Removal of chromium and nickel ions from aqueous solution by adsorption on modified coconut husk

The study investigated the adsorption of Cr(VI) and Ni(II) on modified coconut husk (low cost adsorbent) for the remediation of Cr(VI) and Ni(II) from some synthetic industrial waste effluents. The coconut husk was modified by mixing with 0.1 M NaOH and HCl respectively. The effects of varying adsorbent loading, hydrogen ion concentration, contact time and temperature of adsorption were studied. Similar experiments were carried out using unmodified coconut husk, in order to compare the results obtained from the modification experiments. The result showed that the HCl modified adsorbent gave 96% ± 3.6 removal for Cr(VI) at a pH of 4.0 while about 99% ± 0.7 of Ni(II) was removed at a higher pH of 7.0. The unmodified adsorbent gave a 90% ± 8.8 adsorption for Cr(VI) and 97% ± 1.5 for Ni(II) respectively. However, the NaOH modified adsorbent gave the least adsorption of 40% ± 9.9 for Cr(VI) and 80% ± 6.1 for Ni(II). The equilibrium data for the adsorption of Cr(VI) and Ni(II) on coconut husk was tested using both the Freundlich and Langmuir adsorption isotherms. The Freundlich isotherm was found to be more suitable for Cr(VI) adsorption, while the Langmuir isotherm was observed to better for Ni adsorption on coconut husk. To evaluate the mechanism of adsorption, pseudo-first order and second order kinetic models were used. The adsorption mechanism was found fit the second order. The HCl modified adsorbent gave the best result for removal of Cr(VI) from synthetic industrial effluents

Property Rental Value Classification Model: A Case of Osogbo, Osun State, Nigeria

Residential property rental value forecasting has an impact on property investment decision. This necessitates the need for a study to forecast residential property rental value considering all associated variables including presence of cultural sites in the study area. Data for the study were gathered from the record of recent lettings in the study area. For the purpose of precision, this study adopted three artificial intelligence models. These are artificial neural network, logistic regression and support vector machine as models of classifying the rental value of residential property in Osogbo. The study considered relevant input variables among which are distance to cultural site, age of building, state of exterior/interior of building. Findings from the study revealed that the three adopted forecasting models had over 80% of the forecasted properties correctly classified thus making the residential property rental forecasting very reliable. Also, it was established that, in the study area, distance from cultural site is the property attribute with the highest negative impact on rental value

YekinniOyedeji Taofeeq, Owolabi Ayotunde Olayinka and Obaniyi Kayode Samuel (2023) Extension Practitioners Perception and Constraints on ICT Use in Southwestern Nigeria. SAGE Open 2023 13:4, pg 1-14

The study examined the perception and constraints of extension practitioners on utilization of communication technologies in southwestern Nigeria. This was necessitated by the need to ensure a practicable, vibrant, and efficient extension service delivery in the study area. 124 public and 41 non-public extension practitioners were selected through a three staged sam�pling procedure. Questionnaires were used to elicit vital information on their perceptions on ICT use, constraints faced dur�ing ICT use and other components. These were analyzed using descriptive statistics, mean difference, PPMC, and independent sample t-test. The results showed that (61.0%) of respondents from non-public organizations fell within those with favorable perception level. Also, (64.50%) of respondents had high level of constraints to ICT access. Moreover, (58.10%) of respondents from the public organizations’ encountered high level of constraint to ICT use. Result showed that respondents from the public extension organizations were more constrained in access to (14.10 6 3.17) and use of ICT tools (10.84 6 3.30) and were significant. The study has implications for providing functional ICT tools to the respondents for effective extension delivery. Agricultural extension service organizations should organize more frequent in-house trainings on the benefits of ICT use in relation to their extension wor

Anti-staphylococcal, anti-HIV and cytotoxicity studies of four South African medicinal plants and isolation of bioactive compounds from Cassine transvaalensis (Burtt. Davy) codd

