32,318 research outputs found
Magnetic properties of geometrically frustrated SrGd2O4
A study of the magnetic properties of the frustrated rare earth oxide SrGd2O4
has been completed using bulk property measurements of magnetization,
susceptibility and specific heat on single crystal samples. Two zero-field
phase transitions have been identified at 2.73 and 0.48 K. For the field, H,
applied along the a and b axes, a single boundary is identified that delineates
the transition from a low field, low temperature magnetically ordered regime to
a high field, high temperature paramagnetic phase. Several field-induced
transitions, however, have been observed with H || c. The measurements have
been used to map out the magnetic phase diagram of SrGd2O4, suggesting that it
is a complex system with several competing magnetic interactions. The
low-temperature magnetic behavior of SrGd2O4 is very different compared to the
other SrLn2O4 (Ln = Lanthanide) compounds, even though all of the SrLn2O4
compounds are isostructural, with the magnetic ions forming a low-dimensional
lattice of zigzag chains that run along the c axis. The differences are likely
to be due to the fact that in the ground state Gd3+ has zero orbital angular
momentum and therefore the spin-orbit interactions, which are crucial for other
SrLn2O4 compounds, can largely be neglected. Instead, given the relatively
short Gd3+-Gd3+ distances in SrGd2O4, dipolar interactions must be taken into
account for this antiferromagnet alongside the Heisenberg exchange terms.Comment: 10 pages, 9 figure
Evolution of spin correlations in SrDy2O4 in an applied magnetic field
The development of short- and long-range magnetic order induced in a
frustrated zig-zag ladder compound SrDy2O4 by an applied field is studied using
neutron diffraction techniques. In zero field, SrDy2O4 lacks long-range
magnetic order down to temperatures as low as 60 mK, and the observed powder
neutron diffraction (PND) patterns are dominated by very broad diffuse
scattering peaks. Single crystal neutron diffraction reveals that the
zero-field magnetic structure consists of a collection of antiferromagnetic
chains running along the c axis and that there is very little correlation
between the chains in the ab plane. In an applied magnetic field, the broad
diffuse scattering features in PND are gradually replaced by much sharper
peaks, however, the pattern remains rather complex, reflecting the highly
anisotropic nature of SrDy2O4. Single crystal neutron diffraction shows that a
moderate field applied along the b axis induces an up-up-down magnetic order
associated with a 1/3-magnetisation plateau, in which magnetic correlation
length in the ab plane is significantly increased, but it nevertheless remains
finite. The resolution limited k = 0 peaks associated with a ferromagnetic
arrangement appear in powder and single crystal neutron diffraction patterns in
fields of 2.5 T and above.Comment: 10 pages, 11 figure
Lattice dynamics of anharmonic solids from first principles
An accurate and easily extendable method to deal with lattice dynamics of
solids is offered. It is based on first-principles molecular dynamics
simulations and provides a consistent way to extract the best possible harmonic
- or higher order - potential energy surface at finite temperatures. It is
designed to work even for strongly anharmonic systems where the traditional
quasiharmonic approximation fails. The accuracy and convergence of the method
are controlled in a straightforward way. Excellent agreement of the calculated
phonon dispersion relations at finite temperature with experimental results for
bcc Li and bcc Zr is demonstrated
Degeneracy and Strong Fluctuation-Induced First-Order Phase Transition in the Dipolar Pyrochlore Antiferromagnet
We show that a continuous set of degenerate critical soft modes strongly
enhances the first-order character of a fluctuation-induced first-order
transition in the pyrochlore dipolar Heisenberg antiferromagnet. Such a
degeneracy seems essential to explain the strong first-order transition
recently observed in Gd(2)Sn(2)O(7). We present some evidence from Monte-Carlo
simulations and a perturbative renormalization group expansion.Comment: 8 pages, 9 figures, new version to appear in PRB, added ref
Interannual variability of tropospheric composition:the influence of changes in emissions, meteorology and clouds
