Editorial: A Search for Conjunctions at a Time of Direction-setting Review and Synthesis

This journal reflects a diversity of environment and sustainability education research and viewpoints alongside two synthesis papers. Read as a whole and within a widely held ideal that diversity reflects resilience, the environment and education for sustainable development landscape in Africa might be said to be healthy and proliferating. But read against the pressure to produce tangible evidence of change on an African landscape of persistent climate variation and poverty, along with a widening gap between rich and poor, the picture remains challenging. These contrasting readings are notable at a time when we are looking towards the Associationfor the Development of Education in Africa (ADEA) Triennial in February, 2012, the Rio+20 Earth Summit in June 2012 and our own EEASA +30 conference in September 2012. The UN Decade of Education for Sustainable Development is characterised by a proliferation of education imperatives. These emerged as modern education in response to the issues of the day and now a modernity in deepening crisis. The scope of the change is notable in a UNESCO teacher education module that is today called Global Climate Change Learning for Sustainable Development (UNESCO, 2012). Here, education to address global risk is re-inscribed as learningto mitigate the impact of climate change alongside adaptive learning to change. In the lead-up to Rio+20 there is also an emphasis on learning as transition to a ‘green economy’ or for a ‘green society’. The subtle differences in terms here are provoking as much intense debate as did the advent of education for sustainable development (ESD) over a decade ago. The diversity in this journal challenges us to have a closer look at the ideals that shape and steer a globalising modernity. Here education, as emergent systems of reason, is orientated to shape citizens so as to mitigate risk that is being produced by the growth-orientated engineroom of the modernist project, an issue that still remains relatively untouched by educative practic

Think Piece: Re-thinking Education for Sustainable Development as Transgressive Processes of Educational Engagement with Human Conduct, Emerging Matters of Concern and the Common Good

The modernist expansion of Education is examined to explore how the concept of Education for Sustainable Development (ESD) has emerged, is being worked with, and is being assessed in imperatives intended to foster social-ecological change on a global scale. The opening review sketches how education developed as a mediating process in modernity, tracking some recent shifts that are shaping ESD in more and more diverse contexts of education practice. It scopes an ESD terrain where knowledge and ethics-led learning in relation to valued purposes might enable citizens to become engaged in change that secures a  sustainable future for generations to come. Within these processes, competence specification is  examined as a useful but under-theorised social imaginary for framing learning for future sustainability, primarily in teacher education and curriculum contexts. Here, ESD presents as an open process of situated social learning where emergent  competences steer social innovation towards a more sustainable future (SD). The paper attempts to navigate some of the current tensions in relation to knowledge and participation in these processes of learning-to-change. It probes ESD as praxiological processes of dialectical reflexivity that can become situated in contexts of risk and develop as transgressive1 expansions within many conventional learning sequences in curriculum settings. The paper notes that current discourses on ESD and its assessment have often come to stand outside, and in contrast with, conventions of teaching and learning. These discourses also often conflate  education and sustainable  development in ways that ascribe change to ESD without adequately theorising the expansive and reflexive learning of citizens and how these processes might produce the desired change towards  sustainable development (SD) in diverse contexts of learning in and about a changing world

The Quiescent Spectrum of the AM CVn star CP Eri

We used the 6.5m MMT to obtain a spectrum of the AM CVn star CP Eri in quiescence. The spectrum is dominated by He I emission lines, which are clearly double peaked with a peak-to-peak separation of ~1900 km/s. The spectrum is similar to that of the longer period AM CVn systems GP Com and CE 315, linking the short and the long period AM CVn systems. In contrast with GP Com and CE 315, the spectrum of CP Eri does not show a central 'spike' in the line profiles, but it does show lines of SiII in emission. The presence of these lines indicates that the material being transferred is of higher metallicity than in GP Com and CE 315, which, combined with the low proper motion of the system, probably excludes a halo origin of the progenitor of CP Eri. We constrain the primary mass to M_1>0.27 M_sun and the orbital inclination to 33 degr < i < 80 degr. The presence of the He I lines in emission opens up the possibility for phase resolved spectroscopic studies which allows a determination of the system parameters and a detailed study of helium accretion disks under highly varying circumstances.Comment: 12 pages, 2 figures, accepted for publication in ApJ Letter

Understanding thio-effects in simple phosphoryl systems : role of solvent effects and nucleophile charge.

Recent experimental work (J. Org. Chem., 2012, 77, 5829) demonstrated pronounced differences in measured thio-effects for the hydrolysis of (thio)phosphodichloridates by water and hydroxide nucleophiles. In the present work, we have performed detailed quantum chemical calculations of these reactions, with the aim of rationalizing the molecular bases for this discrimination. The calculations highlight the interplay between nucleophile charge and transition state solvation in SN2(P) mechanisms as the basis of these differences, rather than a change in mechanism

IR Monitoring of the Microquasar GRS 1915+105: Detection of Orbital and Superhump Signatures

We present the results of seven years of K-band monitoring of the low-mass X-ray binary GRS 1915+105. Positive correlations between the infrared flux and the X-ray flux and X-ray hardness are demonstrated. Analysis of the frequency spectrum shows that the orbital period of the system is $P_{orb}= 30.8 \pm 0.2$ days. The phase and amplitude of the orbital modulation suggests that the modulation is due to the heating of the face of the secondary star. We also report another periodic signature between 31.2 and 31.6 days, most likely due to a superhump resonance. From the superhump period we then obtain a range on the mass ratio of the system, $0.05 < q < 0.12$.Comment: 16 pages, 6 figures; v2: minor change

