INVESTIGATION OF CORROSION INHIBITION OF MILD STEEL IN 0.5 M HCL WITH AZADIRACTHAINDICA AND SPONDIAMOMBIN

The corrosion behaviour of mild steel in 0.5 M HCl solution in the presence of Azadiracthaindica and Spondiamombin (AS) was investigated using potentiodynamic polarization and weight loss techniques. Pulverized barks of 60 g of each plant were soaked in 1500 ml, 0.5 M HCl for 48 hours, filtered and mixed in the ratio of 1:1 giving a concentration of 400 g/L (serving as 100 % concentration). The AS mixture was then diluted to 20, 40, 60 and 80% (80, 160, 240 and 320 g/L). The weight loss experiment was carried out for 192 hours at ambient temperature (25oC) and corrodant solution without AS served as the control. Potentiodynamic polarization study was carried out using a device called AutolabPotentiostatGalvanostat (PGSTAT101) in the potential range of ±1.5v versus corrosion potential at a scan rate of 0.005 ms-1. The results obtained showed that corrosion rate reduced in the presence of all the concentrations of AS extract investigated. Highest inhibition efficiency of 99.6% obtained was for the polarization measurement why the highest obtained for gravimetric study was 75.39%. Gibb’s free energy of -3.859 kJ mol-1 was obtained, indicating physisorption and the correlation coefficient was 0.996. The study showed that AS was a very good corrosion inhibitor of mild steel in 0.5 M HCl acid.&nbsp

Power System’s Voltage Stability Improvement Using Static Var Compensator

In alternating current systems, voltage fluctuation is a common phenomenon. Most of the voltage fluctuation problems result from the changes in the system’s reactive power resulting from excessive supply or consumption of reactive power by the elements of the system and the variation in the consumers’ loads. In this paper, the effect of Static Var Compensator (SVC) in stabilizing power system’s voltage through effective reactive power compensation was investigated. Power flow equations involving voltage drop with/without SVC were developed. SVC modeling equations were also developed and used to determine its parameters. Based on the SVC parameters, SIMULINK blocks were used to implement the phase controlled Thyristor–Controlled-Reactor Fixed-Capacitor (TCR-FC) SVC. The Nigerian 28-bus power system used for the study was also modeled using SIMULINK/MATLAB. The 28-bus system was first simulated without SVC and then with two SVCs located at different buses to obtain the bus voltages in both cases. From the bus voltages the total voltage drops for the system with and without SVC were estimated and compared. The compared results clearly showed that, the system’s voltage drop was reduced by 33.78% indicating a significant improvement in the system’s voltage stability when SVCs were applied

Yellow Vein Mosaic disease in kenaf (Hibiscus cannabinus l.) under different sowing dates in two agroecologies

Determination of appropriate sowing dates is an important approach towards obtaining optimum crop yield as it affects the resistance/susceptibility of crops to insect pests and diseases. The study investigated the effect of three sowing dates (May, June and July) on the occurrence and incidence of yellow vein mosaic disease in kenaf variety (IFEKEN-100) planted in the experimental fields of the Institute of Agricultural Research and Training (IAR&T) located in Ibadan and Ilora. The incidence of yellow vein mosaic disease was high in May at the two locations with means of 25 and 30% for Ibadan and Ilora, respectively. Plant height was not significantly different in the two locations across the three months. The highest stem diameter was obtained in May from Ilora and Ibadan with means of 1.44 and 1.53 cm, respectively. The best bast fiber yield was recorded in June at Ibadan with a mean value of 1.72 tha-1. Nucleic acid spot hybridization (NASH) was used to confirm the disease and the results revealed that Begomovirus was present in kenaf sowm in the two locations during the period of the three months except in kenaf sown in July at Ilora. The results of this study revealed the importance of sowing dates on the occurrence of viral diseases on the field. If the sowing date is optimum, the effect of viruses may not be pronounced in the crop as seen in the month of June having relatively low virus incidence as well as the highest plant height and bast fibre yield.Keywords: Begomovirus, kenaf, nucleic acid hybridization, yiel

The Rhetoric Of Celebrity Endorsement Strategy And Consumer Purchase Intention On Fast Moving Consumer Goods Among Al-Hikmah University Undergraduate Students

