380 research outputs found
A Neutral Polyampholyte in an ionic solution
The behavior of a neutral polyampholyte () chain with monomers, in an
ionic solution, is analyzed in the framework of the full Debye-Hckel-Bjerrum-Flory theory. A chain, that in addition to the
neutral monomers, also contains an equal number of positively and negatively
charged monomers, is dissolved in an ionic solution. For \underline{high}
concentrations of salt and at high temperatures, the exists in an extended
state. As the temperature is decreased, the electrostatic energy becomes more
relevant and at a the system collapses into a dilute globular
state, or microelectrolyte. This state contains a concentration of salt higher
than the surrounding medium. As the temperature is decreased even further,
association between the monomers of the polymer and the ions of the salt
becomes relevant and there is a crossover from this globular state to a low
temperature extended state. For \underline{low} densities of salt, the system
is collapsed for almost all temperatures and exhibits a first-order phase
transition to an extended state at an unphysical low temperature.Comment: 10 pages, Revtex with epsf, 9 Postscript figures. Submitted to PR
Dehydration of Alginic Acid Cryogel by TiCl4 vapor : Direct Access to Mesoporous TiO2@C Nanocomposites and Their Performance in Lithium-Ion Batteries
A new strategy for the synthesis of mesoporous TiO2@C nanocomposites through the direct mineralization of seaweed-derived alginic acid cryogel by TiCl4 through a solid/vapor reaction pathway is presented. In this synthesis, alginic acid cryogel can have multiple roles; i) mesoporous template, ii) carbon source, and iii) oxygen source for the TiO2 precursor, TiCl4. The resulting TiO2@alginic acid composite was transformed either into pure mesoporous TiO2 by calcination or into mesoporous TiO2@C nanocomposites by pyrolysis. By comparing with a nonporous TiO2@C composite, the importance of the mesopores on the performance of electrodes for lithium-ion batteries based on mesoporous TiO2@C composite was clearly evidenced. In addition, the carbon matrix in the mesoporous TiO2@C nanocomposite also showed electrochemical activity versus lithium ions, providing twice the capacity of pure mesoporous TiO2 or alginic acid-derived mesoporous carbon (A600). Given the simplicity and environmental friendliness of the process, the mesoporous TiO2@C nanocomposite could satisfy the main prerequisites of green and sustainable chemistry while showing improved electrochemical performance as a negative electrode for lithium-ion batteries
Evidence of selection for resistance to paralytic shellfish toxins during the early life history of soft-shell clam (Mya arenaria) populations
Abstract This study identifies early, postmetamorphic soft-shell clams, Mya arenaria, as the life-history stage most susceptible to effects of blooms of paralytic shellfish poisoning (PSP) toxin-producing Alexandrium spp. Laboratory experiments used progeny from predominantly susceptible (naĂŻve) or resistant (annually exposed) NW Atlantic populations. Growth and survival of toxified veliger larvae did not differ from those fed nontoxic algae. In contrast, postlarvae (4-12-mm shell length) from both populations exposed to a highly toxic Alexandrium tamarense isolate (, 100 cells mL 21 , 64-69 pg saxitoxin equivalents [STXeq] cell 21 ) suffered burrowing incapacitation, toxin accumulation, and mortalities within 1 week of toxin exposure. These effects were greater and occurred sooner in the naĂŻve population. Short-term toxification in the laboratory caused a significant shift in the genotypic composition of this population, determined with a molecular marker for sodium-channel resistance. Clams with the sensitive genotype were selectively eliminated relative to resistant or heterozygote clams. Ingestion of toxic cells (too large for larval capture) is thus required to elicit toxic effects. Exposure to mixed, toxic, and nontoxic algal suspensions demonstrated that adverse effects to fitness (survival and growth) were dose-dependent, occurring only at $ 50 cells mL 21 of the isolate used (PR18b). Paralysis and thus increased predatory risk occurred even at 10 cells mL 21 . Postlarvae , 12 mm, which can co-occur with red tides throughout the Atlantic range of M. arenaria, were more susceptible to PSP than large (. 30 mm) juveniles. Natural selection for resistance in Atlantic populations will thus vary latitudinally with the timing, duration, and intensity of toxic blooms
Strong mechanical driving of a single electron spin
Quantum devices for sensing and computing applications require coherent
quantum systems which can be manipulated in a fast and robust way. Such quantum
control is typically achieved using external electric or magnetic fields which
drive the system's orbital or spin degrees of freedom. However, most of these
approaches require complex and unwieldy antenna or gate structures, and with
few exceptions are limited to the regime of weak driving. Here, we present a
novel approach to strongly and coherently drive a single electron spin in the
solid state using internal strain fields in an integrated quantum device.
