Grand challenges in marine biogeochemistry

The ocean plays a central role in our earth's climate system and also provides a range of important ecosystem services, including food, energy, transport, and nutrient cycling. Marine biogeochemistry focuses on the study of complex biological, chemical, and physical processes involved in the cycling of key chemical elements within the ocean, and between the ocean and the seafloor, land and atmosphere. The ocean is increasingly perturbed by human induced alterations to our planet, including anthropogenic emissions of nitrogen, phosphorus, carbon and trace elements, and climate change. The establishment of a detailed understanding of biogeochemical processes, including their rates, is essential to the identification and assessment of climatic and chemical feedbacks associated with changes in the chemical and physical environment that are mediated through ocean biology, chemistry and physics. Important research areas in marine biogeochemistry involve the cycling of organic and inorganic forms of carbon, nitrogen and phosphorus, the cycling and biological roles of essential trace elements, and the fate and climatic impact of marine produced trace gases

Chemistry and mineralogy of clay minerals in Asian and Saharan dusts and the implications for iron supply to the oceans

Mineral dust supplied to remote ocean regions stimulates phytoplankton growth through delivery of micronutrients, notably iron (Fe). Although attention is usually paid to Fe (hydr)oxides as major sources of available Fe, Fe-bearing clay minerals are typically the dominant phase in mineral dust. The mineralogy and chemistry of clay minerals in dust particles, however, are largely unknown. We conducted microscopic identification and chemical analysis of the clay minerals in Asian and Saharan dust particles. Cross-sectional slices of dust particles were prepared by focused ion beam (FIB) techniques and analyzed by transmission electron microscopy (TEM) combined with energy dispersive X-ray spectroscopy (EDXS). TEM images of FIB slices revealed that clay minerals occurred as either nano-thin platelets or relatively thick plates. Chemical compositions and lattice fringes of the nano-thin platelets suggested that they included illite, smectite, illite–smectite mixed layers, and their nanoscale mixtures (illite–smectite series clay minerals, ISCMs) which could not be resolved with an electron microbeam. EDXS chemical analysis of the clay mineral grains revealed that the average Fe content was 5.8% in nano-thin ISCM platelets assuming 14% H2O, while the Fe content of illite and chlorite was 2.8 and 14.8%, respectively. In addition, TEM and EDXS analyses were performed on clay mineral grains dispersed and loaded on micro-grids. The average Fe content of clay mineral grains was 6.7 and 5.4% in Asian and Saharan dusts, respectively. A comparative X-ray diffraction analysis of bulk dusts showed that Saharan dust was more enriched in clay minerals than Asian dust, while Asian dust was more enriched in chlorite. Clay minerals, in particular nanocrystalline ISCMs and Fe-rich chlorite, are probably important sources of Fe to remote marine ecosystems. Further detailed analyses of the mineralogy and chemistry of clay minerals in global mineral dusts are required to evaluate the inputs of Fe to surface ocean microbial communities

Switch on the Big Brother! Investigating the educational gradients in acceptance of online and public areas surveillance among European citizens

In this study, we investigate whether, and why, individuals express different levels of acceptance of surveillance depending on their educational level, and whether this relationship varies with the level of digitalization and globalization expansion of their country. Additionally, we ask whether the type of surveillance (online surveillance vs cameras in public areas) conditions these differences. We build on two theoretical frameworks, one concerned with the resurgence of authoritarian values via the cultural backlash, and the other one explaining how different people analyse manufactured risks differently due to processes of reflexive modernization. In order to test the hypotheses, we employ data from the latest wave of the European Values Study (EVS) and implement multilevel multivariate regression models. Findings indicate that the lower educated individuals are more prone to accept online surveillance, due to their stronger authoritarianism and weaker reflexive mindset; however, there is no educational gradient in acceptance of video surveillance in public areas. Additionally, the countries' levels of digitalization and globalization expansion do not condition the educational gradient in acceptance of surveillance