The ultimate goal of any business organization is to be prosperous in today’s increasingly competitive and dynamic markets where the cost of acquiring new customers has been found to be exponentially greater than that of maintaining existing ones, firms must continually explore ways of achieving higher customer retention rates. The building of a reputable brand image in the mind of the consumers is especially enhanced through the use of endorsers or spokespersons in the firm’s marketing communications; and celebrities are among the persons commonly used as endorsers or spokespersons in this regard

Investigative study of seasonal changes in Quality Parameters of Oluwa River Water, Agbabu area of Nigeria

Physico-chemical parameters of River Oluwa water in Agbabu, Nigeria were investigated to determine its quality characteristics and establish seasonal effects on the water. Water from the river was collected at five different points in dry season (March, 2008 and 2009) and rainy season (July, 2008 and 2009). Insitu parameters (pH, EC and Turbidity) were measured using Horiba Water Checker Model U-10 while TDS was by Lovibond CM – 21 Tintometer. Subsequently in the Laboratory, Na+ and K+ were determined using flame photometric methods while Ca2+, Mg2+, HCO3-, SO42-, Cl-, PO42- and NO3- were determined by wet analysis. River Oluwa water was alkaline with average pH of 7.41 and 7.53 in dry and rainy seasons respectively. Electrical conductivity (EC) was high during dry season (av. 630.44 µS/cm), but low in the rainy season (av. 317.58 µS/cm) due to long residence time in dry season allowing more water-rock interaction. Turbidity's average values of 0.14 NTU and 2.29 NTU in dry and rainy seasons respectively suggested moderate pollution with particulate matter. The order of average cations concentrations in the dry and rainy seasons was Ca2+ K+ Na+ Mg2+ while that of the anions was HCO3- Cl- SO42- NO3-. The ions concentrations though lower in rainy season, Ca2+-HCO3- water was dominant in both seasons. Quality evaluation for irrigation revealed that the water was suitable for all irrigation purposes. River Oluwa water was soft, low mineralized, chemically potable, suitable for irrigation but with lower ionic concentrations in rainy season

Development of a novel UPLC-MS/MS-based platform to quantify amines, amino acids and methylarginines for applications in human disease phenotyping

Amine quantification is an important strategy in patient stratification and personalised medicine. This is because amines, including amino acids and methylarginines impact on many homeostatic processes. One important pathway regulated by amine levels is nitric oxide synthase (NOS). NOS is regulated by levels of (i) the substrate, arginine, (ii) amino acids which cycle with arginine and (iii) methylarginine inhibitors of NOS. However, biomarker research in this area is hindered by the lack of a unified analytical platform. Thus, the development of a common metabolomics platform, where a wide range of amino acids and methylarginines can be measured constitutes an important unmet need. Here we report a novel high-throughput ultra-high performance liquid chromatography-tandem mass spectrometry (UHPLC-MS/MS) platform where ≈40 amine analytes, including arginine and methylarginines can be detected and quantified on a molar basis, in a single sample of human plasma. To validate the platform and to generate biomarkers, human plasma from a well-defined cohort of patients before and after coronary artery bypass surgery, who developed systemic inflammatory response syndrome (SIRS), were analysed. Bypass surgery with SIRS significantly altered 26 amine analytes, including arginine and ADMA. Consequently, pathway analysis revealed significant changes in a range of pathways including those associated with NOS

The dynamics of Africa’s fruit and vegetable processing sectors

The production of fruits and vegetables (F&V) in Africa has increased 3.3 percent annually during the last 20 years, but only 0.7 percent in per capita terms (FAOSTAT 2022; Figure 3.1). Africa has the lowest per capita production and consumption of F&V in the world, although South Africa, Morocco, and Egypt are large producers and exporters

Comparison of Bacterial Culture With Biofire® Filmarray® Multiplex PCR Screening of Archived Cerebrospinal Fluid Specimens From Children With Suspected Bacterial Meningitis in Nigeria

