Three-dimensional global scale underwater sound modeling: The T-phase wave propagation of a southern Mid-Atlantic ridge earthquake

Author Posting. © Acoustical Society of America, 2019. This article is posted here by permission of Acoustical Society of America for personal use, not for redistribution. The definitive version was published in Journal of the Acoustical Society of America 146(3), (2019): 2124-2135, doi:10.1121/1.5126010.A three-dimensional (3D) geodesic Cartesian parabolic equation model is utilized to study the propagation of low-frequency underwater sound (5 to 20 Hz), the so-called T-phase wave, triggered by a Southern Mid-Atlantic Ridge earthquake. The sound from the earthquake was recorded at 1050 km from the epicenter by the deep water hydrophones of the Comprehensive Nuclear-Test-Ban Treaty Organization network near Ascension Island. A few hours later and at 8655 km from the epicenter, the hydrophones of the Shallow Water 2006 experiment in the U.S. East coast also registered the sound. Recorded field data showed discrepancies between expected and measured arrival angles indicating the likely occurrence of horizontal sound reflection in the long waveguide journey. Numerical modeling of this T-phase wave propagation across the Atlantic Ocean with realistic physical oceanographic inputs was performed, and the results showed the importance of 3D effects induced by the Mid-Atlantic Ridge and Atlantic Islands. Future research directions, including localization of T-phase wave generation/excitation locations, are also discussed.The authors acknowledge David Bradley and Stephen Nichols for the access and support analyzing CTBTO data. The first author acknowledges the Postdoctoral Scholar Program at the Woods Hole Oceanographic Institution, with funding provided by the University of Haifa. The funding supports for the second author were from the Office of Naval Research, USA, under Grant No. N00014-17-1-2692.2020-03-3

Solution of an associating lattice gas model with density anomaly on a Husimi lattice

We study a model of a lattice gas with orientational degrees of freedom which resemble the formation of hydrogen bonds between the molecules. In this model, which is the simplified version of the Henriques-Barbosa model, no distinction is made between donors and acceptors in the bonding arms. We solve the model in the grand-canonical ensemble on a Husimi lattice built with hexagonal plaquettes with a central site. The ground-state of the model, which was originally defined on the triangular lattice, is exactly reproduced by the solution on this Husimi lattice. In the phase diagram, one gas and two liquid (high density-HDL and low density-LDL) phases are present. All phase transitions (GAS-LDL, GAS-HDL, and LDL-HDL) are discontinuous, and the three phases coexist at a triple point. A line of temperatures of maximum density (TMD) in the isobars is found in the metastable GAS phase, as well as another line of temperatures of minimum density (TmD) appears in the LDL phase, part of it in the stable region and another in the metastable region of this phase. These findings are at variance with simulational results for the same model on the triangular lattice, which suggested a phase diagram with two critical points. However, our results show very good quantitative agreement with the simulations, both for the coexistence loci and the densities of particles and of hydrogen bonds. We discuss the comparison of the simulations with our results.Comment: 12 pages, 5 figure

Three-dimensional modeling of T-wave generation and propagation from a South Mid-Atlantic Ridge earthquake

© The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Lecoulant, J., Oliveira, T. C. A., & Lin, Y.-T. Three-dimensional modeling of T-wave generation and propagation from a South Mid-Atlantic Ridge earthquake. The Journal of the Acoustical Society of America, 150(5), (2021): 3807, https://doi.org/10.1121/10.0007072.A three-dimensional (3D) hybrid modeling method is used to study the generation and propagation of T waves in the ocean triggered by a Southern Mid-Atlantic Ridge earthquake. First, a finite-element method model named SPECFEM3D is used to propagate seismic waves in the crust and acoustic waves in the ocean for the T-wave generation in a 200 × 50 km area near the epicenter. A 3D parabolic equation (PE) method is then used to propagate the T waves in the ocean for about 850 km further to the hydrophone stations deployed by the Comprehensive Nuclear-Test-Ban Treaty Organization (CTBTO) near Ascension Island. All of the simulations considered the realistic bathymetry and water sound speed profile. The SPECFEM3D results suggest that T waves with clear modal features could be generated by the concentration of reflected head waves in two depressions 40 km away from the epicenter. To compare with the hybrid modeling method for calculating T-wave propagation losses and arrival azimuths at the CTBTO hydrophones, point source simulations using the 3D PE model from the T waves source locations, identified with SPECFEM3D, were also implemented. The advantages and limitations of each approach are discussed.T.C.A.O. thanks FCT/MCTES for the financial support to CESAM (Grant No. UIDP/50017/2020+UIDB/50017/2020) through national funds. Support from the Office of Naval Research (ONR) to Y.-T.L. (Grant No. N00014-17-1–2692) is also acknowledged