Specifically, we study individual Nitrogen-Vacancy (NV) spins embedded in
diamond mechanical oscillators and exploit the intrinsic strain coupling
between spin and oscillator to strongly drive the spins. As hallmarks of the
strong driving regime, we directly observe the energy spectrum of the emerging
phonon-dressed states and employ our strong, continuous driving for enhancement
of the NV spin coherence time. Our results constitute a first step towards
strain-driven, integrated quantum devices and open new perspectives to
investigate unexplored regimes of strongly driven multi-level systems and to
study exotic spin dynamics in hybrid spin-oscillator devices.We gratefully acknowledge financial support from SNI; NCCR QSIT; SNF grants 200021_143697; and EU FP7 grant 611143 (DIADEMS). AN holds a University Research Fellowship from the Royal Society and acknowledges support from the Winton Programme for the Physics of Sustainability.This is the author accepted manuscript. The final version is available from NPG via http://dx.doi.org/10.1038/nphys341
The school environment and adolescent physical activity and sedentary behaviour : A mixed-studies systematic review
There is increasing academic and policy interest in interventions aiming to promote young people's health by ensuring that the school environment supports healthy behaviours. The purpose of this review was to summarize the current evidence on school-based policy, physical and social-environmental influences on adolescent physical activity and sedentary behaviour. Electronic databases were searched to identify studies that (1) involved healthy adolescents (11-18years old), (2) investigated school-environmental influences and (3) reported a physical activity and/or sedentary behaviour outcome or theme. Findings were synthesized using a non-quantitative synthesis and thematic analysis. Ninety-three papers of mixed methodological quality were included. A range of school-based policy (e.g. break time length), physical (e.g. facilities) and social-environmental (e.g. teacher behaviours) factors were associated with adolescent physical activity, with limited research on sedentary behaviour. The mixed-studies synthesis revealed the importance of specific activity settings (type and location) and intramural sport opportunities for all students. Important physical education-related factors were a mastery-oriented motivational climate and autonomy supportive teaching behaviours. Qualitative evidence highlighted the influence of the wider school climate and shed light on complexities of the associations observed in the quantitative literature. This review identifies future research needs and discusses potential intervention approaches to be considered
Alginic acid-derived mesoporous carbonaceous materials (StarbonÂź) as negative electrodes for lithium ion batteries : Importance of porosity and electronic conductivity
Alginic acid-derived mesoporous carbonaceous materials (StarbonÂź A800 series) were investigated as negative electrodes for lithium ion batteries. To this extent, a set of mesoporous carbons with different pore volume and electronic conductivity was tested. The best electrochemical performance was obtained for A800 with High Pore Volume (A800HPV), which displays both the highest pore volume (0.9 cm3 gâ1) and the highest electronic conductivity (84 S mâ1) of the tested materials. When compared to a commercial mesoporous carbon, A800HPV was found to exhibit both better long-term stability, and a markedly improved rate capability. The presence of a hierarchical interconnected pore network in A800HPV, accounting for a high electrolyte accessibility, could lay at the origin of the good electrochemical performance. Overall, the electronic conductivity and the mesopore size appear to be the most important parameters, much more than the specific surface area. Finally, A800HPV electrodes display similar electrochemical performance when formulated with or without added conductive additive, which could make for a simpler and more eco-friendly electrode processing
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