Synthesis and spectroscopic characterization of selected water-soluble ligands based on 1,10-phenanthroline core

Water-soluble ligands based on a 1,10-phenanthroline core are relatively poorly studied compounds. Developing efficient and convenient syntheses of them would result in new interesting applications because of the importance of 1,10-phenanthrolines. In this manuscript, we describe novel and practical ways to introduce a carboxyl and, for the first time, a phenol and dithiocarboxyl group under mild reaction conditions. This strategy enables highly efficient and practical synthesis of suitable organosulfur compounds with high added value, high chemoselectivity, and a broad substrate range. We present the selective conversion of a hydroxydialdehyde in the form of 10-hydroxybenzo[h]quinoline-7,9-dicarbaldehyde into its derivative, unique hydroxydicarboxylic acid, by an oxidation procedure, giving 10-hydroxybenzo[h]quinoline-7,9-dicarboxylic acid. A similar procedure resulted in the formation of 9-methyl-1,10-phenanthroline-2-carboxylic acid by oxidation of commercially available neocuproine. An alternative method of obtaining 1,10-phenanthroline derivatives possessing carboxylic acid group can be based on the hydrolysis of ester or nitrile groups; however, this synthesis leads to unexpected products. Moreover, we apply Perkin condensation to synthesize a vinyl (or styryl) analog of 1,10-phenanthroline derivatives with phenol function. This reaction also demonstrates a new, simple, and efficient strategy for converting methyl derivatives of 1,10-phenanthroline. We anticipate that the new way of converting methyl will find wide application in chemical synthesis

Ratunku! or just tunku! : evidence for the reliability and concurrent validity of the Language Use Inventory : LUI-Polish

Purpose: To date, there is no tool for assessing early pragmatic development of Polish-speaking children. This study aimed to adapt to Polish a standardized parent report measure, the Language Use Inventory (LUI; O’Neill, 2009, in order to enable cross-cultural comparisons and to use the LUI-Polish to screen for pragmatic development in children 18-47 months of age. We concentrated on the sociocultural and functional adaptation of LUI and aimed to demonstrate its reliability, developmental sensitivity, and concurrent validity. Method: Parents completed an online version of LUIPolish, longitudinally at 3 time points (when the child was 20, 32, and 44 months old). In addition, parents completed the Polish adaptations of the Questionnaire for Communication and Early Language at 22 months and the Language Development Survey at 24 months. Children’s spontaneous speech was assessed at 24 months, and their expressive and receptive vocabulary was assessed at 36 months. Results: All 3 parts of the LUI-Polish (Gestures, Words, and Sentences) showed very good levels of internal consistency at each time point. Significant correlations were observed between all parts of the LUI-Polish at all 3 measurement time points. The expected developmental trajectory was observed for boys and girls providing evidence of its developmental sensitivity for children between the ages of 2 and 4 years: an increase with age in the total score (due to an increase in Words and Sentences) and a decrease in Gestures. Supporting concurrent validity, significant correlations were found between children’s performance on (a) the LUI-Polish at 20 months and the Questionnaire for Communication and Early Language at 22 months as well as the Language Development Survey and spontaneous speech measures at 24 months and (b) the LUI-Polish at 32 months and the 2 measures of vocabulary comprehension and production at 36 months. Conclusion: The Polish adaptation of the LUI demonstrated good psychometric properties that provide a sound basis for cross-cultural comparisons and further research toward norming of the LUI-Polish. Moreover, the expected developmental trajectory in the pragmatic development of Polish children was observed

Measurement of the Generalized Polarizabilities of the Proton in Virtual Compton Scattering

We propose to conduct a measurement of the Virtual Compton Scattering reaction in Hall C that will allow the precise extraction of the two scalar Generalized Polarizabilities (GPs) of the proton in the region of $Q^2=0.05~(GeV/c)^2$ to $Q^2=0.50~(GeV/c)^2$. The Generalized Polarizabilities are fundamental properties of the proton, that characterize the system's response to an external electromagnetic (EM) field. They describe how easily the charge and magnetization distributions inside the system are distorted by the EM field, mapping out the resulting deformation of the densities in the proton. As such, they reveal unique information regarding the underlying system dynamics and provide a key for decoding the proton structure in terms of the theory of the strong interaction that binds its elementary quark and gluon constituents together. Recent measurements of the proton GPs have challenged the theoretical predictions, particularly in regard to the electric polarizability. The magnetic GP, on the other hand, can provide valuable insight to the competing paramagnetic and diamagnetic contributions in the proton, but it is poorly known within the region where the interplay of these processes is very dynamic and rapidly changing.The unique capabilities of Hall C, namely the high resolution of the spectrometers combined with the ability to place the spectrometers in small angles, will allow to pin down the dynamic signature of the GPs through high precision measurements combined with a fine mapping as a function of $Q^2$. The experimental setup utilizes standard Hall C equipment, as was previously employed in the VCS-I (E12-15-001) experiment, namely the HMS and SHMS spectrometers and a 10 cm liquid hydrogen target. A total of 59 days of unpolarized 75 $\mu A$ electron beam with energy of 1100 MeV (6 days) and 2200 MeV (53 days) is requested for this experiment

Density Changes in Low Pressure Gas Targets for Electron Scattering Experiments

A system of modular sealed gas target cells has been developed for use in electron scattering experiments at the Thomas Jefferson National Accelerator Facility (Jefferson Lab). This system was initially developed to complete the MARATHON experiment which required, among other species, tritium as a target material. Thus far, the cells have been loaded with the gas species 3H, 3He, 2H, 1H and 40Ar and operated in nominal beam currents of up to 22.5 uA in Jefferson Lab's Hall A. While the gas density of the cells at the time of loading is known, the density of each gas varies uniquely when heated by the electron beam. To extract experimental cross sections using these cells, density dependence on beam current of each target fluid must be determined. In this study, data from measurements with several beam currents within the range of 2.5 to 22.5 uA on each target fluid are presented. Additionally, expressions for the beam current dependent fluid density of each target are developed.Comment: 8 pages, 12 figures, 4 table

