Esters of (S)-1,2-propanediol and (R,R)-2,3-butanediol — Chiral Compounds Inducing Cholesteric Phases with a Helix Inversion ·

Mesogenic chiral esters of optically active (S)-1,2-propanediol and (R,R)-2,3-butanediol were synthesized. The compounds, added to a nematic phase induce cholesteric phases exhibiting a helix inversion with temperature variation. This effect is independent of the molecular structure of the nematic solvent. The inversion temperature varies only slightly with concentration but can be influenced by the mesogenic substituent

The Role of Covalent Functionalization in the Thermal Stability and Decomposition of Hybrid Layered Hydroxides

The room temperature synthesis of two Co-based hybrid layered hydroxides containing the same organic ligand (suberate [Sub]), one connected through purely electrostatic interactions (CoAl layered double hydroxide [LDH]), and the other covalently functionalized (α-CoII simonkolleite phase) has been carried out. The magnetic properties exhibit an acute difference in the magnetization temperatures (from ≈10 K for the CoAl-LDH to ≈55 K for the α-CoII). Moreover, the role of the covalent functionalization in the thermal stability and the decomposition has been investigated by a forefront characterization tool consisting of thermogravimetric analysis coupled with gas chromatography and mass spectrometry (TG-GC-MS). The LDH exhibits a higher thermal stability of ≈50 ºC with broad mass loss steps, whereas the water molecules interact stronger with the α-CoII(Sub) hybrid, suggesting a higher confinement in the interlayer space. Interestingly, at higher temperatures (>400 ºC), the α-CoII(Sub) gives rise to the selective formation of cycloheptanone, in contrast to the LDH phase leading to different carbonyl containing compounds. These findings offer new fundamental insights into the thermal behavior of hybrid materials based on layered hydroxides, highlighting the important role of covalent functionalization in its properties

A Reanalysis of theUltraviolet Extinction from Interstellar Dust in the Large Magellanic Cloud

We have reanalyzed the Large Magellanic Cloud's (LMC) ultraviolet (UV) extinction using data from the IUE final archive. Our new analysis takes advantage of the improved signal--to--noise of the IUE NEWSIPS reduction, the exclusion of stars with very low reddening, the careful selection of well matched comparison stars, and an analysis of the effects of Galactic foreground dust. Differences between the average extinction curves of the 30 Dor region and the rest of the LMC are reduced compared to previous studies. We find that there is a group of stars with very weak 2175 Ang. bumps that lie in or near the region occupied by the supergiant shell, LMC 2, on the southeast side of 30 Dor. The average extinction curves inside and outside LMC 2 show a very significant difference in 2175 Ang. bump strength, but their far--UV extinctions are similar. While it is unclear whether or not the extinction outside the LMC 2 region can be fit with the relation of Cardelli, Clayton and Mathis (CCM), sightlines near LMC 2 cannot be fit with CCM due to their weak 2175 Ang. bumps. While the extinction properties seen in the LMC lie within the range of properties seen in the Galaxy, the correlations of UV extinction properties with environment seen in the Galaxy do not appear to hold in the LMC.Comment: 29 pages, 10 figures, to be published in Ap

Ultraviolet Imaging Polarimetry of the Large Magellanic Cloud. II. Models

Motivated by new sounding-rocket wide-field polarimetric images of the Large Magellanic Cloud, we have used a three-dimensional Monte Carlo radiation transfer code to investigate the escape of near-ultraviolet photons from young stellar associations embedded within a disk of dusty material (i.e. a galaxy). As photons propagate through the disk, they may be scattered or absorbed by dust. Scattered photons are polarized and tracked until they escape to be observed; absorbed photons heat the dust, which radiates isotropically in the far-infrared, where the galaxy is optically thin. The code produces four output images: near- UV and far-IR flux, and near-UV images in the linear Stokes parameters Q and U. From these images we construct simulated UV polarization maps of the LMC. We use these maps to place constraints on the star + dust geometry of the LMC and the optical properties of its dust grains. By tuning the model input parameters to produce maps that match the observed polarization maps, we derive information about the inclination of the LMC disk to the plane of the sky, and about the scattering phase function g. We compute a grid of models with i = 28 deg., 36 deg., and 45 deg., and g = 0.64, 0.70, 0.77, 0.83, and 0.90. The model which best reproduces the observed polarization maps has i = 36 +2/-5 degrees and g ~0.7. Because of the low signal-to-noise in the data, we cannot place firm constraints on the value of g. The highly inclined models do not match the observed centro-symmetric polarization patterns around bright OB associations, or the distribution of polarization values. Our models approximately reproduce the observed ultraviolet photopolarimetry of the western side of the LMC; however, the output images depend on many input parameters and are nonunique.Comment: Accepted to AJ. 20 pages, 7 figure

