A new stylolite classification scheme to estimate compaction and local permeability variations

This study was carried out within the framework of DGMK (German Society for Petroleum and Coal Science and Technology) research project 718 “Mineral Vein Dynamics Modeling”, which is funded by the companies ExxonMobil Production Deutschland GmbH, GDF SUEZ E&P Deutschland GmbH, DEA Deutsche Erdoel AG and Wintershall Holding GmbH, within the basic research program of the WEG Wirtschaftsverband Erdoel- und Erdgasgewinnung e.V. We thank the companies for their financial support and their permission to publish these results. This work has received funding from the European Union's Seventh Framework Programme for research, technological development and demonstration under grant agreement no 31688. The Zechstein data were collected with the help of Simon Gast. We thank Jean-Pierre Gratier and an anonymous reviewer for their comments that improved an earlier version of the manuscript.Peer reviewedPostprin

The Jabal Akhdar Dome in the Oman Mountains : evolution of a dynamic fracture system

Acknowledgments: This study was carried out within the framework of DGMK (German Society for Petroleum and Coal Science and Technology) research project 718 “Mineral Vein Dynamics Modelling,” which is funded by the companies ExxonMobil Production Deutschland GmbH, GDF SUEZ E&P Deutschland GmbH, RWE Dea AG and Wintershall Holding GmbH, within the basic research program of the WEG Wirtschaftsverband Erdo¨l- und Erdgasgewinnung e.V. We thank the companies for their financial support and their permission to publish these results. The German University of Technology in Oman (GU-Tech) is acknowledged for its logistic support. We gratefully acknowledge the reviewers Andrea Billi and Jean-Paul Breton, whose constructive reviews greatly improved the manuscriptPeer reviewedPreprin

Reactivity of dolomitizing fluids and Mg source evaluation of fault-controlled dolomitization at the Benicàssim outcrop analogue (Maestrat Basin, E Spain)

Peer reviewedPostprin

A new stylolite classification scheme to estimate compaction and local permeability variations

We modeled the geometrical roughening of bedding-parallel, mainly layer-dominated stylolites in order to understand their structural evolution, to present an advanced classification of stylolite shapes and to relate this classification to chemical compaction and permeability variations at stylolites. Stylolites are rough dissolution seams that develop in sedimentary basins during chemical compaction. In the Zechstein 2 carbonate units, an important lean gas reservoir in the southern Permian Zechstein basin in Germany, stylolites influence local fluid flow, mineral replacement reactions and hence the permeability of the reservoir. Our simulations demonstrate that layer-dominated stylolites can grow in three distinct stages: an initial slow nucleation phase, a fast layer-pinning phase and a final freezing phase if the layer is completely dissolved during growth. Dissolution of the pinning layer and thus destruction of the stylolite's compaction tracking capabilities is a function of the background noise in the rock and the dissolution rate of the layer itself. Low background noise needs a slower dissolving layer for pinning to be successful but produces flatter teeth than higher background noise. We present an advanced classification based on our simulations and separate stylolites into four classes: (1) rectangular layer type, (2) seismogram pinning type, (3) suture/sharp peak type and (4) simple wave-like type. Rectangular layer type stylolites are the most appropriate for chemical compaction estimates because they grow linearly and record most of the actual compaction (up to 40 mm in the Zechstein example). Seismogram pinning type stylolites also provide good tracking capabilities, with the largest teeth tracking most of the compaction. Suture/sharp peak type stylolites grow in a non-linear fashion and thus do not record most of the actual compaction. However, when a non-linear growth law is used, the compaction estimates are similar to those making use of the rectangular layer type stylolites. Simple wave-like stylolites are not useful for compaction estimates, since their growth is highly non-linear with a very low growth exponent. In the case where sealing material is collected at the tooth during dissolution, stylolites can act as barriers for local fluid flow as they intensify sealing capabilities of pinning layers. However, the development of teeth and spikes offsets and thus destroys continuous stylolite seams so that the permeability across the stylolite becomes very heterogeneous and they are no continuous barriers. This behavior is best shown in rectangular layer and seismogram pinning type stylolites that develop efficient fluid barriers at teeth tips but destroy sealing capabilities of layers by offsetting them at the flank, leading to a permeability anisotropy along 2-D stylolite planes. Suture/sharp peak stylolites can create fluid barriers if they collect enough sealing material. However, if the collecting material does not seal or if spikes offset the sealing material the stylolite leaks. We propose that our classification can be used to realistically estimate chemical compaction in reservoirs and gives an indication on how heterogeneous the permeability of stylolites can be

Effects of power tension and forms drive belt balancing products in process at zarezonansnom balancing machines pendulum

