1,184 research outputs found
Evaluation of the economic and environmental performance of low-temperature heat to power conversion using a reverse electrodialysis - Multi-effect distillation system
In the examined heat engine, reverse electrodialysis (RED) is used to generate electricity from the salinity difference between two artificial solutions. The salinity gradient is restored through a multi-effect distillation system (MED) powered by low-temperature waste heat at 100 ◦C. The current work presents the first comprehensive economic and environmental analysis of this advanced concept, when varying the number of MED effects, the system sizing, the salt of the solutions, and other key parameters. The levelized cost of electricity (LCOE) has been calculated, showing that competitive solutions can be reached only when the system is at least medium to large scale. The lowest LCOE, at about 0.03 €/kWh, is achieved using potassium acetate salt and six MED effects while reheating the solutions. A similar analysis has been conducted when using the system in energy storage mode, where the two regenerated solutions are stored in reservoir tanks and the RED is operating for a few hours per day, supplying valuable peak power, resulting in a LCOE just below 0.10 €/kWh. A life-cycle assessment has been also carried out, showing that the case with the lowest environmental impact is the same as the one with the most attractive economic performance. Results indicate that the material manufacturing has the main impact; primarily the metallic parts of the MED. Overall, this study highlights the development efforts required in terms of both membrane performance and cost reduction, in order to make this technology cost effective in the future
Hyperthermia-Triggered Gemcitabine Release from Polymer-Coated Magnetite Nanoparticles
In this work a combined, multifunctional platform, which was devised for the simultaneous
application of magnetic hyperthermia and the delivery of the antitumor drug gemcitabine, is
described and tested in vitro. The system consists of magnetite particles embedded in a polymer
envelope, designed to make them biocompatible, thanks to the presence of poly (ethylene glycol) in
the polymer shell. The commercial particles, after thorough cleaning, are provided with carboxyl
terminal groups, so that at physiological pH they present negative surface charge. This was proved by
electrophoresis, and makes it possible to electrostatically adsorb gemcitabine hydrochloride, which is
the active drug of the resulting nanostructure. Both electrophoresis and infrared spectroscopy are
used to confirm the adsorption of the drug. The gemcitabine-loaded particles are tested regarding
their ability to release it while heating the surroundings by magnetic hyperthermia, in principle
their chances as antitumor agents. The release, with first-order kinetics, is found to be faster when
carried out in a thermostated bath at 43 ºC than at 37 ºC, as expected. But, the main result of this
investigation is that while the particles retain their hyperthermia response, with reasonably high
heating power, they release the drug faster and with zeroth-order kinetics when they are maintained
at 43 ºC under the action of the alternating magnetic field used for hyperthermia.This research work is supported by MINECO Ramón y Cajal programme (RYC-2014-16901);
Junta de Andalucía (PE2012-FQM694) and Feder Funds UE
Reverse electrodialysis heat engine with multi-effect distillation: Exergy analysis and perspectives
The increasing worldwide energy demand is rising the interest on alternative power production technologies based on renewable and emission-free energy sources. In this regard, the closed-loop reverse electrodialysis heat engine is a promising technology with the potential to convert low-grade heat into electric power. The reverse electrodialysis technology has been under investigation in the last years to explore the real potentials for energy generation from natural and artificial solutions, and recent works have been addressing also the potential of its coupling with regeneration strategies, looking at medium and large energy supply purposes. In this work, for the first time, a comprehensive exergy analysis at component level is applied to a reverse electrodialysis heat engine with multi-effect distillation in order to determine the real capability of the waste heat to power conversion, identifying and quantifying the sources of exergy destruction. In particular, sensitivity analyses have been performed to assess the influence of the main operating conditions (i.e. solutions concentration and velocity) and design features (aspect ratio of the pile), characterizing the most advantageous scenarios and including the effect of new generations of membranes. Results show that the multi-effect distillation unit is the main source of exergy destruction. Also, using high-performing membranes, inlet solutions concentration and velocity of 4.5\u20130.01 mol/L and 0.2\u20130.36 cm/s, respectively, a global exergy efficiency of 24% is reached for the system, proving the high potential of this technology to sustainably convert waste heat into power