The Solenoidal Large Intensity Device (SoLID) for JLab 12 GeV

The Solenoidal Large Intensity Device (SoLID) is a new experimental apparatus planned for Hall A at the Thomas Jefferson National Accelerator Facility (JLab). SoLID will combine large angular and momentum acceptance with the capability to handle very high data rates at high luminosity. With a slate of approved high-impact physics experiments, SoLID will push JLab to a new limit at the QCD intensity frontier that will exploit the full potential of its 12 GeV electron beam. In this paper, we present an overview of the rich physics program that can be realized with SoLID, which encompasses the tomography of the nucleon in 3-D momentum space from Semi-Inclusive Deep Inelastic Scattering (SIDIS), expanding the phase space in the search for new physics and novel hadronic effects in parity-violating DIS (PVDIS), a precision measurement of $J/\psi$ production at threshold that probes the gluon field and its contribution to the proton mass, tomography of the nucleon in combined coordinate and momentum space with deep exclusive reactions, and more. To meet the challenging requirements, the design of SoLID described here takes full advantage of recent progress in detector, data acquisition and computing technologies. In addition, we outline potential experiments beyond the currently approved program and discuss the physics that could be explored should upgrades of CEBAF become a reality in the future.Comment: This white paper for the SoLID program at Jefferson Lab was prepared in part as an input to the 2023 NSAC Long Range Planning exercise. To be submitted to J. Phys.

First Measurement of the Ti (e,e′) X Cross Section at Jefferson Lab

To probe CP violation in the leptonic sector using GeV energy neutrino beams in current and future experiments using argon detectors, precise models of the complex underlying neutrino and antineutrino interactions are needed. The E12-14-012 experiment at Jefferson Lab Hall A was designed to perform a combined analysis of inclusive and exclusive electron scatterings on both argon (N=22) and titanium (Z=22) nuclei using GeV-energy electron beams. The measurement on titanium nucleus provides essential information to understand the neutrino scattering on argon, large contribution to which comes from scattering off neutrons. Here we report the first experimental study of electron-titanium scattering as double-differential cross section at beam energy E=2.222 GeV and electron-scattering angle θ=15.541^{∘}, measured over a broad range of energy transfer, spanning the kinematical regions in which quasielastic scattering and delta production are the dominant reaction mechanisms. The data provide valuable new information needed to develop accurate theoretical models of the electromagnetic and weak cross sections of these complex nuclei in the kinematic regime of interest to neutrino experiments.National Science Foundation (U.S.) (CAREER Grant PHY-1352106

First Measurement of the Ti(e,e′)X(e,e^\prime){\rm X} Cross Section at Jefferson Lab

To probe CP violation in the leptonic sector using GeV energy neutrino beams in current and future experiments using argon detectors, precise models of the complex underlying neutrino and antineutrino interactions are needed. The E12-14-012 experiment at Jefferson Lab Hall A was designed to perform a combined analysis of inclusive and exclusive electron scatterings on both argon ($N = 22$) and titanium ($Z = 22$) nuclei using GeV energy electron beams. The measurement on titanium nucleus provides essential information to understand the neutrino scattering on argon, large contribution to which comes from scattering off neutrons. Here we report the first experimental study of electron-titanium scattering as double differential cross section at beam energy $E=2.222$ GeV and electron scattering angle $\theta = 15.541$ deg, measured over a broad range of energy transfer, spanning the kinematical regions in which quasielastic scattering and delta production are the dominant reaction mechanisms. The data provide valuable new information needed to develop accurate theoretical models of the electromagnetic and weak cross sections of these complex nuclei in the kinematic regime of interest to neutrino experiments.Comment: 6 pages, 5 figures. Version published in Physical Review

Measurement of the Ar(e,e′^\prime p) and Ti(e,e′^\prime p) cross sections in Jefferson Lab Hall A

The E12-14-012 experiment, performed in Jefferson Lab Hall A, has collected exclusive electron-scattering data (e,e$^\prime$p) in parallel kinematics using natural argon and natural titanium targets. Here, we report the first results of the analysis of the data set corresponding to beam energy of 2,222 MeV, electron scattering angle 21.5 deg, and proton emission angle -50 deg. The differential cross sections, measured with $\sim$4% uncertainty, have been studied as a function of missing energy and missing momentum, and compared to the results of Monte Carlo simulations, obtained from a model based on the Distorted Wave Impulse Approximation.Comment: 14 pages, 8 figures (submitted to PRC

Measurement of the Cross Sections for Inclusive Electron Scattering in the E12-14-012 Experiment at Jefferson Lab

The E12-14-012 experiment performed at Jefferson Lab Hall A has collected inclusive electron-scattering data for different targets at the kinematics corresponding to beam energy 2.222 GeV and scattering angle 15.54°. Here we present a comprehensive analysis of the collected data and compare the double-differential cross sections for inclusive scattering of electrons, extracted using solid targets (aluminum, carbon, and titanium) and a closed argon-gas cell. The data extend over broad range of energy transfer, where quasielastic interaction, Δ-resonance excitation, and inelastic scattering yield contributions to the cross section. The double-differential cross sections are reported with high precision (∼3%) for all targets over the covered kinematic range