Polar mesosphere summer echoes: a comparison of simultaneous observations at three wavelengths

On 5 July 2005, simultaneous observations of Polar Mesosphere Summer Echoes (PMSE) were made using the EISCAT VHF (224 MHz) and UHF (933 MHz) radars located near Tromsø, Norway and the ALWIN VHF radar (53.5 MHz) situated on Andøya, 120 km SW of the EISCAT site. During the short interval from 12:20 UT until 12:26 UT strong echoes at about 84 km altitude were detected with all three radars. The radar volume reflectivities were found to be 4×10<sup>−13</sup> m<sup>−1</sup>, 1.5×10<sup>−14</sup> m<sup>−1</sup> and 1.5×10<sup>−18</sup> m<sup>−1</sup> for the ALWIN, EISCAT-VHF and UHF radars, respectively. We have calculated the reflectivity ratios for each pair of radars and have compared them to ratios obtained from the turbulence-theory model proposed by Hill (1978a). We have tested different values of the turbulent energy dissipation rate ε and Schmidt number <i>S<sub>c</sub></i>, which are free parameters in the model, to try to fit theoretical reflectivity ratios to the experimental ones. No single combination of the parameters ε and <i>S<sub>c</sub></i> could be found to give a good fit. Spectral widths for the EISCAT radars were estimated from the spectra computed from the autocorrelation functions obtained in the experiment. After correction for beam-width broadening, the spectral widths are about 4 m/s for the EISCAT-VHF and 1.5–2 m/s for the UHF radar. However, according to the turbulence theory, the spectral widths in m/s should be the same for both radars. We also tested an incoherent scatter (IS) model developed by Cho et al. (1998), which takes into account the presence of charged aerosols/dust at the summer mesopause. It required very different sizes of particles for the EISCAT-VHF and UHF cases, to be able to fit the experimental spectra with model spectra. This implies that the IS model cannot explain PMSE spectra, at least not for monodisperse distributions of particles

Influence of water vapour on the height distribution of positive ions, effective recombination coefficient and ionisation balance in the quiet lower ionosphere

Mesospheric water vapour concentration effects on the ion composition and electron density in the lower ionosphere under quiet geophysical conditions were examined. Water vapour is an important compound in the mesosphere and the lower thermosphere that affects ion composition due to hydrogen radical production and consequently modifies the electron number density. Recent lower-ionosphere investigations have primarily concentrated on the geomagnetic disturbance periods. Meanwhile, studies on the electron density under quiet conditions are quite rare. The goal of this study is to contribute to a better understanding of the ionospheric parameter responses to water vapour variability in the quiet lower ionosphere. By applying a numerical D region ion chemistry model, we evaluated efficiencies for the channels forming hydrated cluster ions from the NO⁺ and O₂⁺ primary ions (i.e. NO⁺.H₂O and O₂⁺.H₂O, respectively), and the channel forming H⁺(H₂O)_<i>n</i> proton hydrates from water clusters at different altitudes using profiles with low and high water vapour concentrations. Profiles for positive ions, effective recombination coefficients and electrons were modelled for three particular cases using electron density measurements obtained during rocket campaigns. It was found that the water vapour concentration variations in the mesosphere affect the position of both the Cl₂⁺ proton hydrate layer upper border, comprising the NO⁺(H₂O)_<i>n</i> and O₂⁺(H₂O)_<i>n</i> hydrated cluster ions, and the Cl₁⁺ hydrate cluster layer lower border, comprising the H⁺(H₂O)_<i>n</i> pure proton hydrates, as well as the numerical cluster densities. The water variations caused large changes in the effective recombination coefficient and electron density between altitudes of 75 and 87 km. However, the effective recombination coefficient, &alpha;_eff, and electron number density did not respond even to large water vapour concentration variations occurring at other altitudes in the mesosphere. We determined the water vapour concentration upper limit at altitudes between 75 and 87 km, beyond which the water vapour concentration ceases to influence the numerical densities of Cl₂⁺ and Cl₁⁺, the effective recombination coefficient and the electron number density in the summer ionosphere. This water vapour concentration limit corresponds to values found in the H₂O-1 profile that was observed in the summer mesosphere by the Upper Atmosphere Research Satellite (UARS). The electron density modelled using the H₂O-1 profile agreed well with the electron density measured in the summer ionosphere when the measured profiles did not have sharp gradients. For sharp gradients in electron and positive ion number densities, a water profile that can reproduce the characteristic behaviour of the ionospheric parameters should have an inhomogeneous height distribution of water vapour