The dependence of oxygen and nitrogen abundances on stellar mass from the CALIFA survey
We analysed the optical spectra of HII regions extracted from a sample of 350
galaxies of the CALIFA survey. We calculated total O/H abundances and, for the
first time, N/O ratios using the semi-empirical routine HII-CHI-mistry, which,
according to P\'erez-Montero (2014), is consistent with the direct method and
reduces the uncertainty in the O/H derivation using [NII] lines owing to the
dispersion in the O/H-N/O relation. Then we performed linear fittings to the
abundances as a function of the de-projected galactocentric distances. The
analysis of the radial distribution both for O/H and N/O in the non-interacting
galaxies reveals that both average slopes are negative, but a non-negligible
fraction of objects have a flat or even a positive gradient (at least 10\% for
O/H and 4\% for N/O). The slopes normalised to the effective radius appear to
have a slight dependence on the total stellar mass and the morphological type,
as late low-mass objects tend to have flatter slopes. No clear relation is
found, however, to explain the presence of inverted gradients in this sample,
and there is no dependence between the average slopes and the presence of a
bar. The relation between the resulting O/H and N/O linear fittings at the
effective radius is much tighter (correlation coefficient = 0.80) than
between O/H and N/O slopes ( = 0.39) or for O/H and N/O in the
individual \hii\ regions ( = 0.37). These O/H and N/O values at the
effective radius also correlate very tightly (less than 0.03 dex of dispersion)
with total luminosity and stellar mass. The relation with other integrated
properties, such as star formation rate, colour, or morphology, can be
understood only in light of the found relation with mass.Comment: Accepted for publication in A&A. 20 pages, 19 figure
Первичная сексуально−эротическая дезадаптация как причина внебрачных связей супругов
Показаны закономерности развития, проявления и течения сексуально−эротической формы первичной дезадаптации супругов, имеющиеся у них варианты и разновидности сексуальной дезадаптации. Описаны причины, частота и характер обусловленных этой формой дезадаптации внебрачных связей, моральные качества и личностные особенности супругов, способствующие совершению ими супружеских измен. Дается рекомендация учитывать полученные в исследовании данные при психотерапевтической коррекции сексуально−эротической дезадаптации и разработке системы психопрофилактики сопровождающего ее внебрачного секса.The regularities of development, manifestations and course of sexual−erotic form of primary spouse dysadaptation as well as the variants and varieties of dysadaptation are shown. The causes, frequency and character of extramarital relations due to this form of dysadaptation, moral qualities and personality peculiarities of the spouses providing marital unfaithfulness are described. It is recommended to consider the received information in psychopreventive correction of sexual−erotic dysadaptation and working out the system of psychoprevention of the extramarital sex
Aperture effects on the oxygen abundance determinations from CALIFA data
This paper aims at providing aperture corrections for emission lines in a
sample of spiral galaxies from the Calar Alto Legacy Integral Field Area Survey
(CALIFA) database. In particular, we explore the behavior of the
log([OIII]5007/Hbeta)/([NII]6583/Halpha) (O3N2) and log[NII]6583/Halpha (N2)
flux ratios since they are closely connected to different empirical
calibrations of the oxygen abundances in star forming galaxies.
We compute median growth curves of Halpha, Halpha/Hbeta, O3N2 and N2 up to
2.5R_50 and 1.5 disk R_eff. The growth curves simulate the effect of observing
galaxies through apertures of varying radii. The median growth curve of the
Halpha/Hbeta ratio monotonically decreases from the center towards larger
radii, showing for small apertures a maximum value of ~10% larger than the
integrated one. The median growth curve of N2 shows a similar behavior,
decreasing from the center towards larger radii. No strong dependence is seen
with the inclination, morphological type and stellar mass for these growth
curves. Finally, the median growth curve of O3N2 increases monotonically with
radius. However, at small radii it shows systematically higher values for
galaxies of earlier morphological types and for high stellar mass galaxies.