On Echo Outbursts and ER UMa Supercycles in SU UMa-type Cataclysmic Variables

I present a variation on Osaki's tidal-thermal-instability model for SU UMa behavior. I suggest that in systems with the lowest mass ratios, the angular-momentum dissipation in an eccentric disk is unable to sustain the disk on the hot side of the thermal instability. This decoupling of the tidal and thermal instabilities in systems with q < 0.07 allows a better explanation of the `echo' outbursts of EG Cnc and the short supercycles of RZ LMi and DI UMa. The idea might also apply to the soft X-ray transients.Comment: To appear in PASP, April 2001 (6 pages, 4 figs

The Helium-Rich Cataclysmic Variable ES Ceti

We report photometry of the helium-rich cataclysmic variable ES Ceti during 2001-2004. The star is roughly stable at V ~ 17.0 and has a light curve dominated by a single period of 620 s, which remains measurably constant over the 3 year baseline. The weight of evidence suggests that this is the true orbital period of the underlying binary, not a "superhump" as initially assumed. We report GALEX ultraviolet magnitudes, which establish a very blue flux distribution (F_nu ~ nu^1.3), and therefore a large bolometric correction. Other evidence (the very strong He II 4686 emission, and a ROSAT detection in soft X-rays) also indicates a strong EUV source, and comparison to helium-atmosphere models suggests a temperature of 130+-10 kK. For a distance of 350 pc, we estimate a luminosity of (0.8-1.7)x10^34 erg/s, yielding a mass accretion rate of (2-4)x10^-9 M_sol/yr onto an assumed 0.7 M_sol white dwarf. This appears to be about as expected for white dwarfs orbiting each other in a 10 minute binary, assuming that mass transfer is powered by gravitational radiation losses. We estimate mean accretion rates for other helium-rich cataclysmic variables, and find that they also follow the expected M-dot ~ P_o^-5 relation. There is some evidence (the lack of superhumps, and the small apparent size of the luminous region) that the mass transfer stream in ES Cet directly strikes the white dwarf, rather than circularizing to form an accretion disk.Comment: PDF, 26 pages, 3 tables, 9 figures; accepted, in press, to appear February 2005, PASP; more info at http://cba.phys.columbia.edu

The Edinburgh-Cape Blue Object Survey - III. Zone 2; galactic latitudes -30? > b > -40?

The Edinburgh–Cape Blue Object Survey seeks to identify point sources with an ultraviolet excess. Results for zone 2 of the survey are presented here, covering that part of the South Galactic Cap between 30◦ and 40◦ from the Galactic plane and south of about −12. ◦ 3 of declination. Edinburgh–Cape zone 2 comprises 66 UK Schmidt Telescope fields covering about 1730 deg2, in which we find some 892 blue objects, including 423 hot subdwarfs (∼47 per cent); 128 white dwarfs (∼14 per cent); 25 cataclysmic variables (∼3 per cent); 119 binaries (∼13 per cent), mostly composed of a hot subdwarf and a main-sequence F or G star; 66 horizontal branch stars (∼7 per cent) and 48 ‘star-like’ extragalactic objects (∼5 per cent). A further 362 stars observed in the survey, mainly low-metallicity F- and G-type stars, are also listed. Both low-dispersion spectroscopic classification and UBV photometry are presented for almost all of the hot objects and either spectroscopy or photometry (or both) for the cooler ones.Department of HE and Training approved lis

The amino-terminal domain of pyrrolysyl-tRNA synthetase is dispensable in vitro but required for in vivo activity

AbstractPyrrolysine (Pyl) is co-translationally inserted into a subset of proteins in the Methanosarcinaceae and in Desulfitobacterium hafniense programmed by an in-frame UAG stop codon. Suppression of this UAG codon is mediated by the Pyl amber suppressor tRNA, tRNAPyl, which is aminoacylated with Pyl by pyrrolysyl-tRNA synthetase (PylRS). We compared the behavior of several archaeal and bacterial PylRS enzymes towards tRNAPyl. Equilibrium binding analysis revealed that archaeal PylRS proteins bind tRNAPyl with higher affinity (KD=0.1–1.0μM) than D. hafniense PylRS (KD=5.3–6.9μM). In aminoacylation the archaeal PylRS enzymes did not distinguish between archaeal and bacterial tRNAPyl species, while the bacterial PylRS displays a clear preference for the homologous cognate tRNA. We also show that the amino-terminal extension present in archaeal PylRSs is dispensable for in vitro activity, but required for PylRS function in vivo

MMT Observations of the Black Hole Candidate XTE J1118+480 near and in Quiescence

We report on the analysis of new and previously published MMT optical spectra of the black hole binary XTE J1118+480 during the decline from the 2000 outburst to true quiescence. From cross-correlation with template stars, we measure the radial velocity of the secondary to derive a new spectroscopic ephemeris. The observations acquired during approach to quiescence confirm the earlier reported modulation in the centroid of the double-peaked Halpha emission line. Additionally, our data combined with the results presented by Zurita et al. (2002) provide support for a modulation with a periodicity in agreement with the expected precession period of the accretion disk of ~52 day. Doppler images during the decline phase of the Halpha emission line show evidence for a hotspot and emission from the gas stream: the hotspot is observed to vary its position, which may be due to the precession of the disk. The data available during quiescence show that the centroid of the Halpha emission line is offset by about -100 km/s from the systemic velocity which suggests that the disk continues to precess. A Halpha tomogram reveals emission from near the donor star after subtraction of the ring-like contribution from the accretion disk which we attribute to chromospheric emission. No hotspot is present suggesting that accretion from the secondary has stopped (or decreased significantly) during quiescence. Finally, a comparison is made with the black hole XRN GRO J0422+32: we show that the Halpha profile of this system also exhibits a behaviour consistent with a precessing disk.Comment: 11 pages, 5 figures, accepted by Ap