Protecting clean critical points by local disorder correlations

We show that a broad class of quantum critical points can be stable against locally correlated disorder even if they are unstable against uncorrelated disorder. Although this result seemingly contradicts the Harris criterion, it follows naturally from the absence of a random-mass term in the associated order-parameter field theory. We illustrate the general concept with explicit calculations for quantum spin-chain models. Instead of the infinite-randomness physics induced by uncorrelated disorder, we find that weak locally correlated disorder is irrelevant. For larger disorder, we find a line of critical points with unusual properties such as an increase of the entanglement entropy with the disorder strength. We also propose experimental realizations in the context of quantum magnetism and cold-atom physics.Comment: 5 pages, 3 figures; published versio

Small volume expansion of almost supersymmetric large N theories

We consider the small-volume dynamics of nonsupersymmetric orbifold and orientifold field theories defined on a three-torus, in a test of the claimed planar equivalence between these models and appropriate supersymmetric ``parent models". We study one-loop effective potentials over the moduli space of flat connections and find that planar equivalence is preserved for suitable averages over the moduli space. On the other hand, strong nonlinear effects produce local violations of planar equivalence at special points of moduli space. In the case of orbifold models, these effects show that the "twisted" sector dominates the low-energy dynamics.Comment: 20 pages, 3 figures; added references, minor change

Multi-component symmetry-projected approach for molecular ground state correlations

The symmetry-projected Hartree--Fock ansatz for the electronic structure problem can efficiently account for static correlation in molecules, yet it is often unable to describe dynamic correlation in a balanced manner. Here, we consider a multi-component, systematically-improvable approach, that accounts for all ground state correlations. Our approach is based on linear combinations of symmetry-projected configurations built out of a set of non-orthogonal, variationally optimized determinants. The resulting wavefunction preserves the symmetries of the original Hamiltonian even though it is written as a superposition of deformed (broken-symmetry) determinants. We show how short expansions of this kind can provide a very accurate description of the electronic structure of simple chemical systems such as the nitrogen and the water molecules, along the entire dissociation profile. In addition, we apply this multi-component symmetry-projected approach to provide an accurate interconversion profile among the peroxo and bis($\mu$-oxo) forms of [Cu$_2$O$_2$]$^{2+}$, comparable to other state-of-the-art quantum chemical methods

Correlation amplitude and entanglement entropy in random spin chains

Using strong-disorder renormalization group, numerical exact diagonalization, and quantum Monte Carlo methods, we revisit the random antiferromagnetic XXZ spin-1/2 chain focusing on the long-length and ground-state behavior of the average time-independent spin-spin correlation function C(l)=\upsilon l^{-\eta}. In addition to the well-known universal (disorder-independent) power-law exponent \eta=2, we find interesting universal features displayed by the prefactor \upsilon=\upsilon_o/3, if l is odd, and \upsilon=\upsilon_e/3, otherwise. Although \upsilon_o and \upsilon_e are nonuniversal (disorder dependent) and distinct in magnitude, the combination \upsilon_o + \upsilon_e = -1/4 is universal if C is computed along the symmetric (longitudinal) axis. The origin of the nonuniversalities of the prefactors is discussed in the renormalization-group framework where a solvable toy model is considered. Moreover, we relate the average correlation function with the average entanglement entropy, whose amplitude has been recently shown to be universal. The nonuniversalities of the prefactors are shown to contribute only to surface terms of the entropy. Finally, we discuss the experimental relevance of our results by computing the structure factor whose scaling properties, interestingly, depend on the correlation prefactors.Comment: v1: 16 pages, 15 figures; v2: 17 pages, improved discussions and statistics, references added, published versio

Cómo determinar los Parámetros de la Ecuación General de una Cuádrica a través de la Visualización

Las ecuaciones generales de las cuádricas en su forma general presentan un grado de dificultad al momento de determinar a qué tipo de cuádrica pertenece. En este sentido, la visualización juega un papel importante en la determinación y relación de la ecuación con su respectiva gráfica, dado que, al realizar una manipulación algebraica sobre la ecuación canónica de la superficie para transformarla a su forma general, se puede determinar por medio de la simple inspección de la ecuación general, no solamente a qué tipo de cuádrica pertenece, sino también se pueden determinar sus parámetros principale

Excited electronic states from a variational approach based on symmetry-projected Hartree--Fock configurations

Recent work from our research group has demonstrated that symmetry-projected Hartree--Fock (HF) methods provide a compact representation of molecular ground state wavefunctions based on a superposition of non-orthogonal Slater determinants. The symmetry-projected ansatz can account for static correlations in a computationally efficient way. Here we present a variational extension of this methodology applicable to excited states of the same symmetry as the ground state. Benchmark calculations on the C$_2$ dimer with a modest basis set, which allows comparison with full configuration interaction results, indicate that this extension provides a high quality description of the low-lying spectrum for the entire dissociation profile. We apply the same methodology to obtain the full low-lying vertical excitation spectrum of formaldehyde, in good agreement with available theoretical and experimental data, as well as to a challenging model $C_{2v}$ insertion pathway for BeH$_2$. The variational excited state methodology developed in this work has two remarkable traits: it is fully black-box and will be applicable to fairly large systems thanks to its mean-field computational cost

Valence-bond theory of highly disordered quantum antiferromagnets

We present a large-N variational approach to describe the magnetism of insulating doped semiconductors based on a disorder-generalization of the resonating-valence-bond theory for quantum antiferromagnets. This method captures all the qualitative and even quantitative predictions of the strong-disorder renormalization group approach over the entire experimentally relevant temperature range. Finally, by mapping the problem on a hard-sphere fluid, we could provide an essentially exact analytic solution without any adjustable parameters.Comment: 5 pages, 3 eps figure

Proper and improper zero energy modes in Hartree-Fock theory and their relevance for symmetry breaking and restoration

We study the spectra of the molecular orbital Hessian (stability matrix) and random-phase approximation Hamiltonian of broken-symmetry Hartree-Fock solutions, focusing on zero eigenvalue modes. After all negative eigenvalues are removed from the Hessian by following their eigenvectors downhill, one is left with only positive and zero eigenvalues. Zero modes correspond to orbital rotations with no restoring force. These rotations determine states in the Goldstone manifold, which originates from a spontaneously broken continuous symmetry in the wave function. Zero modes can be classified as improper or proper according to their different mathematical and physical properties. Improper modes arise from symmetry breaking and their restoration always lowers the energy. Proper modes, on the other hand, correspond to degeneracies of the wave function, and their symmetry restoration does not necessarily lower the energy. We discuss how the RPA Hamiltonian distinguishes between proper and improper modes by doubling the number of zero eigenvalues associated with the latter. Proper modes in the Hessian always appear in pairs which do not double in RPA. We present several pedagogical cases exemplifying the above statements. The relevance of these results for projected Hartree-Fock methods is also addressed