Applying our aperture corrections to a sample of galaxies from the SDSS
survey at 0.02<=z<=0.3 shows that the average difference between fiber-based
and aperture corrected oxygen abundances, for different galaxy stellar mass and
redshift ranges, reaches typically to ~11%, depending on the abundance
calibration used. This average difference is found to be systematically biased,
though still within the typical uncertainties of oxygen abundances derived from
empirical calibrations. Caution must be exercised when using observations of
galaxies for small radii (e.g. below 0.5R_eff) given the high dispersion shown
around the median growth curves.Comment: Accepted for publication in Ap
Is type of work associated with physical activity and sedentary behaviour in women with fibromyalgia A cross-sectional study from the al-Ándalus project
Objectives To analyse the association between the type of work (productive vs reproductive work) and the levels of physical activity and sedentary behaviour in women with fibromyalgia. Method This cross-sectional study involved 258 women with fibromyalgia from southern Spain. Of them, 55% performed reproductive work (unpaid, associated with caregiving and domestic roles) exclusively, while 45% had productive job (remunerated, that results in goods or services). Physical activity of light, moderate and vigorous intensity in the leisure time, at home, at work, and totally were measured through the leisure time physical activity instrument and with the physical activity at home and work instrument, respectively. Sedentary behaviour was measured by the Sedentary Behaviour Questionnaire. Results After adjusting for age, fat percentage, education level and marital status, the multivariate analysis of covariance model informed the existence of significant differences between type of work groups (p<0.001). Women with productive work engaged in more light physical activity at work (mean difference =448.52 min; 95 % CI 179.66 to 717.38; p=0.001), and total physical activity of light (809.72 min; 535.91 to 1085.53; p<0.001) and moderate (29
Spiral-like star-forming patterns in CALIFA early-type galaxies
Based on a combined analysis of SDSS imaging and CALIFA integral field
spectroscopy data, we report on the detection of faint (24 < {\mu}
mag/arcsec < 26) star-forming spiral-arm-like features in the periphery of
three nearby early-type galaxies (ETGs). These features are of considerable
interest because they document the still ongoing inside-out growth of some
local ETGs and may add valuable observational insight into the origin and
evolution of spiral structure in triaxial stellar systems. A characteristic
property of the nebular component in the studied ETGs, classified i+, is a
two-radial-zone structure, with the inner zone that displays faint
(EW(H\alpha)1{\AA}) low-ionization nuclear emission-line region (LINER)
properties, and the outer one (3{\AA}<EW(H\alpha)<~20{\AA}) HII-region
characteristics. This spatial segregation of nebular emission in two physically
distinct concentric zones calls for an examination of aperture effects in
studies of type i+ ETGs with single-fiber spectroscopic data.Comment: Accepted to A&A, 5 pages, 1 figur
Stellar Population gradients in galaxy discs from the CALIFA survey
While studies of gas-phase metallicity gradients in disc galaxies are common,
very little has been done in the acquisition of stellar abundance gradients in
the same regions. We present here a comparative study of the stellar
metallicity and age distributions in a sample of 62 nearly face-on, spiral
galaxies with and without bars, using data from the CALIFA survey. We measure
the slopes of the gradients and study their relation with other properties of
the galaxies. We find that the mean stellar age and metallicity gradients in
the disc are shallow and negative. Furthermore, when normalized to the
effective radius of the disc, the slope of the stellar population gradients
does not correlate with the mass or with the morphological type of the
galaxies. Contrary to this, the values of both age and metallicity at 2.5
scale-lengths correlate with the central velocity dispersion in a similar
manner to the central values of the bulges, although bulges show, on average,
older ages and higher metallicities than the discs. One of the goals of the
present paper is to test the theoretical prediction that non-linear coupling
between the bar and the spiral arms is an efficient mechanism for producing
radial migrations across significant distances within discs. The process of
radial migration should flatten the stellar metallicity gradient with time and,
therefore, we would expect flatter stellar metallicity gradients in barred
galaxies. However, we do not find any difference in the metallicity or age
gradients in galaxies with without bars. We discuss possible scenarios that can
lead to this absence of difference.Comment: 24 pages, 17 figures, accepted for publication in A&
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