Macroscopic ordering of polystyrene carboxylate-modified nanospheres self-assembled at the water-air interface

Copyright © 2010 American Chemical SocietyThis document is the Accepted Manuscript version of a Published Work that appeared in final form in Langmuir, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://dx.doi.org/10.1021/la1009658We present results from an experimental study of ordering characteristics in monolayers of polystyrene nanospheres self-assembled at a water-air interface. We demonstrate that the interaction of spheres, governed by the dissemination of surface charge, leads to the formation of macroscopic close-packed ordered areas or "domains" with a well-defined orientation of the lattice axes over areas of 25 mm(2). It was found that by changing the surface chemistry of the spheres it is possible to modify the balance between the attractive and repulsive forces and thus to control the ordering characteristics. We implemented a model that simulates the process of self-assembly and examines the ordering characteristics for layers with different ratio between attractive and repulsive forces. A good qualitative agreement was found between the simulations and experiment. These studies are technologically relevant as a method of producing nanosphere templates for large area patterned materials

Ferromagnetic microswimmers

Copyright © 2008 The American Physical SocietyWe propose a model for a novel artificial low Reynolds number swimmer, based on the magnetic interactions of a pair of ferromagnetic particles: one with hard and the other with soft magnetic properties, connected by a linear spring. Using a computational model, we analyze the behavior of the system and demonstrate that for realistic values of the parameters involved, the swimmer is capable of self-propelling with average speeds of the order of hundreds of micrometers per second

Advanced Processing of Micropatterned Elasto-Magnetic Membranes

This is the author accepted manuscript. The final version is available from IEEE via the DOI in this record The dataset associated with this article is located in ORE at: https://doi.org/10.24378/exe.1263We report on a fabrication of a highly structured elasto-magnetic membrane with microscopic unit cells using lithographic techniques and electrodeposition. The membrane comprises micromagnets of CoNiP and Co connected via an elastic PDMS network with an area spanning 12 mm². Ellipsoidal CoNiP and circular Co particles were produced by electrodeposition to achieve diameters of 30 (major) and 10 μ m (minor) and 10 μm, respectively, with a thickness in the range of 6-10 μm. The electrodeposition parameters have been optimized on deposition of CoNiP films to produce an in-plane coercivity for CoNiP elements of 435 Oe. The mechanical properties of the elasto-magnetic membrane were confirmed on application of an alternating magnetic field. The proposed methodology offers a new way for fabrication of novel microfluidic and microelectro-mechanical-systems devices.Engineering and Physical Sciences Research Council (EPSRC)European Union Horizon 202

Theory of ferromagnetic microswimmers

Copyright © 2011 Oxford University Press. This is a pre-copy-editing, author-produced PDF of an article accepted for publication in The Quarterly Journal of Mechanics and Applied Mathematics following peer review. The definitive publisher-authenticated version [Volume 64, Issue 3, pp. 239-263] is available online at: http://qjmam.oxfordjournals.org/content/64/3/239This paper considers the dynamics of a microscale swimmer based on two magnetic beads that are elastically coupled together. A time-varying external magnetic field is imposed that has two principal effects: one is to exert a torque on the magnetic beads. The second is to change the orientation of the magnetic field dipoles in one or both beads, depending on their ferromagnetic properties. This then creates an attraction or repulsion between the two dipoles. The combination of dipole attraction/repulsion, moderated by the elastic coupling, and torque gives motions that are not generally time reversible and can lead to unidirectional swimming, that is persistent motion in one direction, in a Stokes flow regime. The equations of motion for the swimmer are set up using a Lagrangian formulation and supplemented by equations giving the dipole orientation of the magnetic fields of the beads in the external field. The equations are non-dimensionalized and key parameters determined. Numerical simulations reveal a number of regimes that are studied using simplified models and multiple scale analysis. Approximate thresholds are obtained above which the swimmer moves in a closed path and below which the orientation is `trapped' giving unidirectional motion. Three mechanisms for such trapping are isolated and discussed

Magnetic imaging by x-ray holography using extended references

International audienceWe demonstrate magnetic lensless imaging by Fourier transform holography using extended references. A narrow slit milled through an opaque gold mask is used as a holographic reference and magnetic contrast is obtained by x-ray magnetic circular dichroism. We present images of magnetic domains in a Co/Pt multilayer thin film with perpendicular magnetic anisotropy. This technique holds advantages over standard Fourier transform holography, where small holes are used to define the reference beam. An increased intensity through the extended reference reduces the counting time to record the farfield diffraction pattern. Additionally it was found that manufacturing narrow slits is less technologically demanding than the same procedure for holes. We achieve a spatial resolution of similar to 30 nm, which was found to be limited by the sample period of the chosen experimental setup. (C) 2011 Optical Society of Americ

Microscale Magneto-Elastic Composite Swimmers at the Air-Water and Water-Solid Interfaces Under a Uniaxial Field

Peer ReviewedPostprint (published version

Tilted X-Ray Holography of Magnetic Bubbles in MnNiGa Lamellae

Nanoscopic lamellae of centrosymmetric ferromagnetic alloys have recently been reported to host the biskyrmion spin texture; however, this has been disputed as the misidentication of topologically trivial type-II magnetic bubbles. Here we demonstrate resonant soft X-ray holographic imaging of topological magnetic states in lamellae of the centrosymmetric alloy (Mn1–xNix)0.65Ga0.35 (x = 0.5), showing the presence of magnetic stripes evolving into single core magnetic bubbles. We observe rotation of the stripe phase via the nucleation and destruction of disclination defects. This indicates the system behaves as a conventional uniaxial ferromagnet. By utilizing the holography with extended reference by autocorrelation linear dierential operator (HERALDO) method, we show tilted holographic images at 30° incidence confirming the presence of type-II magnetic bubbles in this system. This study demonstrates the utility of X-ray imaging techniques in identifying the topology of localized structures in nanoscale magnetism