BACKGROUND: Diagnosis of bacterial meningitis remains a challenge in most developing countries due to low yield from bacterial culture, widespread use of non-prescription antibiotics, and weak microbiology laboratories. The objective of this study was to compare the yield from standard bacterial culture with the multiplex nested PCR platform, the BioFire® FilmArray® Meningitis/Encephalitis Panel (BioFire ME Panel), for cases with suspected acute bacterial meningitis. METHODS: Following Gram stain and bacterial culture on cerebrospinal fluid (CSF) collected from children aged less than 5 years with a clinical suspicion of acute bacterial meningitis (ABM) as defined by the WHO guidelines, residual CSF specimens were frozen and later tested by BioFire ME Panel. RESULTS: A total of 400 samples were analyzed. Thirty-two [32/400 (8%)] of the specimens were culture positive, consisting of; three Salmonella spp. (2 Typhi and 1 non-typhi), three alpha hemolytic Streptococcus, one Staphylococcus aureus, six Neisseria meningitidis, seven Hemophilus influenzae, 11 Streptococcus pneumoniae and 368 were culture negative. Of the 368 culture-negative specimens, the BioFire ME Panel detected at least one bacterial pathogen in 90 (24.5%) samples, consisting of S. pneumoniae, N. meningitidis and H. influenzae, predominantly. All culture positive specimens for H. influenzae, N. meningitidis and S. pneumoniae also tested positive with the BioFire ME Panel. In addition, 12 specimens had mixed bacterial pathogens identified. For the first time in this setting, we have data on the viral agents associated with meningitis. Single viral agents were detected in 11 (2.8%) samples while co-detections with bacterial agents or other viruses occurred in 23 (5.8%) of the samples. CONCLUSIONS: The BioFire® ME Panel was more sensitive and rapid than culture for detecting bacterial pathogens in CSF. The BioFire® ME Panel also provided for the first time, the diagnosis of viral etiologic agents that are associated with meningoencephalitis in this setting. Institution of PCR diagnostics is recommended as a routine test for suspected cases of ABM to enhance early diagnosis and optimal treatment

Human and preclinical studies of the host-gut microbiome co-metabolite hippurate as a marker and mediator of metabolic health.

OBJECTIVE: Gut microbial products are involved in regulation of host metabolism. In human and experimental studies, we explored the potential role of hippurate, a hepatic phase 2 conjugation product of microbial benzoate, as a marker and mediator of metabolic health. DESIGN: In 271 middle-aged non-diabetic Danish individuals, who were stratified on habitual dietary intake, we applied 1H-nuclear magnetic resonance (NMR) spectroscopy of urine samples and shotgun-sequencing-based metagenomics of the gut microbiome to explore links between the urine level of hippurate, measures of the gut microbiome, dietary fat and markers of metabolic health. In mechanistic experiments with chronic subcutaneous infusion of hippurate to high-fat-diet-fed obese mice, we tested for causality between hippurate and metabolic phenotypes. RESULTS: In the human study, we showed that urine hippurate positively associates with microbial gene richness and functional modules for microbial benzoate biosynthetic pathways, one of which is less prevalent in the Bacteroides 2 enterotype compared with Ruminococcaceae or Prevotella enterotypes. Through dietary stratification, we identify a subset of study participants consuming a diet rich in saturated fat in which urine hippurate concentration, independently of gene richness, accounts for links with metabolic health. In the high-fat-fed mice experiments, we demonstrate causality through chronic infusion of hippurate (20 nmol/day) resulting in improved glucose tolerance and enhanced insulin secretion. CONCLUSION: Our human and experimental studies show that a high urine hippurate concentration is a general marker of metabolic health, and in the context of obesity induced by high-fat diets, hippurate contributes to metabolic improvements, highlighting its potential as a mediator of metabolic health

Energy generation from anaerobic co-digestion of food waste, cow dung and piggery dung.

The study investigated bioenergy generation from anaerobic co-digestion of food wastes (FW), cow dung (CD) and piggery dung (PD). The physicochemical parameters of the substrates were determined before and after digestion following standard procedures after mechanical pretreatment. Throughout the study, pH remained slightly alkaline while temperature varied between 26 and 32 °C. The highest cumulative biogas yield of 0.0488 L was recorded from the digestion of FW + CD + PD on the ninth day. After analyses, the highest methane content of 64.6 was obtained from the digestion of FW + PD while the lowest (54.0%) was from the digestion of FW only. Overall, cumulative biogas production for the four digestion regimes followed the order: FW + CD + PD, FW + PD, FW + CD and FW only respectively. Accumulation of VFAs was recorded at a slow rate during the digestions