The Unusual Infrared Object HDF-N J123656.3+621322

We describe an object in the Hubble Deep Field North with very unusual near-infrared properties. It is readily visible in Hubble Space Telescope NICMOS images at 1.6um and from the ground at 2.2um, but is undetected (with signal-to-noise <~ 2) in very deep WFPC2 and NICMOS data from 0.3 to 1.1um. The f_nu flux density drops by a factor >~ 8.3 (97.7% confidence) from 1.6 to 1.1um. The object is compact but may be slightly resolved in the NICMOS 1.6um image. In a low-resolution, near-infrared spectrogram, we find a possible emission line at 1.643um, but a reobservation at higher spectral resolution failed to confirm the line, leaving its reality in doubt. We consider various hypotheses for the nature of this object. Its colors are unlike those of known galactic stars, except perhaps the most extreme carbon stars or Mira variables with thick circumstellar dust shells. It does not appear to be possible to explain its spectral energy distribution as that of a normal galaxy at any redshift without additional opacity from either dust or intergalactic neutral hydrogen. The colors can be matched by those of a dusty galaxy at z >~ 2, by a maximally old elliptical galaxy at z >~ 3 (perhaps with some additional reddening), or by an object at z >~ 10 whose optical and 1.1um light have been suppressed by the intergalactic medium. Under the latter hypothesis, if the luminosity results from stars and not an AGN, the object would resemble a classical, unobscured protogalaxy, with a star formation rate >~ 100 M_sun/yr. Such UV-bright objects are evidently rare at 2 < z < 12.5, however, with a space density several hundred times lower than that of present-day L* galaxies.Comment: Accepted for publication in the Astrophysical Journal. 27 pages, LaTeX, with 7 figures (8 files); citations & references updated + minor format change

Macromolecular and electrical coupling between inner hair cells in the rodent cochlea

Inner hair cells (IHCs) are the primary receptors for hearing. They are housed in the cochlea and convey sound information to the brain via synapses with the auditory nerve. IHCs have been thought to be electrically and metabolically independent from each other. We report that, upon developmental maturation, in mice 30% of the IHCs are electrochemically coupled in ‘mini-syncytia’. This coupling permits transfer of fluorescently-labeled metabolites and macromolecular tracers. The membrane capacitance, Ca2+-current, and resting current increase with the number of dye-coupled IHCs. Dual voltage-clamp experiments substantiate low resistance electrical coupling. Pharmacology and tracer permeability rule out coupling by gap junctions and purinoceptors. 3D electron microscopy indicates instead that IHCs are coupled by membrane fusion sites. Consequently, depolarization of one IHC triggers presynaptic Ca2+-influx at active zones in the entire mini-syncytium. Based on our findings and modeling, we propose that IHC-mini-syncytia enhance sensitivity and reliability of cochlear sound encoding

Marketing madness or financial folly?: Implementing equity crowdfunding in the record industry

Purpose The purpose of this paper is to explore the implementation of equity crowdfunding (ECF) within the record industry in terms of challenges and opportunities, in addition to the marketing and financial implications for independent music artists and major record labels. Design/methodology/approach This study adopted a qualitative methodology consisting of two-stage interview-based research methods. A total of 44 semi-structured in-depth interviews were conducted with the CEOs of ECF platforms in the record industry, other related record industry informants, independent artist managers and senior executives from major record labels. Findings The loyalty aspect of ECF may have significant marketing potential in terms of inconspicuously using the equity platform as a “prosumer” identification mechanism. As this early career stage of artists is delicate in terms of establishing trust and patronage from their fans, these early marketing and ECF ventures should be implemented directly from the artist without external third-party involvement. Research limitations/implications The implications of this paper’s findings and theoretical model are not limited to the two studied stakeholder groups of the record industry. The insights in relation to the obstinate lack of understanding and clarity (particularly for independent artists) which surround ECF are likely to influence short-term strategic approaches by other players throughout the wider music industry. Practical implications The insights regarding negative approaches towards ECF by the labels may influence future “coopetition strategies” for independent labels, as they seek to navigate the changing industry dynamics. Originality/value This paper is the first study to empirically explore the predominantly under-researched area of ECF implementation in the record industry in terms of marketing and financial consequences for artists and labels. </jats:sec

