10 research outputs found

    Collaborative information seeking and sharing: The 9th Symposium of SIG/USE

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    No Abstract.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/65060/1/1720360310_ftp.pd

    Progress in creating a joint research agenda that allows networked long-term socio-ecological research in southern South America : addressing crucial technological and human capacity gaps limiting its application in Chile and Argentina

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    Since 1980, more than 40 countries have implemented long-term ecological research (LTER) programs, which have shown their power to affect advances in basic science to understand the natural world at meaningful temporal and spatial scales and also help link research with socially relevant outcomes. Recently, a disciplinary paradigmatic shift has integrated the human dimensions of ecosystems, leading to a long-term socio-ecological research (LTSER) framework to address the world's current environmental challenges. A global gap in LTER/LTSER only exists in the latitudinal range of 40–60°S, corresponding to Argentina and Chile's temperate/sub-Antarctic biome. A team of Chilean, Argentine and US researchers has participated in an ongoing dialogue to define not only conceptual, but also practical barriers limiting LTER/LTSER in southern South America. We have found a number of existing long-term research sites and platforms throughout the region, but at the same time it has been concluded an agenda is needed to create and implement further training courses for students, postdoctoral fellows and young scientists, particularly in the areas of data and information management systems. Since LTER/LTSER efforts in Chile and Argentina are incipient, instituting such courses now will enhance human and technical capacity of the natural science and resource community to improve the collection, storage, analysis and dissemination of information in emerging LTER/LTSER platforms. In turn, having this capacity, as well as the ongoing formalization of LTER/LTSER programs at national levels, will allow the enhancement of crucial collaborations and comparisons between long-term research programs within the region and between hemispheres and continents. For Spanish version of the entire article, see Online Supporting Information (Appendix S1).Desde 1980, más de cuarenta países han implementado programas de Investigación Ecológica a Largo Plazo (LTER por sus siglas en inglés), los cuales han mostrado su capacidad para influir sobre los avances en las ciencias básicas que permiten entender el mundo natural en escalas temporales y espaciales significativas, y también ayudar a enfocar la investigación hacia estudios socialmente relevantes. Recientemente, gracias a un cambio de paradigma en la disciplina, se integró también la dimensión humana de los ecosistemas, llevándola a un marco conceptual de Investigación Socio-Ecológica a Largo Plazo (LTSER por sus siglas en inglés) para enfrentar los desafíos medio-ambientales del mundo actual. Existe un vacío global en LTER/LTSER en el rango latitudinal de 40–60°S, correspondiente a los biomas templados/subantárticos de Argentina y Chile. Un equipo de investigadores chilenos, argentinos y estadounidenses ha trabajado por varios años para definir cuáles son la barreras que actualmente limitan la creación de una Red de LTER/LTSER en el sur de Sudamérica, no solamente en términos conceptuales, sino también a nivel práctico. Existe un buen número de sitios de investigación a largo plazo en la región, pero también concluimos que es necesario crear e implementar más cursos de capacitación para estudiantes, investigadores post-doctorales y jóvenes científicos, particularmente en las áreas de sistemas de manejo de datos e información. Considerando que los esfuerzos LTER/LTSER en Chile y Argentina son incipientes, este tipo de cursos podría mejorar la capacidad humana y técnica en la comunidad de las ciencias y los recursos naturales, así como mejorar los procesos de recolección, almacenamiento, análisis y difusión de la información. A su vez, la formalización de cursos de programas LTER/LTSER a nivel nacional para adquirir dicha capacidad de manejo de la información, permitirá un fortalecimiento crucial de las colaboraciones y comparaciones entre programas de investigación a largo plazo dentro de la región, y entre hemisferios y continentes. La versión en castellano del artículo se encuentra disponible en forma digital como Online Supporting Information S1.Fil: Anderson, Chistopher B. University of North Texas. Department of Biological Sciences; Estados UnidosFil: Celis-Diez, Juan Luis. Pontificia Universidad Católica de Valparaíso, Escuela de Agronomía; ChileFil: Bond, Barbara J.H.G. Oregon State University. Andrews Forest Long-Term Ecological Research Site. Department of Forest Ecosystems and Society; Estados UnidosFil: Martínez Pastur, Guillermo José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Austral de Investigaciones Cientificas; ArgentinaFil: Little, Christian. Universidad Austral de Chile. Facultad de Ciencias. Instituto de Ciencias de la Tierra y Evolución; Chile. Fundación Centro de los Bosques Nativos FORECOS; ChileFil: Armesto, Juan J. Pontificia Universidad Católica de Valparaíso, Escuela de Agronomía; ChileFil: Ghersa, Claudio Marco. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Instituto de Investigaciones Fisiológicas y Ecológicas Vinculadas a la Agricultura. Universidad de Buenos Aires. Facultad de Agronomía. Instituto de Investigaciones Fisiológicas y Ecológicas Vinculadas a la Agricultura; ArgentinaFil: Austin, Amy Theresa. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Instituto de Investigaciones Fisiológicas y Ecológicas Vinculadas a la Agricultura. Universidad de Buenos Aires. Facultad de Agronomía. Instituto de Investigaciones Fisiológicas y Ecológicas Vinculadas a la Agricultura; ArgentinaFil: Schlichter, Tomas Miguel. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Bariloche. Grupo de Ecología Forestal; ArgentinaFil: Lara, Antonio. Fundación Centro de los Bosques Nativos FORECOS; Chile. Universidad Austral de Chile. Facultad de Ciencias Forestales y Recursos Naturales. Instituto de Silvicultura; ChileFil: Carmona, Martin. Universidad de Chile. Instituto de Ecologıa y Biodiversidad; ChileFil: Chaneton, Enrique Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Instituto de Investigaciones Fisiológicas y Ecológicas Vinculadas a la Agricultura; Argentina. Universidad de Buenos Aires. Facultad de Agronomia. Departamento de Recursos Naturales y Ambiente; ArgentinaFil: Gutierrez, Julio R. Universidad de La Serena. Departamento de Biología. Instituto de Ecología y Biodiversidad. Centro de Estudios Avanzados en Zonas Aridas; ChileFil: Rozzi, Ricardo. Universidad de La Serena. Departamento de Biología. Instituto de Ecología y Biodiversidad; ChileFil: Vanderbilt, Kristin University of New Mexico. Department of Biology. Sevilleta Long-Term Ecological Research Site; Estados UnidosFil: Oyarce, Guillermo University of North Texas. Library and Information Sciences; Estados UnidosFil: Fernandez, Roberto J. University of North Texas, Department of Biological Sciences; Estados Unido