We developed two programs, "Vein Growth" and "Fringe Growth", to investigate progressive growth of crystals in dilation sites (veins and strain fringes). Even though these models are based on a simple anisotropic growth function, they produce complex textures that compare well with natural examples of veins and strain fringes. In our simulations the most important factor that controls the crystal shape in the dilation site is the roughness of the growth surface (defined by asperities on the wall-rock of veins or core-object of fringe structures) and the amplitude of these asperities relative to the width of the dilation site after an opening-event. Fibrous crystals (crystals with a high length to width ratio) which can track the opening trajectory of the dilation site will develop if grain boundaries of crystals are locked to asperities on the wall-rock of veins or core-object of fringes. This happens only if the amplitude of the asperities is large relative to single opening steps of the dilation site and if crystals grow fast enough to close the site. The width of fibres depends on the number of initial nuclei and on the distance of adjacent asperities on the wall-rock- or core-object surface. Our simulations suggest that single fibres should not be used for structural analysis especially in the case of strain fringes since relative rotation between fringes and core-object influences fibre-growth directions. We discuss the implications of our modelling results for the use of crystal textures in veins and strain fringes for structural analysis

The effect of dynamic recrystallisation on the rheology and microstructures of partially molten rocks

This work was founded by the joint project “Rheology of the continental crust in collision”, funded by the Procope scheme of PHC Egide in France and by the DAAD PPP scheme in Germany. M-GL acknowledges the support of the Juan de la Cierva programme of the Government of Spain’s Ministry for Science, Innovation and Universities. EGR acknowledges the support of the Beatriu de Pinós programme of the Government of Catalonia's Secretariat for Universities and Research of the Department of Economy and Knowledge (2016 BP 00208). This work benefited from discussions with Pi L. Jolivet and E. Burov within the ERC project RHEOLITH. We thank Elisabetta Mariani and Marcin Dabrowski for their helpful comments, together with the editorial guidance of Dave Healy and Bill Dunne.Peer reviewedPostprin

Serum sex hormone-binding globulin levels are reduced and inversely associated with intrahepatic lipid content and saturated fatty acid fraction in adult patients with glycogen storage disease type 1a

PURPOSE: De novo lipogenesis has been inversely associated with serum sex hormone-binding globulin (SHBG) levels. However, the directionality of this association has remained uncertain. We, therefore, studied individuals with glycogen storage disease type 1a (GSD1a), who are characterized by a genetic defect in glucose-6-phosphatase resulting in increased rates of de novo lipogenesis, to assess the downstream effect on serum SHBG levels. METHODS: A case-control study comparing serum SHBG levels in patients with GSD1a (n = 10) and controls matched for age, sex, and BMI (n = 10). Intrahepatic lipid content and saturated fatty acid fraction were quantified by proton magnetic resonance spectroscopy. RESULTS: Serum SHBG levels were statistically significantly lower in patients with GSD1a compared to the controls (p = 0.041), while intrahepatic lipid content and intrahepatic saturated fatty acid fraction-a marker of de novo lipogenesis-were significantly higher in patients with GSD1a (p = 0.001 and p = 0.019, respectively). In addition, there was a statistically significant, inverse association of intrahepatic lipid content and saturated fatty acid fraction with serum SHBG levels in patients and controls combined (β: - 0.28, 95% CI: - 0.47;- 0.09 and β: - 0.02, 95% CI: - 0.04;- 0.01, respectively). CONCLUSION: Patients with GSD1a, who are characterized by genetically determined higher rates of de novo lipogenesis, have lower serum SHBG levels than controls

Crystallographic preferred orientations of ice deformed in direct-shear experiments at low temperatures

Synthetic polycrystalline ice was sheared at temperatures of −5, −20 and −30&thinsp;∘C, to different shear strains, up to γ=2.6, equivalent to a maximum stretch of 2.94 (final line length is 2.94 times the original length). Cryo-electron backscatter diffraction (EBSD) analysis shows that basal intracrystalline slip planes become preferentially oriented parallel to the shear plane in all experiments, with a primary cluster of crystal c axes (the c axis is perpendicular to the basal plane) perpendicular to the shear plane. In all except the two highest-strain experiments at −30&thinsp;∘C, a secondary cluster of c axes is observed, at an angle to the primary cluster. With increasing strain, the primary c-axis cluster strengthens. With increasing temperature, both clusters strengthen. In the −5&thinsp;∘C experiments, the angle between the two clusters reduces with strain. The c-axis clusters are elongated perpendicular to the shear direction. This elongation increases with increasing shear strain and with decreasing temperature. Highly curved grain boundaries are more prevalent in samples sheared at higher temperatures. At each temperature, the proportion of curved boundaries decreases with increasing shear strain. Subgrains are observed in all samples. Microstructural interpretations and comparisons of the data from experimentally sheared samples with numerical models suggest that the observed crystallographic orientation patterns result from a balance of the rates of lattice rotation (during dislocation creep) and growth of grains by strain-induced grain boundary migration (GBM). GBM is faster at higher temperatures and becomes less important as shear strain increases. These observations and interpretations provide a hypothesis to be tested in further experiments and using numerical models, with the ultimate goal of aiding the interpretation of crystallographic preferred orientations in naturally deformed ice.</p

Aging impairs the osteocytic regulation of collagen integrity and bone quality

Poor bone quality is a major factor in skeletal fragility in elderly individuals. The molecular mechanisms that establish and maintain bone quality, independent of bone mass, are unknown but are thought to be primarily determined by osteocytes. We hypothesize that the age-related decline in bone quality results from the suppression of osteocyte perilacunar/canalicular remodeling (PLR), which maintains bone material properties. We examined bones from young and aged mice with osteocyte-intrinsic repression of TGFβ signaling (TβRI