6,931 research outputs found

    Bis[5-(4-bromo­phen­yl)-4-(tert-but­oxy­carbon­yl)pyrrolidine-2-carboxyl­ato]copper(II) dihydrate

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    In the title compound, [Cu(C16H19BrNO4)2]·2H2O, the CuII ion resides on an inversion centre and is coordinated by two O and two N atoms from two enanti­omeric 5-(4-bromo­phen­yl)-4-(tert-but­oxy­carbon­yl)pyrrolidine-2-carboxyl­ate ligands in a distorted square-planar geometry. The relative stereochemistry of the three stereogenic C atoms in each ligand has been determined. In the crystal, inter­molecular N—H⋯O and O—H⋯O hydrogen bonds link the mol­ecules into layers parallel to the bc plane. The crystal studied was twinned by pseudo­merohedry with twin fractions of 0.719 (3) and 0.281 (3)

    Thermo-Mechanical Modeling of Friction Stir Spot Welding and Numerical Solution With The Finite Element Method

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    In this paper, friction stir spot welding (FSSW) of magnesium sheets were analyzed using finite element method (FEM). Various tool shoulder types used in Friction stir welding (FSW) were chosen as different parameter. Thermic simulations were showed that thermic conditions vary with tool shoulder design types used in friction stir welding. Heat energy input (Q) of numerical model was solved analytically and calculated based on the various parameter values. Friction factor surface pressure and materials thermic properties which are changing with generated heat during friction welding were also considered in the FEM analysis. Thermic field model was solved numerically and results were presented

    2-[(1RS,3RS,3aRS,6aSR)-5-Benzyl-4,6-dioxo-3-phenyl­octa­hydro­pyrrolo­[3,4-c]pyrrol-1-yl]acetamide

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    In the title compound, C21H21N3O3, the relative stereochemistry of the four stereogenic C atoms has been determined. The dihedral angle between the phenyl rings is 77.63 (7)°. In the crystal, ribbons spread along the a axis are formed by N—H⋯O hydrogen bonds. C—H⋯π inter­actions also occur

    Step Bunching with Alternation of Structural Parameters

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    By taking account of the alternation of structural parameters, we study bunching of impermeable steps induced by drift of adatoms on a vicinal face of Si(001). With the alternation of diffusion coefficient, the step bunching occurs irrespective of the direction of the drift if the step distance is large. Like the bunching of permeable steps, the type of large terraces is determined by the drift direction. With step-down drift, step bunches grows faster than those with step-up drift. The ratio of the growth rates is larger than the ratio of the diffusion coefficients. Evaporation of adatoms, which does not cause the step bunching, decreases the difference. If only the alternation of kinetic coefficient is taken into account, the step bunching occurs with step-down drift. In an early stage, the initial fluctuation of the step distance determines the type of large terraces, but in a late stage, the type of large terraces is opposite to the case of alternating diffusion coefficient.Comment: 8pages, 16 figure

    A systematic study on luminescence characterization of lanthanide-doped BeO ceramic dosimeters

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    This work aimed to investigate the luminescent characteristics of lanthanide and alkali metal ion-doped BeO ceramic pellets prepared using the co-precipitation synthesis technique for Optically Stimulated Luminescence (OSL) dosimetry applications. In this study, BeO nano phosphor was doped with lanthanides (Ln(3+)) Eu3+, Ce3+, Nd3+, Yb3+, Er3+, Gd3+, Tb3+, Tm3+, Sm3+, Pr3+, and Dy3+ and co-doped with Na+, and characterized using radioluminescence (RL), thermoluminescence (TL) and OSL techniques. Lanthanides introduced as dopants not only affected the luminescence centers but also changed the luminescence mechanisms. The RL spectra of lanthanide-doped BeO samples showed that they mostly possess dominant emissions in the narrow bands (between 200 and 450 nm) in the UV region. OSL emission bands were found to be located between similar to 250 and similar to 390 nm. The results have demonstrated that the incorporation of appropriate Ln(3+) and alkali metal ion dopants and their optimum concentrations enhanced the luminescence intensity of undoped BeO. The studied BeO:Na-5%,Ce-0.01%,Er-0.01%, BeO:Na-5%,Ce-0.005%,Tb-0.05%, and BeO:Na-5%,Ce-0.01%,Dy-0.01% ceramics can be regarded as highly sensitive controllable luminescence dosimeters. The range of sensitivity of those samples is such that their most probable use in clinical therapy dosimetry rather than in health physics. (C) 2021 Elsevier B.V. All rights reserved

    Entanglement and teleportation via chaotic system

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    The dynamics of entangled state interacting with a single cavity mode is investigated in the presence of a random parameter. We have shown that degree of entanglement decays with time and rate of decay is defined by features of random parameter. Quantum teleportation through dissipative channal and teleportation fidelity as a function of damping rates has been studied. The sensitivity of the fidelity with respect to random parameter is discussed. We have evaluated the time interval during which one can perform the quantum teleportation and send the information with reasonable fidelity, for a given values of correlation length of random parameter.Comment: Accepted in Physica

    The SFXC software correlator for Very Long Baseline Interferometry: Algorithms and Implementation

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    In this paper a description is given of the SFXC software correlator, developed and maintained at the Joint Institute for VLBI in Europe (JIVE). The software is designed to run on generic Linux-based computing clusters. The correlation algorithm is explained in detail, as are some of the novel modes that software correlation has enabled, such as wide-field VLBI imaging through the use of multiple phase centres and pulsar gating and binning. This is followed by an overview of the software architecture. Finally, the performance of the correlator as a function of number of CPU cores, telescopes and spectral channels is shown.Comment: Accepted by Experimental Astronom
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