    Thiophene-containing β-diketonate complex of copper(II): X-ray crystal structure and electropolymerization

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    International audienceIn this work, we report the synthesis of the asymmetrical β-diketone 1-(thiophen-2-yl)-3-(thiophen-3-yl)propane-1,3-dione (HL) and its corresponding bis(β-diketonate)copper(II) complex [Cu₁-(thiophen-2-yl)-3-(thiophen-3-yl)-1,3-propanedionate₂] (CuL2), isolated in 60 and 86% yields, respectively. These two new compounds have been characterized by elemental analysis, FT-IR and UV–Vis spectroscopy and, in the case of HL, by 1H and 13C NMR spectroscopy. Additionally, both compounds were authenticated by X-ray diffraction analysis. The β-diketone HL exists as its keto-enol tautomer both in solution and in the solid-state with the [sbnd]OH group adjacent to the 3-thienyl unit. The CuL2 is essentially flat and the Cu(II) center adopts a perfect square planar geometry. The CuL2 modified electrode was fabricated through the electropolymerization of the monomer in a 0.1 M of tetrabutylammonium tetrafluoroborate (TBATFB) in anhydrous acetonitrile solution, in the potential window −1.0 V to 1.6 V. The thin film Pt|(CuL2)n modified electrode response was studied employing a 0.1 M of TBATFB solution in CH3CN. Likewise, the potentiostatic method was also employed to synthesize the films on Fluorine Doped Tin Oxide electrode (FTO). Images from the electrode surface were obtained using Scanning Electron Microscopy (SEM)