Cosmic-ray energy spectrum and composition up to the ankle - the case for a second Galactic component

We have carried out a detailed study to understand the observed energy spectrum and composition of cosmic rays with energies up to ~10^18 eV. Our study shows that a single Galactic component with subsequent energy cut-offs in the individual spectra of different elements, optimised to explain the observed spectra below ~10^14 eV and the knee in the all-particle spectrum, cannot explain the observed all-particle spectrum above ~2x10^16 eV. We discuss two approaches for a second component of Galactic cosmic rays -- re-acceleration at a Galactic wind termination shock, and supernova explosions of Wolf-Rayet stars, and show that the latter scenario can explain almost all observed features in the all-particle spectrum and the composition up to ~10^18 eV, when combined with a canonical extra-galactic spectrum expected from strong radio galaxies or a source population with similar cosmological evolution. In this two-component Galactic model, the knee at ~ 3x10^15 eV and the second knee at ~10^17 eV in the all-particle spectrum are due to the cut-offs in the first and second components, respectively. We also discuss several variations of the extra-galactic component, from a minimal contribution to scenarios with a significant component below the ankle (at ~4x10^18 eV), and find that extra-galactic contributions in excess of regular source evolution are neither indicated nor in conflict with the existing data. Our main result is that the second Galactic component predicts a composition of Galactic cosmic rays at and above the second knee that largely consists of helium or a mixture of helium and CNO nuclei, with a weak or essentially vanishing iron fraction, in contrast to most common assumptions. This prediction is in agreement with new measurements from LOFAR and the Pierre Auger Observatory which indicate a strong light component and a rather low iron fraction between ~10^17 and 10^18 eV.Comment: Added Table 4; Published in A&A, 595 (2016) A33 (Highlight paper

Nonlinear shock acceleration beyond the Bohm limit

We suggest a physical mechanism whereby the acceleration time of cosmic rays by shock waves can be significantly reduced. This creates the possibility of particle acceleration beyond the knee energy at ~10^15eV. The acceleration results from a nonlinear modification of the flow ahead of the shock supported by particles already accelerated to the knee momentum at p ~ p_*. The particles gain energy by bouncing off converging magnetic irregularities frozen into the flow in the shock precursor and not so much by re-crossing the shock itself. The acceleration rate is thus determined by the gradient of the flow velocity and turns out to be formally independent of the particle mean free path (m.f.p.). The velocity gradient is, in turn, set by the knee-particles at p ~ p_* as having the dominant contribution to the CR pressure. Since it is independent of the m.f.p., the acceleration rate of particles above the knee does not decrease with energy, unlike in the linear acceleration regime. The reason for the knee formation at p ~ p_* is that particles with $p > p_*$ are effectively confined to the shock precursor only while they are within limited domains in the momentum space, while other particles fall into ``loss-islands'', similar to the ``loss-cone'' of magnetic traps. This structure of the momentum space is due to the character of the scattering magnetic irregularities. They are formed by a train of shock waves that naturally emerge from unstably growing and steepening magnetosonic waves or as a result of acoustic instability of the CR precursor. These losses steepen the spectrum above the knee, which also prevents the shock width from increasing with the maximum particle energy.Comment: aastex, 13 eps figure

Analysis of longitudinal variations in North Pacific alkalinity to improve predictive algorithms

The causes of natural variation in alkalinity in the North Pacific surface ocean need to be investigated to understand the carbon cycle and to improve predictive algorithms. We used GLODAPv2 to test hypotheses on the causes of three longitudinal phenomena in Alk*, a tracer of calcium carbonate cycling. These phenomena are (a) an increase from east to west between 45°N and 55°N, (b) an increase from west to east between 25°N and 40°N, and (c) a minor increase from west to east in the equatorial upwelling region. Between 45°N and 55°N, Alk* is higher on the western than on the eastern side, and this is associated with denser isopycnals with higher Alk* lying at shallower depths. Between 25°N and 40°N, upwelling along the North American continental shelf causes higher Alk* in the east. Along the equator, a strong east-west trend was not observed, even though the upwelling on the eastern side of the basin is more intense, because the water brought to the surface is not high in Alk*. We created two algorithms to predict alkalinity, one for the entire Pacific Ocean north of 30°S and one for the eastern margin. The Pacific Ocean algorithm is more accurate than the commonly used algorithm published by Lee et al. (2006), of similar accuracy to the best previously published algorithm by Sasse et al. (2013), and is less biased with longitude than other algorithms in the subpolar North Pacific. Our eastern margin algorithm is more accurate than previously published algorithms

