Dressing effects in the attosecond transient absorption spectra of doubly excited states in helium

Strong-field manipulation of autoionizing states is a crucial aspect of electronic quantum control. Recent measurements of the attosecond transient absorption spectrum (ATAS) of helium dressed by a few-cycle visible pulse [C. Ott, Nature (London) 516, 374 (2014)] provide evidence of the inversion of Fano profiles. With the support of accurate ab initio calculations that reproduce the results of the latter experiment, here we investigate the new physics that arise from ATAS when the laser intensity is increased. In particular, we show that (i) previously unnoticed signatures of the dark 2p2 1S doubly excited state are observed in the experimental spectrum, (ii) inversion of Fano profiles is predicted to be periodic in the laser intensity, and (iii) the ac Stark shift of the higher terms in the sp2,n+ autoionizing series exceeds the ponderomotive energy, which is the result of a genuine two-electron contribution to the polarization of the excited atomWe acknowledge computer time from the CCC-UAM and Marenostrum Supercomputer Centers and financial support from the European Research Council under the European Union’s Seventh Framework Programme (FP7/2007-2013)/ERC grant agreement 290853 XCHEM, the MINECO project FIS2013-42002-R, the ERAChemistry Project PIM2010EEC-00751, the European COST Action XLIC CM1204, the Marie Curie ITN CORINF, and the CAM project NANOFRONTMAG. C.O. and T.P. acknowledge financial support by the Max-Planck Research Group Program of the Max-Planck Gesellschaft (MPG) and the European Research Council (ERC, Grant No. X-MuSiC-616783