184 research outputs found
Heating of magnetic fluid systems driven by circularly polarized magnetic field
Cataloged from PDF version of article.A theory is presented to calculate the heat dissipation of a magnetic suspension, a ferrofluid, driven by7 circularly polarized magnetic field. Theory is tested by in vitro experiments and it is shown that, regardless of the character of the relaxation process, linearly and circularly polarized magnetic field excitations, having the same root-mean-square magnitude, are equivalent in terms of heating efficiency. (C) 2010 Elsevier B.V. All rights reserved
Extracción en fase sólida de β-sitosterol y α-tocoferol de destilados de aceite de girasol desodorizado utilizando zeolita desilicada
In this study, the efficiency of using zeolite-based adsorbents in a solid phase extraction (SPE) procedure of α-tocopherol and β-sitosterol isolation from Sunflower Oil Deodorizer Distillate (SuDOD) without pre-treatment was investigated. The results showed that 99.2% α-tocopherol and 97.3% β-sitosterol were successfully isolated as pure fractions from SuDOD, when desilicated ZSM-5-type zeolite (DSiZSM-5) was used as adsorbent on a SPE. A simple and rapid HPLC method for simultaneous α-tocopherol and β-sitosterol analysis was developed and validated according to AOAC guidelines. It was found that the inclusion of a DSiZSM-5 SPE step increased the precision of the α-tocopherol and β-sitosterol analysis. In conclusion, DSiZSM-5 zeolite was proven to be an efficient adsorbent which can be used not only for the recovery of α-tocopherol and β-sitosterol from SuDOD in industrial scale, but also in a laboratory scale clean-up method prior to the analysis of α-tocopherol and β-sitosterol.En este estudio, se investigó la eficacia del uso de adsorbentes a base de zeolita en el procedimiento de extracción en fase sólida (EFS) para el aislamiento de α-tocoferol y β-sitosterol a partir de destilados de aceites de girasol desodorizados (SuDOD) sin ningún tratamiento previo. Los resultados mostraron que el 99,2% de α-tocoferol y el 97,3% de β-sitosterol se aislaron con éxito como fracciones puras de SuDOD, cuando se usó zeolita de tipo ZSM-5 desilicado (DSiZSM-5) como adsorbente en una EFS. Se desarrolló y validó un método HPLC simple y rápido para el análisis simultáneo de α-tocoferol y β-sitosterol de acuerdo con las directrices de la AOAC. Se encontró que la inclusión del paso DSiZSM-5 EFS aumentó la precisión del análisis de α-tocoferol y β-sitosterol. En conclusión, se demostró que la zeolita DSiZSM-5 es un adsorbente eficiente que puede usarse, no solo para la recuperación de α-tocoferol y β-sitosterol de SuDOD a escala industrial, sino también en un método de limpieza a escala de laboratorio antes del análisis de α-tocoferol y β-sitosterol
Self similar Barkhausen noise in magnetic domain wall motion
A model for domain wall motion in ferromagnets is analyzed. Long-range
magnetic dipolar interactions are shown to give rise to self-similar dynamics
when the external magnetic field is increased adiabatically. The power spectrum
of the resultant Barkhausen noise is of the form , where
can be estimated from the critical exponents for interface
depinning in random media.Comment: 7 pages, RevTex. To appear in Phys. Rev. Let
Shear bands in granular flow through a mixing length model
We discuss the advantages and results of using a mixing-length, compressible
model to account for shear banding behaviour in granular flow. We formulate a
general approach based on two function of the solid fraction to be determined.
Studying the vertical chute flow, we show that shear band thickness is always
independent from flowrate in the quasistatic limit, for Coulomb wall boundary
conditions. The effect of bin width is addressed using the functions developed
by Pouliquen and coworkers, predicting a linear dependence of shear band
thickness by channel width, while literature reports contrasting data. We also
discuss the influence of wall roughness on shear bands. Through a Coulomb wall
friction criterion we show that our model correctly predicts the effect of
increasing wall roughness on the thickness of shear bands. Then a simple
mixing-length approach to steady granular flows can be useful and
representative of a number of original features of granular flow.Comment: submitted to EP
Force fluctuation in a driven elastic chain
We study the dynamics of an elastic chain driven on a disordered substrate
and analyze numerically the statistics of force fluctuations at the depinning
transition. The probability distribution function of the amplitude of the slip
events for small velocities is a power law with an exponent
depending on the driving velocity. This result is in qualitative agreement with
experimental measurements performed on sliding elastic surfaces with
macroscopic asperities. We explore the properties of the depinning transition
as a function of the driving mode (i.e. constant force or constant velocity)
and compute the force-velocity diagram using finite size scaling methods. The
scaling exponents are in excellent agreement with the values expected in
interface models and, contrary to previous studies, we found no difference in
the exponents for periodic and disordered chains.Comment: 8 page
On the role of laser-induced microstructures in influencing the surface energy of magnesia partially stabilized zirconia bioceramic
Surface energy must in some way be connected to surface chemistry and is therefore an important determinant of a biomaterial’s functions. This work elucidates the basic phenomena and wetting mechanisms associated for a widely used bioinert ceramic, magnesia partially stabilized
zirconia (MgO-PSZ) following CO2 laser treatment. Contact angles for a set of test liquids were used to measure the wettability characteristics and to reduce the surface energy of the MgO-PSZ before and after CO2 laser treatment. CO2 laser treatment of the MgO-PSZ surface was seen to
effect an improvement in the material’s wettability characteristics. Furthermore, it was found that the extent of wettability modi®cation was closely related to the microstructure induced by CO2 laser radiation on the surface of the MgO-PSZ
Depinning with dynamic stress overshoots: A hybrid of critical and pseudohysteretic behavior
A model of an elastic manifold driven through a random medium by an applied
force F is studied focussing on the effects of inertia and elastic waves, in
particular {\it stress overshoots} in which motion of one segment of the
manifold causes a temporary stress on its neighboring segments in addition to
the static stress. Such stress overshoots decrease the critical force for
depinning and make the depinning transition hysteretic. We find that the steady
state velocity of the moving phase is nevertheless history independent and the
critical behavior as the force is decreased is in the same universality class
as in the absence of stress overshoots: the dissipative limit which has been
studied analytically. To reach this conclusion, finite-size scaling analyses of
a variety of quantities have been supplemented by heuristic arguments.