Modeling the interfacial energy of surfactant-free amphiphilic Janus nanoparticles from phase inversion in Pickering emulsions

Determining the interfacial energy of nanoparticles is very challenging via traditional methods that first require measuring the contact angle of several liquids of a sessile drop on pellets or capillary rise in powder beds. In this work, we propose an alternative way to model the interfacial energy of nanoparticles directly from emulsion phase inversion data in Pickering emulsions. This could establish itself as a universal and facile way to determine the polarity of nanoparticles relative to a series of standard particles without the need to measure contact angles. Pickering emulsions of several oils in water were generated with a series of snowman-like Janus nanoparticles (JNPs), whose polarity gradually increased with the size of the more polar lobe. Depending on the oil to water ratio and the JNPs lobe size, oil-in-water (o/w) or water-in-oil (w/o) Pickering emulsions were obtained and the affinity of the JNPs to either water or oil can be inferred from the evolution of the emulsion phase inversion curves with these parameters. We further demonstrate that by adopting a simple model for the work of adhesion of JNPs with the water and oil phases, one can quantitatively calculate the relative interfacial energy change of the JNPs with the liquid. In addition, a knowledge of the interfacial energy of nanoparticles is useful for employing these in suspension polymerization to create surface nanostructured materials. The o/w and w/o Pickering emulsions obtained from monomers, such as styrene, could be polymerized, resulting in colloidosomes or hollow-like materials. The hollow materials exhibited a rather high volume storage capacity for the aqueous phase for extended periods of time, which could be released upon microwaving, making them ideal for use in long-term storage applications of various water-soluble actives

Reduced Population Control of an Insect Pest in Managed Willow Monocultures

BACKGROUND: There is a general belief that insect outbreak risk is higher in plant monocultures than in natural and more diverse habitats, although empirical studies investigating this relationship are lacking. In this study, using density data collected over seven years at 40 study sites, we compare the temporal population variability of the leaf beetle Phratora vulgatissima between willow plantations and natural willow habitats. METHODOLOGY/PRINCIPAL FINDINGS: The study was conducted in 1999-2005. The density of adult P. vulgatissima was estimated in the spring every year by a knock-down sampling technique. We used two measures of population variability, CV and PV, to compare temporal variations in leaf beetle density between plantation and natural habitat. Relationships between density and variability were also analyzed to discern potential underlying processes behind stability in the two systems. The results showed that the leaf beetle P. vulgatissima had a greater temporal population variability and outbreak risk in willow plantations than in natural willow habitats. We hypothesize that the greater population stability observed in the natural habitat was due to two separate processes operating at different levels of beetle density. First, stable low population equilibrium can be achieved by the relatively high density of generalist predators observed in natural stands. Second, stable equilibrium can also be imposed at higher beetle density due to competition, which occurs through depletion of resources (plant foliage) in the natural habitat. In willow plantations, competition is reduced mainly because plants grow close enough for beetle larvae to move to another plant when foliage is consumed. CONCLUSION/SIGNIFICANCE: To our knowledge, this is the first empirical study confirming that insect pest outbreak risk is higher in monocultures. The study suggests that comparative studies of insect population dynamics in different habitats may improve our ability to predict insect pest outbreaks and could facilitate the development of sustainable pest control in managed systems

A case study of gravity waves in noctilucent clouds

We present a case study of a noctilucent cloud (NLC) display appearing on 10-11 August 2000 over Northern Sweden. Clear wave structures were visible in the clouds and time-lapse photography was used to derive the parameters characterising the gravity waves which could account for the observed NLC modulation. Using two nearby atmospheric radars, the Esrange MST Radar data and Andoya MF radar, we have identified gravity waves propagating upward from the upper stratosphere to NLC altitudes. The wave parameters derived from the radar measurements support the suggestion that gravity waves are responsible for the observed complex wave dynamics in the NLC

Inertia gravity waves in the upper troposphere during the MaCWAVE winter campaign &ndash; Part I: Observations with collocated radars