The effects of dust in simple environments: Large Magellanic Cloud HII regions

We investigate the effects of dust on Large Magellanic Cloud (LMC) HII region spectral energy distributions using arcminute-resolution far-ultraviolet (FUV), H-alpha, far-infrared (FIR), and radio images. Widely-used indicators of the amount of light lost to dust (attenuation) at H-alpha and in the FUV correlate with each other, although often with substantial scatter. There are two interesting systematic discrepancies. First, H-alpha attenuations estimated from the Balmer decrement are lower than those estimated from the H-alpha-to-thermal radio luminosity ratio. Our data, at this stage, cannot unambiguously identify the source of this discrepancy. Second, the attenuation at 1500 angstroms and UV spectral slope, beta, correlate, although the slope and scatter are substantially different from the correlation first derived for starbursting galaxies by Calzetti et al. Combining our result with those of Meurer et al. for ultra-luminous infrared galaxies and Calzetti et al. for starbursting galaxies, we conclude that no single relation between beta and 1500 angstrom attenuation is applicable to all star-forming systems.Comment: 15 pages; 11 embedded postscript figures; 1 GIF figure; to appear in ApJ on 20 January 2002, vol. 565, no. 1. Section 5.1 (the discussion of the discrepancies between Balmer-derived and Radio-derived H alpha attenuations) has changed considerably to take into account small number statistics for high-mass stars in the model HII region IMFs. The abstract and conclusions have been modifie

Spitzer SAGE-SMC Infrared Photometry of Massive Stars in the Small Magellanic Cloud

We present a catalog of 5324 massive stars in the Small Magellanic Cloud (SMC), with accurate spectral types compiled from the literature, and a photometric catalog for a subset of 3654 of these stars, with the goal of exploring their infrared properties. The photometric catalog consists of stars with infrared counterparts in the Spitzer, SAGE-SMC survey database, for which we present uniform photometry from 0.3-24 um in the UBVIJHKs+IRAC+MIPS24 bands. We compare the color magnitude diagrams and color-color diagrams to those of the Large Magellanic Cloud (LMC), finding that the brightest infrared sources in the SMC are also the red supergiants, supergiant B[e] (sgB[e]) stars, luminous blue variables, and Wolf-Rayet stars, with the latter exhibiting less infrared excess, the red supergiants being less dusty and the sgB[e] stars being on average less luminous. Among the objects detected at 24 um are a few very luminous hypergiants, 4 B-type stars with peculiar, flat spectral energy distributions, and all 3 known luminous blue variables. We detect a distinct Be star sequence, displaced to the red, and suggest a novel method of confirming Be star candidates photometrically. We find a higher fraction of Oe and Be stars among O and early-B stars in the SMC, respectively, when compared to the LMC, and that the SMC Be stars occur at higher luminosities. We estimate mass-loss rates for the red supergiants, confirming the correlation with luminosity even at the metallicity of the SMC. Finally, we confirm the new class of stars displaying composite A & F type spectra, the sgB[e] nature of 2dFS1804 and find the F0 supergiant 2dFS3528 to be a candidate luminous blue variable with cold dust.Comment: 23 pages, 17 figures, 5 tables, accepted for publication in the Astronomical Journa

Distances, ages, and epoch of formation of globular clusters

We review the results on distances and absolute ages of galactic globular clusters (GCs) obtained after the release of the Hipparcos catalogue. Several methods for the Population II local distance scale are discussed, exploiting NEW RESULTS for RR Lyraes in the Large Magellanic Cloud (LMC). We find that the so-called Short and Long Distance Scales may be reconciled whether a consistent reddening scale is adopted for Cepheids and RR Lyrae variables in the LMC. Distances and ages for the 9 clusters discussed in Paper I are re-derived using an enlarged sample of local subdwarfs, which includes about 90% of the metal-poor dwarfs with accurate parallaxes (Delta p/p < 0.12) in the whole Hipparcos catalogue. On average, our revised distance moduli are decreased by 0.04 mag with respect to Paper I. The corresponding age of the GCs is t=11.5+-2.6 Gyr (95% confidence range). The relation between Mv(ZAHB) and metallicity for the nine programme clusters turns out to be Mv(ZAHB)=(0.18+-0.09)([Fe/H]+1.5)+(0.53+-0.12).Thanks to Hipparcos the major contribution to the total error budget associated with the subdwarf fitting technique has been moved from parallaxes to photometric calibrations, reddening and metallicity scale. This total uncertainty still amounts to about +-0.12 mag. Comparing the corresponding (true) LMC distance modulus 18.64+-0.12 mag with other existing determinations, we conclude that at present the best estimate for the distance of the LMC is: 18.54+-0.03+-0.06, suggesting that distances from the subdwarf fitting method are 1 sigma too long. Consequently, our best estimate for the age of the GCs is revised to: Age = 12.9+-2.9 Gyr (95% confidence range). The best relation between Mv(ZAHB) and [Fe/H] is: Mv(ZAHB) =(0.18+-0.09)([Fe/H]+1.5)+(0.63+-0.07).Comment: 76 pages, 6 encapsulated figures and 6 tables. Latex, uses aasms4.sty. Revised and improved version, with new data on field RR Lyraes in LMC. Accepted in the Astrophysical Journa