6,703 research outputs found
Effect of polymer concentration and length of hydrophobic end block on the unimer-micelle transition broadness in amphiphilic ABA symmetric triblock copolymer solutions
The effects of the length of each hydrophobic end block N_{st} and polymer
concentration \bar{\phi}_{P} on the transition broadness in amphiphilic ABA
symmetric triblock copolymer solutions are studied using the self-consistent
field lattice model. When the system is cooled, micelles are observed, i.e.,the
homogenous solution (unimer)-micelle transition occurs. When N_{st} is
increased, at fixed \bar{\phi}_{P}, micelles occur at higher temperature, and
the temperature-dependent range of micellar aggregation and half-width of
specific heat peak for unimer-micelle transition increase monotonously.
Compared with associative polymers, it is found that the magnitude of the
transition broadness is determined by the ratio of hydrophobic to hydrophilic
blocks, instead of chain length. When \bar{\phi}_{P} is decreased, given a
large N_{st}, the temperature-dependent range of micellar aggregation and
half-width of specific heat peak initially decease, and then remain nearly
constant. It is shown that the transition broadness is concerned with the
changes of the relative magnitudes of the eductions of nonstickers and solvents
from micellar cores.Comment: 8 pages, 4 figure
The effect of asymmetry of the coil block on self-assembly in ABC coil-rod-coil triblock copolymers
Using the self-consistent field approach, the effect of asymmetry of the coil
block on the microphase separation is focused in ABC coil-rod-coil triblock
copolymers. For different fractions of the rod block , some stable
structures are observed, i.e., lamellae, cylinders, gyroid, and core-shell
hexagonal lattice, and the phase diagrams are constructed. The calculated
results show that the effect of the coil block fraction is
dependent on . When , the effect of asymmetry of
the coil block is similar to that of the ABC flexible triblock copolymers; When
, the self-assembly of ABC coil-rod-coil triblock copolymers
behaves like rod-coil diblock copolymers under some condition. When continues to increase, the effect of asymmetry of the coil block reduces.
For , under the symmetrical and rather asymmetrical
conditions, an increase in the interaction parameter between different
components leads to different transitions between cylinders and lamellae. The
results indicate some remarkable effect of the chain architecture on
self-assembly, and can provide the guidance for the design and synthesis of
copolymer materials.Comment: 9 pages, 3 figure
Study on the Effect of Track Curve Radius on Friction-Induced Oscillation of a Wheelset–Track System
© 2019, © 2019 Society of Tribologists and Lubrication Engineers. The purpose of this article is to investigate the correlation between the friction-induced oscillation of a wheelset–track system and curve radius and to explain a general phenomenon of rail corrugation based on the viewpoint of friction-induced oscillation. The typical phenomenon of rail corrugation in metros is that corrugation generally arises when the curve radius is quite small, whereas it rarely occurs when the curve radius is larger or on a straight track. Different multibody models of the vehicle–track system and finite-element models of the multiple-wheelset–track system with different curve radii are established, respectively. According to the creep force analyses and unstable vibration analyses, the correlation between the creep force and friction-induced oscillation can be identified. Then the effect of the track curve radius on the friction-induced oscillation of the wheelset–track system can be summarized, which provides an explanation of the typical phenomenon of corrugation
Trajectory optimization of unmanned aerial vehicle in dynamic soaring
An aircraft can extract energy from a gradient wind field by dynamic soaring. The paper presents trajectory optimization of an unmanned aerial vehicle for dynamic soaring by numerical analysis and validates the theoretical work through flight test. The collocation approach is used to convert the trajectory optimization problem into parameters optimization. The control and state parameters include lift coefficient, bank angle, positions, flight path angle, heading angle, and airspeed, which are obtained from the parameter optimization software. To validate the results of numerical simulation, the dynamic soaring experiment is also performed and experimental data are analyzed. This research work shows that the unmanned aerial vehicle can gain enough flight energy from the gradient wind field by following an optimal dynamic soaring trajectory. Meanwhile, the variation of flight path angle, heading angle, and airspeed has a significant influence on the energy transform. The solution can provide theoretical guide to unmanned aerial vehicles for extracting maximum energy from gradient wind fields. </jats:p
Mitigate data skew caused stragglers through ImKP partition in MapReduce
Speculative execution is the mechanism adopted by current MapReduce framework when dealing with the straggler problem, and it functions through creating redundant copies for identified stragglers. The result of the quicker task will be adopted to improve the overall job execution performance. Although proved to be effective for contention caused stragglers, speculative execution can easily meet its bottleneck when mitigating data skew caused stragglers due to its replication nature: the identical unbalanced input data will lead to a slow speculative task. The Map inputs are typically even in size according to the HDFS block configuration, therefore the skew caused stragglers happen mainly in the Reduce phase because of the unknown intermediate key distribution. In this paper, we focus on mitigating data skew caused Reduce stragglers, propose ImKP, an Intermediate Key Pre-processing framework that enables the even distributed partition for Reduce inputs. A group based ranking technique has been developed that dramatically decreases the pre-processing time, and ImKP manages to eliminate this timing overhead through parallelizing the pre-processing with the file uploading procedure (from local file system to HDFS). For jobs that take input directly from HDFS, ImKP minimizes the overhead by storing the mapping result on every node within the cluster for reuse. Experiments are conducted on different datasets with various workloads. Results show that, compared to the popular hash partition, ImKP can dramatically decrease Reduce skew, achieving a 99.8% reduction in the coefficient of variation of the input sizes in average, and improve up to 29.37% job response performance
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Trace doping of multiple elements enables stable battery cycling of LiCoO2 at 4.6 V
LiCoO2 is a dominant cathode material for lithium-ion (Li-ion) batteries due to its high volumetric energy density, which could potentially be further improved by charging to high voltages. However, practical adoption of high-voltage charging is hindered by LiCoO2’s structural instability at the deeply delithiated state and the associated safety concerns. Here, we achieve stable cycling of LiCoO2 at 4.6 V (versus Li/Li+) through trace Ti–Mg–Al co-doping. Using state-of-the-art synchrotron X-ray imaging and spectroscopic techniques, we report the incorporation of Mg and Al into the LiCoO2 lattice, which inhibits the undesired phase transition at voltages above 4.5 V. We also show that, even in trace amounts, Ti segregates significantly at grain boundaries and on the surface, modifying the microstructure of the particles while stabilizing the surface oxygen at high voltages. These dopants contribute through different mechanisms and synergistically promote the cycle stability of LiCoO2 at 4.6 V
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