Megameter propagation and correlation of T-waves from Kermadec Trench and Islands

On 18 June 2020 and 4 March 2021, very energetic low-frequency underwater T-wave signals (2 to 25 Hz) were recorded at the Comprehensive Nuclear-Test-Ban Treaty (CTBT) International Monitoring System (IMS) hydrophone stations in the Pacific Ocean (Stations HA11 and HA03) and the South Atlantic Ocean (Station HA10). This work investigates the long-range (megameters) propagation of these T-waves. Their sources were three powerful submarine earthquakes in the Kermadec Trench and Islands, located at approximately 6000, 8800, and 15100 km from Stations HA11, HA03, and HA10, respectively. Arrival time and back azimuth of the recorded T-waves were estimated using the Progressive Multi-Channel Correlation algorithm installed on the CTBT Organization (CTBTO) virtual Data Exploitation Centre (vDEC). Different arrivals within the duration of the earthquake signals were identified, and their correlations were also analyzed. The data analysis at HA03 and HA10 revealed intriguing T-wave propagation paths reflecting, refracting, or even transmitting through continents, as well as T-wave excitation along a chain of seamounts. The analysis also showed much higher transmission loss (TL) in the propagation paths to HA11 than to HA03 and HA10. Moreover, strong discrepancies between expected and measured back azimuths were observed for HA11, and a three-dimensional (3D) parabolic equation model was utilized to identify the cause of these differences. Numerical results revealed the importance of 3D effects induced by the Kermadec Ridge, Fiji archipelago, and Marshall Islands on T-wave propagation to HA11. This analysis can guide future improvements in underwater event localization using the CTBT-IMS hydroacoustic sensor network.info:eu-repo/semantics/publishedVersio

Fucoidan immobilized at the surface of a fibrous mesh presents toxic effects over melanoma cells, but not over non-cancer skin cells

The use of fucoidan, a marine-origin bioactive polymer, is herein proposed as a component of an innovative and effective strategy against melanoma, one of the most aggressive skin cancers. First, fucoidan antitumor activity, in its soluble form, was assessed presenting increased cytotoxicity over melanoma cells when compared to human dermal fibroblasts and keratinocytes. After this antitumor activity validation and trying to develop a more targeted and local strategy aiming to diminish the cytotoxic effects over noncancer cells, fucoidan was immobilized at the surface of an electrospun nanofiber mesh (NFM_Fu), envisioning the development of a therapeutic patch. The maximum immobilization concentration was 1.2 mg mLâ 1, determined by the Toluidine Blue Assay and confirmed by XPS. Furthermore, NFM_Fu is more hydrophilic than NFM, presenting a contact angle of 36°, lower than the 121° of the control condition. NFM_Fu was able to reduce human melanoma cell viability by 50% without affecting human dermal fibroblasts and keratinocytes. Taken together, these results set the basis for a valuable approach for melanoma treatment.This work was developed under the scope of the Structured Projects for R&D&I NORTE-01-0145-FEDER-000021 and NORTE-01-0145-FEDER-000023 supported by the Northern Portugal Regional Operational Programme (NORTE 2020),under the Portugal 2020 Partnership Agreement. The authors would like also to thank NORTE 2020 for financing the Ph.D.scholarship of C.O.“Norte-08-5369-000037”and the Portuguese Foundation for Science and Technology for the Investigator Grant of A.M. (IF/00376/2014). Dr. Luísa Rodrigues is acknowledged by the XPS analysis

Effective Targeting Of Proton Transfer At Ground And Excited States Of Ortho-(2 '-imidazolyl)naphthol Constitutional Isomers