Characterization of a Time-Domain Dual Lifetime Referencing pCO2 Optode and Deployment as a High-Resolution Underway Sensor across the High Latitude North Atlantic Ocean

The ocean is a major sink for anthropogenic carbon dioxide (CO2), with the CO2 uptake causing changes to ocean chemistry. To monitor these changes and provide a chemical background for biological and biogeochemical studies, high quality partial pressure of CO2 (pCO2) sensors are required, with suitable accuracy and precision for ocean measurements. Optodes have the potential to measure in situ pCO2 without the need for wet chemicals or bulky gas equilibration chambers that are typically used in pCO2 systems. However, optodes are still in an early developmental stage compared to more established equilibrator-based pCO2 systems. In this study, we performed a laboratory-based characterization of a time-domain dual lifetime referencing pCO2 optode system. The pCO2 optode spot was illuminated with low intensity light (0.2mA, 0.72 mW) to minimize spot photobleaching. The spot was calibrated using an experimental gas calibration rig prior to deployment, with a determined response time (t63) of 50 s at 25◦C. The pCO2 optode was deployed as an autonomous shipboard underway system across the high latitude North Atlantic Ocean with a resolution of ca.10 measurements per hour. The optode data was validated with a secondary shipboard equilibrator-based infrared pCO2 instrument, and pCO2 calculated fromdiscrete samples of dissolved inorganic carbon and total alkalinity. Further verification of the pCO2 optode data was achieved using complimentary variables such as nutrients and dissolved oxygen. The shipboard precision of the pCO2 sensor was 9.5μatmdetermined both from repeat measurements of certified reference materials and from the standard deviation of seawater measurements while on station. Finally, the optode deployment data was used to evaluate the physical and biogeochemical controls on pCO2

On the Structure and Scale of Cosmic Ray Modified Shocks

Strong astrophysical shocks, diffusively accelerating cosmic rays (CR) ought to develop CR precursors. The length of such precursor $L_{p}$ is believed to be set by the ratio of the CR mean free path $\lambda$ to the shock speed, i.e., $L_{p}\sim c\lambda/V_{sh}\sim cr_{g}/V_{sh}$, which is formally independent of the CR pressure $P_{c}$. However, the X-ray observations of supernova remnant shocks suggest that the precursor scale may be significantly shorter than $L_{p}$ which would question the above estimate unless the magnetic field is strongly amplified and the gyroradius $r_{g}$ is strongly reduced over a short (unresolved) spatial scale. We argue that while the CR pressure builds up ahead of the shock, the acceleration enters into a strongly nonlinear phase in which an acoustic instability, driven by the CR pressure gradient, dominates other instabilities (at least in the case of low $\beta$ plasma). In this regime the precursor steepens into a strongly nonlinear front whose size scales with \emph{the CR pressure}as $L_{f}\sim L_{p}\cdot(L_{s}/L_{p})^{2}(P_{c}/P_{g})^{2}$, where $L_{s}$ is the scale of the developed acoustic turbulence, and $P_{c}/P_{g}$ is the ratio of CR to gas pressure. Since $L_{s}\ll L_{p}$, the precursor scale reduction may be strong in the case of even a moderate gas heating by the CRs through the acoustic and (possibly also) the other instabilities driven by the CRs.Comment: EPS 2010 paper, to appear in PPC