If the force is increased slowly from zero, the spectrum of avalanche sizes
that occurs appears to be quite different from the dissipative limit. After
stopping from the moving phase, the restarting involves both fractal and
bubble-like nucleation. Hysteresis loops can be understood in terms of a
depletion layer caused by the stress overshoots, but surprisingly, in the limit
of very large samples the hysteresis loops vanish. We argue that, although
there can be striking differences over a wide range of length scales, the
universality class governing this pseudohysteresis is again that of the
dissipative limit. Consequences of this picture for the statistics and dynamics
of earthquakes on geological faults are briefly discussed.Comment: 43 pages, 57 figures (yes, that's a five followed by a seven), revte
A constitutive law for dense granular flows
A continuum description of granular flows would be of considerable help in
predicting natural geophysical hazards or in designing industrial processes.
However, the constitutive equations for dry granular flows, which govern how
the material moves under shear, are still a matter of debate. One difficulty is
that grains can behave like a solid (in a sand pile), a liquid (when poured
from a silo) or a gas (when strongly agitated). For the two extreme regimes,
constitutive equations have been proposed based on kinetic theory for
collisional rapid flows, and soil mechanics for slow plastic flows. However,
the intermediate dense regime, where the granular material flows like a liquid,
still lacks a unified view and has motivated many studies over the past decade.
The main characteristics of granular liquids are: a yield criterion (a critical
shear stress below which flow is not possible) and a complex dependence on
shear rate when flowing. In this sense, granular matter shares similarities
with classical visco-plastic fluids such as Bingham fluids. Here we propose a
new constitutive relation for dense granular flows, inspired by this analogy
and recent numerical and experimental work. We then test our three-dimensional
(3D) model through experiments on granular flows on a pile between rough
sidewalls, in which a complex 3D flow pattern develops. We show that, without
any fitting parameter, the model gives quantitative predictions for the flow
shape and velocity profiles. Our results support the idea that a simple
visco-plastic approach can quantitatively capture granular flow properties, and
could serve as a basic tool for modelling more complex flows in geophysical or
industrial applications.Comment: http://www.nature.com/nature/journal/v441/n7094/abs/nature04801.htm
Partially fluidized shear granular flows: Continuum theory and MD simulations
The continuum theory of partially fluidized shear granular flows is tested
and calibrated using two dimensional soft particle molecular dynamics
simulations. The theory is based on the relaxational dynamics of the order
parameter that describes the transition between static and flowing regimes of
granular material. We define the order parameter as a fraction of static
contacts among all contacts between particles. We also propose and verify by
direct simulations the constitutive relation based on the splitting of the
shear stress tensor into a``fluid part'' proportional to the strain rate
tensor, and a remaining ``solid part''. The ratio of these two parts is a
function of the order parameter. The rheology of the fluid component agrees
well with the kinetic theory of granular fluids even in the dense regime. Based
on the hysteretic bifurcation diagram for a thin shear granular layer obtained
in simulations, we construct the ``free energy'' for the order parameter. The
theory calibrated using numerical experiments with the thin granular layer is
applied to the surface-driven stationary two dimensional granular flows in a
thick granular layer under gravity.Comment: 20 pages, 19 figures, submitted to Phys. Rev.
SiC substrate effects on electron transport in the epitaxial graphene layer
Cataloged from PDF version of article.Hall effect measurements on epitaxial graphene (EG) on SiC substrate have been carried out as a function of temperature. The mobility and concentration of electrons within the two-dimensional electron gas (2DEG) at the EG layers and within the underlying SiC substrate are readily separated and characterized by the simple parallel conduction extraction method (SPCEM). Two electron carriers are identified in the EG/SiC sample: one high-mobility carrier (3493 cm(2)/Vs at 300 K) and one low-mobility carrier (1115 cm(2)/Vs at 300 K). The high mobility carrier can be assigned to the graphene layers. The second carrier has been assigned to the SiC substrate
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