    Synthesis, structures, electrochemical and quantum chemical investigations of Ni(II) and Cu(II) complexes with a tetradentate Schiff base derived from 1-(2-thienyl)-1,3-butanedione

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    International audienceDouble condensation of the newly prepared 1-(2-thienyl)-1,3-butanedione with ethylenediamine led to the formation of a novel symmetrical Schiff base proligand bearing two potentially electropolymerizable 2-thienyl groups. Both organic species were obtained in 55 and 80% yields, respectively. They exist in their respective keto-enol and enaminone tautomeric forms that were computed to be more stable by 8.6 and 30.3 kcal mol(-1) than their beta-diketone and keto-imine isomers. The corresponding Ni(ii) and Cu(ii) complexes featuring a N2O2-tetradentate Schiff base ligand were readily synthesized upon reaction of the diprotic Schiff base precursor with the appropriate hydrated metal acetates, and isolated as neutral, air and thermally stable solids in excellent yields (84 and 90%). The four compounds were characterized using various analytical and spectroscopic methods, and by an X-ray diffraction study for the two coordination complexes. Both Ni(ii) and Cu(ii) metal ions are four-coordinated and adopt a perfect square planar environment (tau(4) values of 0.036 and 0.025) with two nitrogen and two oxygen atoms as donors. Both complexes were analyzed by cyclic voltammetry experiments showing a decrease of the current response per cycle, indicating the formation of oligomeric units. This was verified using their doping/undoping responses. The optimized geometries of the four compounds as well as the electronic structures of the two Ni(ii) and Cu(ii) complexes and their respective cations were analysed through DFT calculations, allowing the provision of a consistent view of their structure and properties. TDDFT calculations were used to interpret the major features of the UV-vis spectra

    Improving equity in access to early diagnosis of cancer in different healthcare systems of Latin America: protocol for the EquityCancer-LA implementation-effectiveness hybrid study

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    Introduction Healthcare fragmentation, a main cause for delay in cancer diagnosis and treatment, contributes to high mortality in Latin America (LA), particularly among disadvantaged populations. This research focuses on integrated care interventions, which have been limitedly implemented in the region. The objective is to evaluate the contextual effectiveness of scaling-up an integrated care intervention to improve early diagnosis of frequent cancers in healthcare networks of Chile, Colombia and Ecuador.Methods and analysis This research is two pronged: (A) quasi-experimental design (controlled before and after) with an intervention and a control healthcare network in each LA country, using an implementation-effectiveness hybrid approach to assess the intervention process, effectiveness and costs; and (B) case study design to analyse access to diagnosis of most frequent cancers. Focusing on the most vulnerable socioeconomic population, it develops in four phases: (1) analysis of delays and barriers to early diagnosis (baseline); (2) intervention adaptation and implementation (primary care training, fast-track referral pathway and patient information); (3) intracountry evaluation of intervention and (4) cross-country analysis. Baseline and evaluation studies adopt mixed-methods qualitative (semistructured individual interviews) and quantitative (patient questionnaire survey) methods. For the latter, a sample size of 174 patients with cancer diagnosis per healthcare network and year was calculated to detect a proportions difference of 15%, before and after intervention (α=0.05; β=0.2) in a two-sided test. A participatory approach will be used to tailor the intervention to each context, led by a local steering committee (professionals, managers, policy makers, patients and researchers).Ethics and dissemination This study complies with international and national legal stipulations on ethics. It was approved by each country’s ethical committee and informed consent will be obtained from participants. Besides the coproduction of knowledge with key stakeholders, it will be disseminated through strategies such as policy briefs, workshops, e-tools and scientific papers

    Emergencias y desastres

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    Aplicación de encuesta en aldeas, instaladas posterremoto/tsunami, Región del MauleCooperación internacional y respuesta del sistema de salud frente al terremoto de febrero de 2010Estudio de los fallecidos durante el desastre del 27 de febrero en ChileExperiencia de solidaridad internacional de urgencia en Rancagua, Chile, postsismo 2010Incidencia de patologías posterremoto en la comunidad de HualañéIncidencia de trastorno de estrés postraumático posterior al terremoto en Chile en los trabajadores bancarios&nbsp
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