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The use of the Continuously Regenerating Trap (CRT<sup>TM</sup>) and SCRT<sup>TM</sup> Systems to meet future emissions legislation
The progressive tightening of particulate matter (PM) legislation presents challenges to the engine development and aftertreatment communities. The Continuously Regenerating Trap (CRTTM) has been developed to enable diesel engines to meet the proposed future legislation. This passive filter system combines an oxidation catalyst with a Diesel Particulate Filter (DPF); the filter traps the PM and the oxidation catalyst generates NO2 which combusts the trapped PM at substantially lower temperatures than is possible using oxygen.
This paper outlines the operating principle of the CRTTM, and describes the performance of the system. It has been shown that the very high PM conversions obtained with the CRTTM can enable even Euro 1 engines to meet the PM limits proposed for introduction in Europe in 2005. In addition, the system removes PM across the whole particle size range, including ultrafine particulates. These results will be discussed, as will in-field durability studies which have shown that the system is still capable of converting 90% of PM after very high mileage operation (up to 600,000 km).
In addition to requiring very high PM conversion, the proposed future legislation requires substantial reductions in NOx emissions form heavy duty diesel vehicles. To meet these challenges the SCRTTM has been developed. This combines the CRTTM with SCR (Selective Catalytic Reduction) technology, and enables very high simultaneous conversions of CO, HC, PM and NOx to be achieved. The SCRTTM system is described, and its operating characteristics are discussed. It has been shown that the SCRTTM can potentially meet the legislative limits proposed for introduction in Europe in 2008
Finite-temperature critical point of a glass transition
We generalize the simplest kinetically constrained model of a glass-forming
liquid by softening kinetic constraints, allowing them to be violated with a
small finite rate. We demonstrate that this model supports a first-order
dynamical (space-time) phase transition, similar to those observed with hard
constraints. In addition, we find that the first-order phase boundary in this
softened model ends in a finite-temperature dynamical critical point, which we
expect to be present in natural systems. We discuss links between this critical
point and quantum phase transitions, showing that dynamical phase transitions
in dimensions map to quantum transitions in the same dimension, and hence
to classical thermodynamic phase transitions in dimensions. We make these
links explicit through exact mappings between master operators, transfer
matrices, and Hamiltonians for quantum spin chains.Comment: 10 pages, 5 figure
The projection of a nonlocal mechanical system onto the irreversible generalized Langevin equation, II: Numerical simulations
The irreversible generalized Langevin equation (iGLE) contains a
nonstationary friction kernel that in certain limits reduces to the GLE with
space-dependent friction. For more general forms of the friction kernel, the
iGLE was previously shown to be the projection of a mechanical system with a
time-dependent Hamiltonian. [R. Hernandez, J. Chem. Phys. 110, 7701 (1999)] In
the present work, the corresponding open Hamiltonian system is further
explored. Numerical simulations of this mechanical system illustrate that the
time dependence of the observed total energy and the correlations of the
solvent force are in precise agreement with the projected iGLE.Comment: 8 pages, 9 figures, submitted to J. Chem. Phy
Chemical propulsion research at MSFC
Chemical propulsion research reviews at Marshall Space Flight Cente
Two-dimensional colloidal fluids exhibiting pattern formation
Fluids with competing short range attraction and long range repulsive
interactions between the particles can exhibit a variety of microphase
separated structures. We develop a lattice-gas (generalised Ising) model and
analyse the phase diagram using Monte Carlo computer simulations and also with
density functional theory (DFT). The DFT predictions for the structures formed
are in good agreement with the results from the simulations, which occur in the
portion of the phase diagram where the theory predicts the uniform fluid to be
linearly unstable. However, the mean-field DFT does not correctly describe the
transitions between the different morphologies, which the simulations show to
be analogous to micelle formation. We determine how the heat capacity varies as
the model parameters are changed. There are peaks in the heat capacity at state
points where the morphology changes occur. We also map the lattice model onto a
continuum DFT that facilitates a simplification of the stability analysis of
the uniform fluid.Comment: 13 pages, 15 figure
Isomorphic classical molecular dynamics model for an excess electron in a supercritical fluid
Ring polymer molecular dynamics (RPMD) is used to directly simulate the
dynamics of an excess electron in a supercritical fluid over a broad range of
densities. The accuracy of the RPMD model is tested against numerically exact
path integral statistics through the use of analytical continuation techniques.
At low fluid densities, the RPMD model substantially underestimates the
contribution of delocalized states to the dynamics of the excess electron.
However, with increasing solvent density, the RPMD model improves, nearly
satisfying analytical continuation constraints at densities approaching those
of typical liquids. In the high density regime, quantum dispersion
substantially decreases the self-diffusion of the solvated electron.
In this regime where the dynamics of the electron is strongly coupled to the
dynamics of the atoms in the fluid, trajectories that can reveal diffusive
motion of the electron are long in comparison to .Comment: 24 pages, 4 figure
cr sn: the significance of macroconidiation for mutant hunts
cr sn: significance of macroconidiation for mutant hunt
Network synchronization of groups
In this paper we study synchronized motions in complex networks in which
there are distinct groups of nodes where the dynamical systems on each node
within a group are the same but are different for nodes in different groups.
Both continuous time and discrete time systems are considered. We initially
focus on the case where two groups are present and the network has bipartite
topology (i.e., links exist between nodes in different groups but not between
nodes in the same group). We also show that group synchronous motions are
compatible with more general network topologies, where there are also
connections within the groups
VLA Survey of Dense Gas in Extended Green Objects: Prevalence of 25 GHz Methanol Masers
We present resolution Very Large Array (VLA) observations of four
CHOH - 25~GHz transitions (=3, 5, 8, 10) along with 1.3~cm
continuum toward 20 regions of active massive star formation containing
Extended Green Objects (EGOs), 14 of which we have previously studied with the
VLA in the Class~I 44~GHz and Class~II 6.7~GHz maser lines (Cyganowski et al.
2009). Sixteen regions are detected in at least one 25~GHz line (=5), with
13 of 16 exhibiting maser emission. In total, we report 34 new sites of
CHOH maser emission and ten new sites of thermal CHOH emission,
significantly increasing the number of 25~GHz Class I CHOH masers observed
at high angular resolution. We identify probable or likely maser counterparts
at 44~GHz for all 15 of the 25~GHz masers for which we have complementary data,
providing further evidence that these masers trace similar physical conditions
despite uncorrelated flux densities. The sites of thermal and maser emission of
CHOH are both predominantly associated with the 4.5 m emission from
the EGO, and the presence of thermal CHOH emission is accompanied by 1.3~cm
continuum emission in 9 out of 10 cases. Of the 19 regions that exhibit 1.3~cm
continuum emission, it is associated with the EGO in 16 cases (out of a total
of 20 sites), 13 of which are new detections at 1.3~cm. Twelve of the 1.3~cm
continuum sources are associated with 6.7~GHz maser emission and likely trace
deeply-embedded massive protostars
Understanding the truth about subjectivity
Results of two experiments show children’s understanding of diversity in personal preference is incomplete. Despite acknowledging diversity, in Experiment 1(N=108), 6-
and 8-year-old children were less likely than adults to see preference as a legitimate basis for personal tastes and more likely to say a single truth could be found about a matter of taste. In Experiment 2 (N=96), 7- and 9-year-olds were less likely than 11- and 13-yearolds to say a dispute about a matter of preference might not be resolved. These data suggest that acceptance of the possibility of diversity does not indicate an adult-like understanding of subjectivity. An understanding of the relative emphasis placed on objective and subjective factors in different contexts continues to develop into adolescence
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