We have run a chemistry transport model (CTM) to systematically examine the drivers of interannual variability of tropospheric composition during 1996-2000. This period was characterised by anomalous meteorological conditions associated with the strong El Nino of 1997-1998 and intense wildfires, which produced a large amount of pollution. On a global scale, changing meteorology (winds, temperatures, humidity and clouds) is found to be the most important factor driving interannual variability of NO2 and ozone on the timescales considered. Changes in stratosphere-troposphere exchange, which are largely driven by meteorological variability, are found to play a particularly important role in driving ozone changes. The strong influence of emissions on NO2 and ozone interannual variability is largely confined to areas where intense biomass burning events occur. For CO, interannual variability is almost solely driven by emission changes, while for OH meteorology dominates, with the radiative influence of clouds being a very strong contributor. Through a simple attribution analysis for 1996-2000 we conclude that changing cloudiness drives 25% of the interannual variability of OH over Europe by affecting shortwave radiation. Over Indonesia this figure is as high as 71%. Changes in cloudiness contribute a small but non-negligible amount (up to 6%) to the interannual variability of ozone over Europe and Indonesia. This suggests that future assessments of trends in tropospheric oxidizing capacity should account for interannual variability in cloudiness, a factor neglected in many previous studies
Development of the technology for the fabrication of reliable laminar from control panels
Materials were assessed and fabrication techniques were developed for use in the manufacture of wing surface materials compatible with the application of both aluminum alloys and nonmetallic composites. The concepts investigated included perforations and slots in the metallic test panels and microporosity and perforations in the composite test panels. Perforations were produced in the metallic test panels by the electron beam process and slots were developed by controlled gaps between the metal sheets. Microporosity was produced in the composite test panels by the resin bleed process, and perforations were produced by the fugitive fiber technique. Each of these concepts was fabricated into test panels, and air flow tests were conducted on the panels
Dynamic van der Waals Theory of two-phase fluids in heat flow
We present a dynamic van der Waals theory. It is useful to study phase
separation when the temperature varies in space. We show that if heat flow is
applied to liquid suspending a gas droplet at zero gravity, a convective flow
occurs such that the temperature gradient within the droplet nearly vanishes.
As the heat flux is increased, the droplet becomes attached to the heated wall
that is wetted by liquid in equilibrium. In one case corresponding to partial
wetting by gas, an apparent contact angle can be defined. In the ther case with
larger heat flux, the droplet completely wets the heated wall expelling liquid.Comment: 6pages, 8figure
Proportional-integral-plus (PIP) control of time delay systems
The paper shows that the digital proportional-integral-plus (PIP) controller formulated within the context of non-minimum state space (NMSS) control system design methodology is directly equivalent, under certain non-restrictive pole assignment conditions, to the equivalent digital Smith predictor (SP) control system for time delay systems. This allows SP controllers to be considered within the context of NMSS state variable feedback control, so that optimal design methods can be exploited to enhance the performance of the SP controller. Alternatively, since the PIP design strategy provides a more flexible approach, which subsumes the SP controller as one option, it provides a superior basis for general control system design. The paper also discusses the robustness and disturbance response characteristics of the two PIP control structures that emerge from the analysis and demonstrates the efficacy of the design methods through simulation examples and the design of a climate control system for a large horticultural glasshouse system
Absence of Ferromagnetism in Mn-doped Tetragonal Zirconia
In a recent letter, it has been predicted within first principle studies that
Mn-doped ZrO2 compounds could be good candidate for spintronics application
because expected to exhibit ferromagnetism far beyond room temperature. Our
purpose is to address this issue experimentally for Mn-doped tetragonal
zirconia. We have prepared polycrystalline samples of Y0.15(Zr0.85-yMny)O2
(y=0, 0.05, 0.10, 0.15 & 0.20) by using standard solid state method at
equilibrium. The obtained samples were carefully characterized by using x-ray
diffraction, scanning electron microscopy, elemental color mapping, X-ray
photoemission spectroscopy and magnetization measurements. From the detailed
structural analyses, we have observed that the 5% Mn doped compound
crystallized into two symmetries (dominating tetragonal & monoclinic), whereas
higher Mn doped compounds are found to be in the tetragonal symmetry only. The
spectral splitting of the Mn 3s core-level x-ray photoelectron spectra confirms
that Mn ions are in the Mn3+ oxidation state and indicate a local magnetic
moment of about 4.5 {\mu}B/Mn. Magnetic measurements showed that compounds up
to 10% of Mn doping are paramagnetic with antiferromagnetic interactions.
However, higher Mn doped compound exhibits local ferrimagnetic ordering. Thus,
no ferromagnetism has been observed for all Mn-doped tetragonal ZrO2 samples.Comment: 20 pages, 4 figure
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