR scans. (C) 2001 Academic Press
Synthesis and electrochemical characterization of Si/TiO2/Au composite anode: Efficient oxygen evolution and hydroxyl radicals generation
This paper describes the photoelectrochemical properties of a novel composite anode composed of a 200 nm Au-Sb ohmic contact/300 μm n-Si wafer/20 nm TiO2 /120 nm Au grid. By connecting the Au ohmic contact to the gold grid via a power supply, holes thermally or photochemically generated in the Si are launched to the TiO2 surface where they are converted to •OH radicals. We show that the Si/TiO2/Au composite anode can be efficiently employed in the oxygen evolution reaction and prove that the anode generates hydroxyl radicals (using p-nitrosodimethylaniline as a probe). Potential applications include the photoelectrocatalytic oxidation of organic contaminants, water splitting, and organic electro-synthesis
An assessment of the carbon balance of Arctic tundra:Comparisons among observations, process models, and atmospheric inversions
Although Arctic tundra has been estimated to cover only 8% of the global land surface, the large and potentially labile carbon pools currently stored in tundra soils have the potential for large emissions of carbon (C) under a warming climate. These emissions as radiatively active greenhouse gases in the form of both CO<sub>2</sub> and CH<sub>4</sub> could amplify global warming. Given the potential sensitivity of these ecosystems to climate change and the expectation that the Arctic will experience appreciable warming over the next century, it is important to assess whether responses of C exchange in tundra regions are likely to enhance or mitigate warming. In this study we compared analyses of C exchange of Arctic tundra between 1990 and 2006 among observations, regional and global applications of process-based terrestrial biosphere models, and atmospheric inversion models. Syntheses of flux observations and inversion models indicate that the annual exchange of CO<sub>2</sub> between Arctic tundra and the atmosphere has large uncertainties that cannot be distinguished from neutral balance. The mean estimate from an ensemble of process-based model simulations suggests that Arctic tundra has acted as a sink for atmospheric CO<sub>2</sub> in recent decades, but based on the uncertainty estimates it cannot be determined with confidence whether these ecosystems represent a weak or a strong sink. Tundra was 0.6 °C warmer in the 2000s compared to the 1990s. The central estimates of the observations, process-based models, and inversion models each identify stronger sinks in the 2000s compared with the 1990s. Some of the process models indicate that this occurred because net primary production increased more in response to warming than heterotrophic respiration. Similarly, the observations and the applications of regional process-based models suggest that CH<sub>4</sub> emissions from Arctic tundra have increased from the 1990s to 2000s because of the sensitivity of CH<sub>4</sub> emissions to warmer temperatures. Based on our analyses of the estimates from observations, process-based models, and inversion models, we estimate that Arctic tundra was a sink for atmospheric CO<sub>2</sub> of 110 Tg C yr<sup>−1</sup> (uncertainty between a sink of 291 Tg C yr<sup>−1</sup> and a source of 80 Tg C yr<sup>−1</sup>) and a source of CH<sub>4</sub> to the atmosphere of 19 Tg C yr<sup>−1</sup> (uncertainty between sources of 8 and 29 Tg C yr<sup>−1</sup>). The suite of analyses conducted in this study indicate that it is important to reduce uncertainties in the observations, process-based models, and inversions in order to better understand the degree to which Arctic tundra is influencing atmospheric CO<sub>2</sub> and CH<sub>4</sub> concentrations. The reduction of uncertainties can be accomplished through (1) the strategic placement of more CO<sub>2</sub> and CH<sub>4</sub> monitoring stations to reduce uncertainties in inversions, (2) improved observation networks of ground-based measurements of CO<sub>2</sub> and CH<sub>4</sub> exchange to understand exchange in response to disturbance and across gradients of climatic and hydrological variability, and (3) the effective transfer of information from enhanced observation networks into process-based models to improve the simulation of CO<sub>2</sub> and CH<sub>4</sub> exchange from Arctic tundra to the atmosphere
Punctuated equilibria and 1/f noise in a biological coevolution model with individual-based dynamics
We present a study by linear stability analysis and large-scale Monte Carlo
simulations of a simple model of biological coevolution. Selection is provided
through a reproduction probability that contains quenched, random interspecies
interactions, while genetic variation is provided through a low mutation rate.
Both selection and mutation act on individual organisms. Consistent with some
current theories of macroevolutionary dynamics, the model displays
intermittent, statistically self-similar behavior with punctuated equilibria.
The probability density for the lifetimes of ecological communities is well
approximated by a power law with exponent near -2, and the corresponding power
spectral densities show 1/f noise (flicker noise) over several decades. The
long-lived communities (quasi-steady states) consist of a relatively small
number of mutualistically interacting species, and they are surrounded by a
``protection zone'' of closely related genotypes that have a very low
probability of invading the resident community. The extent of the protection
zone affects the stability of the community in a way analogous to the height of
the free-energy barrier surrounding a metastable state in a physical system.
Measures of biological diversity are on average stationary with no discernible
trends, even over our very long simulation runs of approximately 3.4x10^7
generations.Comment: 20 pages RevTex. Minor revisions consistent with published versio
Noise Kernel and Stress Energy Bi-Tensor of Quantum Fields in Hot Flat Space and Gaussian Approximation in the Optical Schwarzschild Metric
Continuing our investigation of the regularization of the noise kernel in
curved spacetimes [N. G. Phillips and B. L. Hu, Phys. Rev. D {\bf 63}, 104001
(2001)] we adopt the modified point separation scheme for the class of optical
spacetimes using the Gaussian approximation for the Green functions a la
Bekenstein-Parker-Page. In the first example we derive the regularized noise
kernel for a thermal field in flat space. It is useful for black hole
nucleation considerations. In the second example of an optical Schwarzschild
spacetime we obtain a finite expression for the noise kernel at the horizon and
recover the hot flat space result at infinity. Knowledge of the noise kernel is
essential for studying issues related to black hole horizon fluctuations and
Hawking radiation backreaction. We show that the Gaussian approximated Green
function which works surprisingly well for the stress tensor at the
Schwarzschild horizon produces significant error in the noise kernel there. We
identify the failure as occurring at the fourth covariant derivative order.Comment: 21 pages, RevTeX
Gravitons in One-Loop Quantum Cosmology: Correspondence Between Covariant and Non-Covariant Formalisms
The discrepancy between the results of covariant and non-covariant one-loop
calculations for higher-spin fields in quantum cosmology is analyzed. A
detailed mode-by-mode study of perturbative quantum gravity about a flat
Euclidean background bounded by two concentric 3-spheres, including
non-physical degrees of freedom and ghost modes, leads to one-loop amplitudes
in agreement with the covariant Schwinger-DeWitt method. This calculation
provides the generalization of a previous analysis of fermionic fields and
electromagnetic fields at one-loop about flat Euclidean backgrounds admitting a
well-defined 3+1 decomposition.Comment: 29 pages, latex, recently appearing in Physical Review D, volume 50,
pages 6329-6337, November 1994. The authors apologize for the delay in
circulating the paper, due to technical problems now fixe
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