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Steady-state and time-resolved spectroscopy and quantum chemical computational studies were employed to investigate ground and excited state proton transfer of a novel series of ortho-(1H-imidazol-2-yl)naphthol constitutional isomers: 1-(1H-imidazol-2-yl)naphthalen-2-ol (1NI2OH), 2-(1H-imidazol-2-yl)naphthalen-1-ol (2NI1OH) and 3-(1H-imidazol-2-yl)naphthalen-2-ol (3NI2OH). Proper Near Attack Conformations (NACs) involving a strong intramolecular hydrogen bond between the naphthol moiety and the ortho-imidazole group account for the highest ground state acidity of 2NI1OH compared with 1NI2OH and 3NI2OH. Moreover, ESIPT for 2NI1OH and 3NI2OH is further associated with planar chelate H-ring formation whereas 1NI2OH shows the highest ESIPT barrier and a noncoplanar imidazole group. In addition to energetic and structural requirements, the final state also depends on electronic configuration of the ESIPT product with the neutral 3NI2OH showing an ICT effect that correlates with the excited state pKa of the cationic species.17424042415Brazilian Foundation INCT-CataliseConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Fundação de Amparo à Pesquisa do Estado de Minas Gerais (FAPEMIG)Fundação de Amparo à Pesquisa do Estado de Minas Gerais (FAPEMIG)Brazilian Foundation Pro-Reitoria de Pesquisa da UFMGConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq

Constrangimento mecânico provocado pela válvula aquatrainer® associada ao sistema de oximetria directa (K4 B2) na cinemática de crol

O estudo teve como objectivo determinar o constrangimento cinemático provocado pela válvula de treino Aquatrainer® (Cosmed, Roma, Itália), integrada com o sistema portátil analisador de gases K4 b2 (Cosmed, Roma, Itália), durante um esforço máximo na técnica de Crol. O protocolo consistiu na realização de dois percursos à intensidade máxima de 100 m Crol, em piscina de 50 metros: um percurso com o sistema de oximetria acoplado e outro em nado livre (sem o sistema) e um intervalo mínimo de 48 horas por seis crolistas. Duas câmaras registaram respectivamente imagens aéreas e subaquáticas no plano sagital. Foi efectuada a análise cinemática (Ariel Performance Analysis System, Ariel Dynamics Inc., Califórnia, EUA) de um ciclo gestual completo, através de um leitor de vídeo a 50 Hz (Panasonic, AG 7355, Japão). A duração do teste foi significativamente superior no nado constrangido do que no nado livre (P = 0.04). Sem a válvula os nadadores cumpriram os 100 metros em 95.24 ± 2.18 % do seu recorde pessoal e com a válvula a 90.99 ± 2.86 %. As restantes variáveis não apresentaram diferenças significativas entre as duas condições de exercitação. Verificou-se uma tendência para a frequência gestual (-1.58 %), distância de ciclo (-3.62 %), a velocidade de nado (-5.75 %), a a flutuação da velocidade do centro de massa (-2.21 %) e o índice de nado (-9.27 %) serem inferiores com a utilização da válvula. Já a o período do ciclo foi superior no nado constrangido do que no nado livre (1.63 %)

On the use of organic semiconductors as handles for optical tweezers experiments: trapping and manipulating polyaniline (PANI) microparticles

Here we propose the use of the organic semiconductor polyaniline (PANI) for the preparation of spherical-shaped microparticles to serve as handles in optical tweezers (OT) experiments. The stable trapping and manipulation of PANI beads was demonstrated for the first time, using a Gaussian ($TEM_{00}$) beam optical tweezers. The trap stiffness was characterized for various different parameters such as the bead radius, the laser power and the distance between the bead and the coverslip of the sample chamber, attesting the viability of using such material for optical manipulation. Since the effective optical properties of PANI can be modulated by the synthesis process, new related applications are also proposed. The results of the present work therefore open the door for using semiconductor polymeric materials in OT applications.Comment: 10 pages and 5 figure

The African hind's (Cephalopholis taeniops, serranidae) use of artificial reefs off Sal Island (Cape Verde): a preliminary study based on acoustic telemetry

The African hind Cephalopholis taeniops (Valenciennes, 1828) is one of the most important commercial demersal species caught in the Cape Verde archipelago. The species is closely associated with hard substrate and is one of the main attractions for SCUBA divers. In January 2006 a former Soviet fishing vessel - the Kwarcit - was sunk off Santa Maria Bay (Sal Island). Young C. taeniops are commonly observed in this artificial reef (AR). In order to investigate the species' use of the AR, 4 specimens were captured and surgically implanted underwater with Vemco brand acoustic transmitters. The fish were monitored daily with an active telemetry receiver for one week after release. Simultaneously, an array of 3 passive VR2 / VR2W receivers was set for 63 days, registering data that allowed an analysis of spatial, daily and short term temporal activity patterns. The results showed site fidelity to the AR, with no migrations to the nearby natural reef. The method used allowed to register a consistent higher activity during daytime and a preference for the area opposite the dominant current