Background: Medicinal plants represent an important opportunity to rural communities in Africa, as a source of affordable medicine and as a source of income. Increased patient awareness about safe usage is important as well as more training with regards to traditional medicine. The aim of this study was to evaluate the ethnomedicinal prowess of some indigenous South African plants commonly used in Eastern Cape Province of South Africa for the treatment of skin and respiratory tract infections, HIV and their toxicity potential. Methods: Cassine transvaalensis, Vangueria infausta, Croton gratissimus and Vitex ferruginea were tested for antibacterial activities against Staphylococcus aureus and Staphylococcus epidermidis using Kirby-Bauer disk diffusion and minimum inhibition concentration (MIC). Cytotoxic and anti-HIV-1 activities of plants were tested using MTT Assay (3- (Dimethylthiozole-2-yl-2,5-diphenyltetrazolium bromide)) and anti- HIV-1iib assay. In search of bioactive lead compounds, Cassine transvaalensis which was found to be the most active plant extract against the two Staphylocoous bacteria was subjected to various chromatographic. Thin layer chromatography, Column chromatography and Nuclear Magnetic Resonance (NMR), (1H-1H, 13C-13C, in DMSO_d6, Bruker 600 MHz) were used to isolate and characterize 3-Oxo-28-hydroxylbetuli-20(29)-ene and 3,28-dihydroxylbetuli-20(29)-ene bioactive compounds from C. transvaalensis. Results: The four plants studied exhibited bioactive properties against the test isolates. The zones of inhibition rangedbetween 16 mm to 31 mm for multi-drug resistant staphylococci species. MIC values varied between 0.6 and 0.02 μg/ml. C. gratissimus and C. transvaalensis exhibited the abilities to inhibit HIV-1iib. Two bioactive compounds were isolated from C. transvaalensis. Conclusion: Data from this study reveals the use of these plant by traditional healers in the Eastern Cape. Furthermore, C. transvaalensis and C. gratissimus were found to be more active as against HIV-1iib. While C. transvaalensis was most active against the two Staphylococcus bacteria

Anti-staphylococcal, anti-HIV and cytotoxicity studies of four South African medicinal plants and isolation of bioactive compounds from Cassine transvaalensis (Burtt. Davy) codd

Background: Medicinal plants represent an important opportunity to rural communities in Africa, as a source of affordable medicine and as a source of income. Increased patient awareness about safe usage is important as well as more training with regards to traditional medicine. The aim of this study was to evaluate the ethnomedicinal prowess of some indigenous South African plants commonly used in Eastern Cape Province of South Africa for the treatment of skin and respiratory tract infections, HIV and their toxicity potential. Methods: Cassine transvaalensis, Vangueria infausta, Croton gratissimus and Vitex ferruginea were tested for antibacterial activities against Staphylococcus aureus and Staphylococcus epidermidis using Kirby-Bauer disk diffusion and minimum inhibition concentration (MIC). Cytotoxic and anti-HIV-1 activities of plants were tested using MTT Assay (3- (Dimethylthiozole-2-yl-2,5-diphenyltetrazolium bromide)) and anti- HIV-1iib assay. In search of bioactive lead compounds, Cassine transvaalensis which was found to be the most active plant extract against the two Staphylocoous bacteria was subjected to various chromatographic. Thin layer chromatography, Column chromatography and Nuclear Magnetic Resonance (NMR), (1H-1H, 13C-13C, in DMSO_d6, Bruker 600 MHz) were used to isolate and characterize 3-Oxo-28-hydroxylbetuli-20(29)-ene and 3,28-dihydroxylbetuli-20(29)-ene bioactive compounds from C. transvaalensis. Results: The four plants studied exhibited bioactive properties against the test isolates. The zones of inhibition rangedbetween 16 mm to 31 mm for multi-drug resistant staphylococci species. MIC values varied between 0.6 and 0.02 μg/ml. C. gratissimus and C. transvaalensis exhibited the abilities to inhibit HIV-1iib. Two bioactive compounds were isolated from C. transvaalensis. Conclusion: Data from this study reveals the use of these plant by traditional healers in the Eastern Cape. Furthermore, C. transvaalensis and C. gratissimus were found to be more active as against HIV-1iib. While C. transvaalensis was most active against the two Staphylococcus bacteria

Microbiological quality of ready to eat coleslaw marketed in Ibadan, Oyo-State, Nigeria

ABSTRACTThis study assessed the microbiological quality of coleslaw samples sold at restaurants in Ibadan, Oyo-state, Nigeria. Three hundred and sixty samples were analyzed over a 12-week period for aerobic mesophilic counts, psychrotrophic counts, levels of Enterobacteriaceae, yeasts and molds, total lactic acid bacteria and total anaerobes. The coleslaw samples were also analyzed for presumptive L. monocytogenes and Salmonella spp. Counts of up to 9.2, 8.2, 9.4, 9.0, 8.7, and 8.9 log CFU/g for aerobic mesophilic organisms, psychrotrophic counts, Enterobacteriaceae, yeasts and molds, total lactic acid bacteria and total anaerobes, respectively, were recovered from the coleslaw samples. Despite high counts of yeasts and molds and LAB (up to 9 and 8.7 log CFU/g, respectively) recovered from some samples, no visible spoilage was detected. The levels of microorganisms recovered from the coleslaw samples at different sample collection time (week 1–12) were significantly (P < 0.05) different for each restaurant. Similarly, microbial levels recovered from coleslaw samples collected from different restaurants differed significantly (P < 0.05) from one restaurant to the other. Thirty (30.5%) and 24.7% of the coleslaw samples were positive for presumptive L. monocytogenes and Salmonella, respectively, an indication of potential threats to food safety in the area. The study concluded that the roles of yeasts and molds, as well as LAB in the spoilage of coleslaw sold in the study area, need to be further investigated. Public health intervention strategies to enhance microbiological safety of RTE coleslaw are required in the city