During the {MaCWAVE} campaign, combined rocket, radiosonde and ground-based measurements have been performed at the Norwegian Andøya Rocket Range (ARR) near Andenes and the Swedish Rocket Range (ESRANGE) near Kiruna in January 2003 to study gravity waves in the vicinity of the Scandinavian mountain ridge. The investigations presented here are mainly based on the evaluation of continuous radar measurements with the ALWIN VHF radar in the upper troposphere/ lower stratosphere at Andenes (69.3&deg; N, 16.0&deg; E) and the ESRAD VHF radar near Kiruna (67.9&deg; N, 21.9&deg; E). Both radars are separated by about 260 km. Based on wavelet transformations of both data sets, the strongest activity of inertia gravity waves in the upper troposphere has been detected during the first period from 24&ndash;26 January 2003 with dominant vertical wavelengths of about 4&ndash;5 km as well as with dominant observed periods of about 13&ndash;14 h for the altitude range between 5 and 8 km under the additional influence of mountain waves. The results show the appearance of dominating inertia gravity waves with characteristic horizontal wavelengths of ~200 km moving in the opposite direction than the mean background wind. The results show the appearance of dominating inertia gravity waves with intrinsic periods in the order of ~5 h and with horizontal wavelengths of 200 km, moving in the opposite direction than the mean background wind. From the derived downward energy propagation it is supposed, that these waves are likely generated by a jet streak in the upper troposphere. The parameters of the jet-induced gravity waves have been estimated at both sites separately. The identified gravity waves are coherent at both locations and show higher amplitudes on the east-side of the Scandinavian mountain ridge, as expected by the influence of mountains

Inertia gravity waves in the upper troposphere during the MaCWAVE winter campaign ? Part II: Radar investigations and modelling studies

International audienceWe present an experimental and modelling study of a strong gravity wave event in the upper troposphere/lower stratosphere near the Scandinavian mountain ridge. Continuous VHF radar measurements during the MaCWAVE rocket and ground-based measurement campaign were performed at the Norwegian Andoya Rocket Range (ARR) near Andenes (69.3° N, 16° E) in January 2003. Detailed gravity wave investigations based on PSU/NCAR Fifth-Generation Mesoscale Model (MM5) data have been used for comparison with experimentally obtained results. The model data show the presence of a mountain wave and of an inertia gravity wave generated by a jet streak near the tropopause region. Temporal and spatial dependencies of jet induced inertia gravity waves with dominant observed periods of about 13 h and vertical wavelengths of ~4.5?5 km are investigated with wavelet transform applied on radar measurements and model data. The jet induced wave packet is observed to move upstream and downward in the upper troposphere. The model data agree with the experimentally obtained results fairly well. Possible reasons for the observed differences, e.g. in the time of maximum of the wave activity, are discussed. Finally, the vertical fluxes of horizontal momentum are estimated with different methods and provide similar amplitudes. We found indications that the derived positive vertical flux of the horizontal momentum corresponds to the obtained parameters of the jet-induced inertia gravity wave, but only at the periods and heights of the strongest wave activity

Inertia gravity waves in the upper troposphere during the MaCWAVE winter campaign - Part I: Observations with collocated radars

During the {MaCWAVE} campaign, combined rocket, radiosonde and ground-based measurements have been performed at the Norwegian Andøya Rocket Range (ARR) near Andenes and the Swedish Rocket Range (ESRANGE) near Kiruna in January 2003 to study gravity waves in the vicinity of the Scandinavian mountain ridge. The investigations presented here are mainly based on the evaluation of continuous radar measurements with the ALWIN VHF radar in the upper troposphere/ lower stratosphere at Andenes (69.3° N, 16.0° E) and the ESRAD VHF radar near Kiruna (67.9° N, 21.9° E). Both radars are separated by about 260 km. Based on wavelet transformations of both data sets, the strongest activity of inertia gravity waves in the upper troposphere has been detected during the first period from 24–26 January 2003 with dominant vertical wavelengths of about 4–5 km as well as with dominant observed periods of about 13–14 h for the altitude range between 5 and 8 km under the additional influence of mountain waves. The results show the appearance of dominating inertia gravity waves with characteristic horizontal wavelengths of ~200 km moving in the opposite direction than the mean background wind. The results show the appearance of dominating inertia gravity waves with intrinsic periods in the order of ~5 h and with horizontal wavelengths of 200 km, moving in the opposite direction than the mean background wind. From the derived downward energy propagation it is supposed, that these waves are likely generated by a jet streak in the upper troposphere. The parameters of the jet-induced gravity waves have been estimated at both sites separately. The identified gravity waves are coherent at both locations and show higher amplitudes on the east-side of the Scandinavian mountain ridge, as expected by the influence of mountains